High-order superlattices by rolling up van der Waals heterostructures.

Two-dimensional (2D) materials1,2 and the associated van der Waals (vdW) heterostructures3-7 have provided great flexibility for integrating distinct atomic layers beyond the traditional limits of lattice-matching requirements, through layer-by-layer mechanical restacking or sequential synthesis. However, the 2D vdW heterostructures explored so far have been usually limited to relatively simple heterostructures with a small number of blocks8-18. The preparation of high-order vdW superlattices with larger number of alternating units is exponentially more difficult, owing to the limited yield and material damage associated with each sequential restacking or synthesis step8-29. Here we report a straightforward approach to realizing high-order vdW superlattices by rolling up vdW heterostructures. We show that a capillary-force-driven rolling-up process can be used to delaminate synthetic SnS2/WSe2 vdW heterostructures from the growth substrate and produce SnS2/WSe2 roll-ups with alternating monolayers of WSe2 and SnS2, thus forming high-order SnS2/WSe2 vdW superlattices. The formation of these superlattices modulates the electronic band structure and the dimensionality, resulting in a transition of the transport characteristics from semiconducting to metallic, from 2D to one-dimensional (1D), with an angle-dependent linear magnetoresistance. This strategy can be extended to create diverse 2D/2D vdW superlattices, more complex 2D/2D/2D vdW superlattices, and beyond-2D materials, including three-dimensional (3D) thin-film materials and 1D nanowires, to generate mixed-dimensional vdW superlattices, such as 3D/2D, 3D/2D/2D, 1D/2D and 1D/3D/2D vdW superlattices. This study demonstrates a general approach to producing high-order vdW superlattices with widely variable material compositions, dimensions, chirality and topology, and defines a rich material platform for both fundamental studies and technological applications.

Bifunctional vanadium doped mesoporous Co3O4 on nickel foam towards highly efficient overall urea and water splitting in the alkaline electrolyte.

Developing more active and stable electrode materials for oxygen evolution reaction (OER) and urea oxidation reaction (UOR) is necessary for electrocatalytic water and urea oxidation which can be used to generate hydrogen. Here, a low-cost vanadium-doped mesoporous cobalt oxide on Ni foam (V/meso-Co/NF) electrodes are obtained via the grouping of an in-situ citric acid (CA)-assisted evaporation-induced self-assembly (EISA) method and electrophoretic deposition process, and work as highly efficient and long-lasting electrocatalytic materials for OER/UOR. In particular, V/meso-Co/NF electrodes require 329 mV overpotential to maintain a 50 mA/cm2, with exceptional long-term durability of 30 h. Interestingly, V/meso-Co/NF also exhibits excellent electrocatalytic UOR performance, reaching 50 and 100 mA/cm2 versus RHE at low potentials of 1.34 and 1.35 V, respectively. By employing the V/meso-Co/NF materials as both the anode and cathode, this urea electrolysis assembly V/meso-Co/NF-5 (+,-) reaches current densities of 100 mA cm-2 at 1.62 V in KOH/urea, which is nearly 340 mV lesser than classical water electrolysis. The V/meso-Co/NF-5 electrocatalysts also exhibit remarkable durability for electrocatalytic OERs and UORs. The obtained findings revealed that the synthesized V/meso-Co/NF might be a promising electrode materials for overall urea-rich wastewater management and H2 generation from wastewater.

A Simplified Numerical Approach to Examine the Sensitivity of Two-Electrode Capacitance Sensor Orientation to Capture Different Gas-Liquid Flow Patterns in a Small Circular Pipe.

This work involved the simulation of both a multiphase gas-liquid flow and the electromagnetic field representing a two-electrode capacitance sensor in a circular pipe. The simulation investigates in particular the sensitivity of the sensor orientation around the pipe (i.e., top-to-bottom or side-to-side) that best capture the induced flow patterns. The presented numerical work is a simplified simulation by COMSOL multi-physics which was validated by a systematic and an extensive experimental work, using (a) a specially designed simple capacitance sensor (i.e., concave two electrodes), (b) different gas-liquid superficial velocity combinations, (c) different flow section inclinations, and (d) high-speed camera images. The numerical modelling capacitance values were validated against the experimentally measured values which shows a satisfactory level of agreement with a deviation of less than ±2%. The quantity of finite points was between 280,000 and 340,000, which was influenced by the simulated flow pattern. The simulated cases captured the generated flow patterns and their variation inside the pipe, which was in a good agreement when compared to the experimental work as time-dependent values. It was found that the best orientation for the utilized two-electrode capacitance sensor was the top-to-bottom configuration. This is because the sensor's electrical field distribution was more sensitive, and capable of detecting a greater range of capacitance values. The sensitivity of the top-to-bottom configuration was 1.25-1.64 times greater than that of the side-to-side configuration. Therefore, for design purposes and performance optimization, it is recommended to use the top-to-bottom configuration.

The Effect of Femtosecond Laser Surface Patterns on the Effectiveness of Resin Composite to Zirconia Bonding.

