1.
Chem Commun (Camb)
; 54(27): 3399-3402, 2018 Mar 29.
Artigo
em Inglês
| MEDLINE
| ID: mdl-29557452
RESUMO
The addition of nucleophilic imines, using 2-hydroxybenzophenone as a chemical auxiliary, is presented. An intramolecular six-membered ring via hydrogen bonding that enhances the reactivity and selectivity is the key of this strategy, which is supported by DFT calculations and experimental trials.
2.
Chem Commun (Camb)
; 53(55): 7764-7767, 2017 Jul 06.
Artigo
em Inglês
| MEDLINE
| ID: mdl-28650038
RESUMO
In this communication, a new photocatalytic strategy for the addition of alkyl-radical derivatives to N-sulfinimines with complete diastereoselectivity and moderate to good yields is presented. This is the first asymmetric photocatalytic addition to N-sulfinimines under visible light irradiation with smooth conditions and functional group tolerance.