RESUMO
An understanding on roles of excitons and plasmons is important in excitonic solar cells and photovoltaic (PV) technologies. Here, we produce new amorphous carbon (a-C) like films on Indium Tin Oxide (ITO) generating PV cells with efficiency three order of magnitude higher than the existing biomass-derived a-C. The amorphous carbon films are prepared from the bioproduct of palmyra sap with a simple, environmentally friendly, and highly reproducible method. Using spectroscopic ellipsometry, we measure simultaneously complex dielectric function, loss function as well as reflectivity and reveal coexistence of many-body resonant excitons and correlated-plasmons occurring due to strong electronic correlations. X-ray absorption and photoemission spectroscopies show the nature of electron and hole in defining the energy of the excitons and plasmons as a function of N or B doping. Our result shows new a-C like films and the importance of the coupling of resonant excitons and correlated plasmons in determining efficiency of photovoltaic devices.
RESUMO
Phase-sensitive order parameter symmetry test experiments are presented on the electron-doped high-T(c) cuprate Nd(2-x)Ce(x)CuO(4-y). These experiments have been conducted using zigzag-shaped thin film Josephson structures, in which the Nd(2-x)Ce(x)CuO(4-y) is connected to the low-T(c) superconductor Nb via an Au barrier layer. For the optimally doped as well as for the overdoped Nd(2-x)Ce(x)CuO(4-y), a clear predominant d(x2-y2)-wave behavior is observed at T=4.2 K. Both compounds were also investigated at T=1.6 K, presenting no indications for a change to a predominant s-wave symmetry with decreasing temperature.