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Synthesis and properties of an O-doped aromatic belt.
Han, Ying; Guo, Wei-Chen; Du, Xu-Sheng; Chen, Chuan-Feng.
Afiliação
  • Han Y; Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. hanying463@iccas.ac.cn.
  • Guo WC; Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. hanying463@iccas.ac.cn.
  • Du XS; University of Chinese Academy of Sciences, Beijing 100049, China.
  • Chen CF; Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. hanying463@iccas.ac.cn.
Chem Commun (Camb) ; 60(44): 5719-5722, 2024 May 28.
Article em En | MEDLINE | ID: mdl-38742271
ABSTRACT
A new macrocyclic arene, dibenzofuran[3]arene, was synthesized, which could be conveniently transformed to an O-doped aromatic belt with a rigid ring-shaped structure and deep cavity. Moreover, the O-doped aromatic belt also showed a high HOMO energy and a narrow HOMO-LUMO gap experimentally and theoretically.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Ano de publicação: 2024 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Ano de publicação: 2024 Tipo de documento: Article