A weakly solvating electrolyte towards practical rechargeable aqueous zinc-ion batteries.
Nat Commun
; 15(1): 302, 2024 Jan 05.
Article
em En
| MEDLINE
| ID: mdl-38182604
ABSTRACT
Structure deterioration and side reaction, which originated from the solvated H2O, are the main constraints for the practical deployment of both cathode and anode in aqueous Zn-ion batteries. Here we formulate a weakly solvating electrolyte to reduce the solvating power of H2O and strengthen the coordination competitiveness of SO42- to Zn2+ over H2O. Experiment results and theoretical simulations demonstrate that the water-poor solvation structure of Zn2+ is achieved, which can (i) substantially eliminate solvated-H2O-mediated undesirable side reactions on the Zn anode. (ii) boost the desolvation kinetics of Zn2+ and suppress Zn dendrite growth as well as structure aberration of the cathode. Remarkably, the synergy of these two factors enables long-life full cells including Zn/NaV3O8·1.5H2O, Zn/MnO2 and Zn/CoFe(CN)6 cells. More importantly, practical rechargeable AA-type Zn/NVO cells are assembled, which present a capacity of 101.7 mAh and stability of 96.1% capacity retention after 30 cycles at 0.66 C.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Nat Commun
Ano de publicação:
2024
Tipo de documento:
Article