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Effective removal of acetamiprid and eosin Y by adsorption on pristine and modified MIL-101(Fe).
Sakr, Mohamed; Adly, Mina Shawky; Gar Alalm, Mohamed; Mahanna, Hani.
Afiliação
  • Sakr M; Public Works Engineering Department, Faculty of Engineering, Mansoura University, Mansoura, 35516, Egypt.
  • Adly MS; Chemistry Department, Faculty of Science, Mansoura University, Mansoura, 35516, Egypt.
  • Gar Alalm M; Public Works Engineering Department, Faculty of Engineering, Mansoura University, Mansoura, 35516, Egypt. m_gar_alalm@mans.edu.eg.
  • Mahanna H; Public Works Engineering Department, Faculty of Engineering, Mansoura University, Mansoura, 35516, Egypt.
Environ Sci Pollut Res Int ; 31(28): 41221-41245, 2024 Jun.
Article em En | MEDLINE | ID: mdl-38847950
ABSTRACT
In this work, the efficacy of two metal-organic frameworks (MIL-101(Fe) and NH2-MIL-101(Fe)) in eliminating acetamiprid (ATP) insecticide and eosin Y (EY) dye from aqueous solution is tested. An analysis was conducted on the developed nanocomposite's optical, morphological, and structural characteristics. The adsorption isotherm, kinetics, thermodynamics, reusability, and mechanisms for ATP and EY dye removal were assessed. NH2-MIL-101(Fe) adsorbed 76% and 90% of ATP pesticide and EY dye, respectively after 10 to 15 min in optimum conditions. For both adsorbents, with regard to explaining the isotherm data, the Langmuir model offered the most accurate description. Moreover, the adsorption of ATP and EY dye is described by the pseudo-second-order kinetic model. The maximum adsorption capacities of ATP and EY dye on MIL-101(Fe) were 57.6 and 48.9 mg/g compared to 70.5 and 97.8 mg/g using NH2-MIL-101(Fe). The greatest amount of ATP and EY dye clearance was obtained at a neutral medium for both adsorbents. The results of this investigation demonstrate the effectiveness of MIL-101(Fe) and NH2-MIL-101(Fe) as effective substances in the adsorption process for removing pesticides and dyes from aqueous solution.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Poluentes Químicos da Água / Amarelo de Eosina-(YS) / Estruturas Metalorgânicas / Neonicotinoides Idioma: En Revista: Environ Sci Pollut Res Int Ano de publicação: 2024 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Poluentes Químicos da Água / Amarelo de Eosina-(YS) / Estruturas Metalorgânicas / Neonicotinoides Idioma: En Revista: Environ Sci Pollut Res Int Ano de publicação: 2024 Tipo de documento: Article