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Regulating luminescence thermal enhancement in negative thermal expansion metal-organic frameworks.
Chen, Liang; Cao, Yili; Ma, Rui; Cao, Hongmei; Chen, Xin; Lin, Kun; Li, Qiang; Deng, Jinxia; Liu, Chunyu; Wang, Yilin; Huang, Ling; Xing, Xianran.
Afiliação
  • Chen L; Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.
  • Cao Y; Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.
  • Ma R; Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.
  • Cao H; Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.
  • Chen X; Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.
  • Lin K; Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.
  • Li Q; Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.
  • Deng J; Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.
  • Liu C; Department of Chemistry, Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education, Tsinghua University 100084 Beijing China.
  • Wang Y; Institute of Advanced Materials, Nanjing Tech University 211816 Nanjing China iamlhuang@njtech.edu.cn.
  • Huang L; Institute of Advanced Materials, Nanjing Tech University 211816 Nanjing China iamlhuang@njtech.edu.cn.
  • Xing X; Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing 100083 Beijing China xing@ustb.edu.cn yilicao@ustb.edu.cn.
Chem Sci ; 15(10): 3721-3729, 2024 Mar 06.
Article em En | MEDLINE | ID: mdl-38455009
ABSTRACT
Overcoming thermal quenching is generally essential for the practical application of luminescent materials. It has been recently found that frameworks with negative thermal expansion (NTE) could be a promising candidate to engineer unconventional luminescence thermal enhancement. However, the mechanism through which luminescence thermal enhancement can be well tuned remains an open issue. In this work, enabled by altering ligands in a series of UiO-66 derived Eu-based metal-organic frameworks, it was revealed that the changes in the thermal expansion are closely related to luminescence thermal enhancement. The NTE of the aromatic ring part favors luminescence thermal enhancement, while contraction of the carboxylic acid part plays the opposite role. Modulation of functional groups in ligands can change the thermal vibration of aromatic rings and then achieve luminescence thermal enhancement in a wide temperature window. Our findings pave the way to manipulate the NTE and luminescence thermal enhancement based on ligand engineering.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Sci Ano de publicação: 2024 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Sci Ano de publicação: 2024 Tipo de documento: Article