Hydrazido complexes prepared by methylation of an anionic end-on bridging dinitrogen dititanium complex.
Chem Commun (Camb)
; 60(58): 7459-7462, 2024 Jul 16.
Article
em En
| MEDLINE
| ID: mdl-38946396
ABSTRACT
Here we report stepwise methylation of end-on bridging dinitrogen to a hydrazido ligand to a pentamethylhydrazinium salt, which is mediated by a titanium system with a tripodal aryloxide supporting ligand. The results constitute a synthetic cycle for pentamethylhydrazinium formation from dinitrogen and methyl iodide. We also describe silylation of the dinitrogen complex and carboxylation of the hydrazido complex.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2024
Tipo de documento:
Article