A comparative study of the effects of graphite, wollastonite, and titanium dioxide fillers on the properties of starch-based biodegradable plastic film.

ABSTRACT

This research paper aims to explore the effect of graphite, wollastonite, and titanium dioxide as reinforcing fillers on starch-based biodegradable plastic (SBP) films. GF-SBP (graphite filler containing SBP), WF-SBP (wollastonite containing SBP), and TF-SBP (titanium dioxide containing SBP) films were developed and analyzed for various properties such as thickness, density, tensile strength, elongation break, morphology, thermal stability, solubility, moisture content, moisture absorbance, biodegradability, and antibacterial activity. The results reveal that WF-SBP films had the highest tensile strength of 5.43 MPa and greatest elongation break value of 22% as compared to other films. Thermogravimetric analysis showed that SBP films with and without filler degraded slowly between 150 and 600°C. The highest thermal stability was recorded for TF-SBP films which showed stability (11% mass loss) up to 150°C. The biodegradability test conducted using soil burial method suggested that TF-SBP film degraded within 90 days, GF-SBP films degraded completely in 120 days, and WF-SBP films took more than 120 days to degrade. The synthesized SBP films were analyzed for their antibacterial potential against gram-positive and gram-negative bacteria, and results showed that WF-SBP film exhibited the best antibacterial activity by producing a large zone of inhibition against Escherichia coli.