Recent Advances on the Chemistry of Transition Metal Complexes with Monoanionic Bidentate Silyl Ligands.
Chempluschem
; : e202400162, 2024 May 23.
Article
em En
| MEDLINE
| ID: mdl-38781084
ABSTRACT
The chemistry of transition-metal (TM) complexes with monoanionic bidentate (κ2-L,Si) silyl ligands has considerably grown in recent years. This work summarizes the advances in the chemistry of TM-(κ2-L,Si) complexes (L=N-heterocycle, phosphine, N-heterocyclic carbene, thioether, ester, silylether or tetrylene). The most common synthetic method has been the oxidative addition of the Si-H bond to the metal center assisted by the coordination of L. The metal silicon bond distances in TM-(κ2-L,Si) complexes are in the range of metal-silyl bond distances. TM-(κ2-L,Si) complexes have proven to be effective catalysts for hydrosilylation and/or hydrogenation of unsaturated molecules among other processes.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
ChemPlusChem (Weinh.)
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ChemPlusChem (Weinheim)
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Chempluschem
Ano de publicação:
2024
Tipo de documento:
Article