Structure of the five-coordinate CoII complex (1H-imidazole){tris-[(1-benzyl-triazol-4-yl-κN3)meth-yl]amine-κN}cobalt(II) bis-(tetra-fluoro-borate).
Acta Crystallogr E Crystallogr Commun
; 80(Pt 5): 486-488, 2024 Apr 01.
Article
em En
| MEDLINE
| ID: mdl-38721414
ABSTRACT
The title compound, [Co(C3H4N2)(C30H30N10)](BF4)2, is a five-coordinate CoII complex based on the neutral ligands tris-[(1-benzyl-triazol-4-yl)meth-yl]amine (tbta) and imidazole. It exhibits a distorted trigonal bipyramidal geometry in which the equatorial positions are occupied by the three N-atom donors from the triazole rings of the tripodal tbta ligand. The apical amine N-atom donor of tbta and the N-atom donor of the imidazole ligand occupy the axial positions of the coordination sphere. Two tetra-fluoro-borate anions provide charge balance in the crystal.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
Acta Crystallogr E Crystallogr Commun
Ano de publicação:
2024
Tipo de documento:
Article