1.
J Org Chem
; 84(12): 8112-8120, 2019 06 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-31117580
RESUMO
In the presence of ( S,S)-Trost ligand and (allyl-Pd-Cl)2 catalyst, the reaction of allyl acetate with the anionic species prepared from various N-(2- tert-butylphenyl)sulfonamides and NaH proceeded in an enantioselective manner (up to 95% ee) to give optically active N-allylated sulfonamide derivatives possessing an N-C axially chiral structure in high yields.