{N-[1-(2-Oxidophen-yl)ethyl-idene]-dl-alaninato}(pentane-1,5-di-yl)silicon(IV).
IUCrdata
; 9(Pt 3): x240228, 2024 Mar.
Article
em En
| MEDLINE
| ID: mdl-38586525
ABSTRACT
The title SiIV complex, C16H21NO3Si, is built up by a tridentate dinegative Schiff base ligand bound to a sila-cyclo-hexane unit. The coordination geometry of the penta-coordinated SiIV atom is a distorted trigonal bipyramid. The presence of the sila-cyclo-hexane ring in the complex leads to an unusual coordination geometry of the SiIV atom with the N atom from the Schiff base ligand and an alkyl-C atom in apical positions of the trigonal bipyramid. There is a disorder of the methyl group at the imine bond with two orientations resolved for the H atoms [major orientation = 0.55â
(3)]. In the crystal, C-Hâ¯O inter-actions are found within corrugated layers of mol-ecules parallel to the ab plane.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
IUCrdata
Ano de publicação:
2024
Tipo de documento:
Article