This laboratory study aimed to evaluate the effect of different surface patterns using femtosecond laser treatment on the enclosed mold shear bond strength (EM-SBS) of resin composite to zirconia (ZrO2) surfaces and to contrast it with the widely used tribochemical silica coating (TBC) surface conditioning method. A set of fifteen rectangular ZrO2 blocks were randomly divided into five groups according to surface pretreatment: Control G0-no treatment; G1-TBC with silane application; G2-femtosecond laser irradiation with horizontal lines 30 µm apart; G3-femtosecond laser irradiation with horizontal lines 15 µm apart; and G4-femtosecond laser irradiation with cross lines 30 µm apart. The pretreated surfaces were characterized by a surface profilometer, tensiometer and scanning electron microscope. The EM-SBS of resin composite stubs to ZrO2 was measured followed by fractographic analysis. The surface roughness and water contact angle were observed to be statistically higher among the femtosecond laser groups compared to the TBC and control groups. The G4 group exhibited the highest EM-SBS among all the groups, irrespective of the ageing conditions used. At the end of 5000 thermocycles, G4 exhibited EM-SBS of 14.05 ± 4.21 MPa compared to 13.80 ± 3.01 MPa in G1 and 5.47 ± 0.97 MPa in G0. The two-way ANOVA revealed a significant effect of both study groups and ageing conditions on the EM-SBS (p < 0.001). Utilization of femtosecond laser technology holds promise as a potential and alternative mechanical retention approach for enhancing the bonding strength of the resin composite to ZrO2.

Characterization of Low-Cost Particulates Used as Energy Storage and Heat-Transfer Medium in Concentrated Solar Power Systems.

Utilizing solid particles as a heat-transfer medium in concentrated solar power applications has gained growing attention lately. Unlike molten salts, solid particles offer many benefits, which include: high operating temperatures (greater than 1000 °C), a lack of freezing issues and corrosivity, abundant availability, high thermal energy storage capacity, a low cost, and applicability in direct irradiation. Comprehensive knowledge of thermophysical and optical properties of solid particles is essential to ensure an effective harnessing of solar energy. The most important considerations when selecting solid particles include: thermophysical and optical properties, thermal resistance, crack resistance, satisfactory health and safety risks, availability, and low cost. It is also imperative to consider optical and thermophysical characteristics that might change from what they were "as received" after cyclic heating for a long period. Therefore, the knowledge of thermal performance of particulate materials becomes significant before using them as a heat-transfer medium. In this study, some particulate materials were chosen to study their feasibilities as heat-transfer and storage media for a particle-based central receiver tower system. These particulate materials included white sand, red sand, ilmenite, and Carbobead CP. The candidate particulate materials were heated at high temperatures for 6 h and then cooled to room temperature. After that, cyclic heating was performed on the particulate materials for 500 h at 1200 °C. The optical properties were represented by weighted solar absorptance, and the thermophysical properties of the particulates were measured "as received" and after cyclic heating (aging). EDX and XRD were conducted to quantify the chemical composition and interpret the changes in appearance associated with the particulate materials after cyclic heating. The results showed a considerable agglomeration in all particulates except for white sand in the 6 h heating test, and high agglomeration in the ilmenite. A slight decrease in the optical properties in the white sand and Carbobead CP was found after the aging test. The specific heat was decreased for red and white sand. The EDX and XRD results for white sand and Carbobead CP showed chemical stability, indicating high durability and reliability.

Photobleaching absorbed Rhodamine B to improve temperature measurements in PDMS microchannels.

Rhodamine B based fluorescence thermometry is commonly used in microfluidics to measure fluid temperatures in microchannels. Notable absorption of Rhodamine B into PDMS channel walls, however, causes difficulties in obtaining accurate temperature measurements due to a steady increase in the overall fluorescent signal. A simple and effective technique is reported that removes the fluorescent signal from absorbed Rhodamine B dye by means of photobleaching with a high intensity light source before taking images for thermometry analysis. The temperature field at the convergence of hot and cold streams in a Y-channel fabricated in PDMS/glass microfluidic chip is studied to demonstrate the execution of the photobleaching technique.

Characterization of natural fiber obtained from different parts of date palm tree (Phoenix dactylifera L.).

The current study is motivated by the strict environmental regulations regarding the utilization and consumption of ecofriendly materials. In this context, the aim of this study has been to prepare and characterize different date palm tree (Phoenix dactylifera L.) fibers processed through the conventional water retting method. The chemical, elemental, crystallinity, thermal and morphological characterization of trunk (DPTRF), leaf stalk (DPLST), sheath or leaf sheath (DPLSH) and fruit bunch stalk (DPFBS) fibers was carried out. Chemical analysis revealed that the four types of date palm fibers display noteworthy differences in the content of cellulose, hemicellulose and lignin. Also, the amount of calcium is relatively high in all the date palm fibers; besides this, DPTRF exhibited 69.2% crystallinity, which is lower than that of DPLSH with 72.4% crystallinity. Moreover, DPLST and DPFBS fibers are more thermally stable (higher thermal degradation temperature) than DPTRF and DPLSH samples. Morphological analysis revealed that the fracture surface of DPFBS was relatively rougher, which would probably lead to increased bonding strength with polymers in composites. Overall, we conclude that DPFBS would be promising alternative sustainable and biomass material for the isolation of respective cellulose nanofibers and cellulose nanocrystals as potential reinforcement in polymer composites.