Fabrication of high performance poly(vinyl alcohol)/straw composite film used for package via melt casting and biaxial stretching.

ABSTRACT

A high performance poly(vinyl alcohol)/straw (PVA/SP) composite film for package was fabricated in this study by using thermal processing technology of PVA established in our research group and biaxial stretching technology. The introduction of SP disrupted the original hydrogen bonds in modified PVA by forming new hydrogen bonds with the hydroxyl groups of each component in modified system, thus promoting the stable melt casting of PVA/SP composites and also endowing the obtained PVA/SP precursor sheets with good drawability. Upon biaxial stretching, SP reinforced the crystalline structure and orientation of PVA through their hydrogen bonds with PVA, improving the mechanical strength, crystallinity and thermal stability of PVA/SP films. The film with 3.0 × 3.0 stretching ratios demonstrated the exceptional tensile strength (62.2 MPa), tear strength (119.7 kN/m), low heat shrinkage (5.2 %), and oxygen permeability coefficient (1.38 × 10-16 cm3·cm/cm2·s·Pa), which surpassed most conventional plastic films used in food packaging field. This research not only pioneered an environmentally friendly packaging solution, but also offered a novel strategy for solid-state high-value, large-scale and economical utilization of waste crop straw, greatly avoiding the adverse effects of its burning on the environment.