Electrochemical decarboxylative alkylation of ß-ketoacids with phenol derivatives.
Chem Commun (Camb)
; 60(10): 1329-1332, 2024 Jan 30.
Article
em En
| MEDLINE
| ID: mdl-38197300
ABSTRACT
An electrochemical method for the decarboxylative alkylation of ß-ketoacids with phenol derivatives has been developed. The protocol was carried out in readily available unseparated cells at room temperature in the absence of catalysts and oxidants. The corresponding aryl ketones were obtained in satisfactory yields without additional electrolytes, and were easy to produce in gram-scale synthesis. Based on control experiments and cyclic voltammetry, a plausible reaction mechanism was proposed.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2024
Tipo de documento:
Article