The Limited Incorporation and Role of Fluorine in Mn-rich Disordered Rocksalt Cathodes.
ACS Energy Lett
; 9(6): 3027-3035, 2024 Jun 14.
Article
em En
| MEDLINE
| ID: mdl-38911531
ABSTRACT
Disordered rocksalt oxide (DRX) cathodes are promising candidates for next-generation Co- and Ni-free Li-ion batteries. While fluorine substitution for oxygen has been explored as an avenue to enhance their performance, the amount of fluorine incorporated into the DRX structure is particularly challenging to quantify and impedes our ability to relate fluorination to electrochemical performance. Herein, an experimental-computational method combining 7Li and 19F solid-state nuclear magnetic resonance, and ab initio cluster expansion Monte Carlo simulations, is developed to determine the composition of DRX oxyfluorides. Using this method, the synthesis of Mn- and Ti-containing DRX via standard high temperature sintering and microwave heating is optimized. Further, the upper fluorination limit attainable using each of these two synthesis routes is established for various Mn-rich DRX compounds. A comparison of their electrochemical performance reveals that the capacity and capacity retention mostly depend on the Mn content, while fluorination plays a secondary role.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
ACS Energy Lett
Ano de publicação:
2024
Tipo de documento:
Article