Fluorescent silicon nanoparticle-based quantitative hemin assay.

Hemin with functions such as oxygen carrying, oxygen storing, promoting redox, and performing electron transfer is important for the health of organisms. In this paper, green synthetic silicon nanoparticles (Si-NPs) were synthesized and used for free hemin detection in serum (a low limit of detection (LOD), 29.5 nM). The quenching mechanism was investigated by UV-vis absorption spectra, time-resolved luminescence decay curve, and circular dichroism (CD) spectra. It was confirmed that multiple redox centers of hemin led to intensified effective collision and increased the electron transfer rate, therefore enhancing the dynamic quenching, and it was undeniable that the inner filter effect (IFE) also played a role in the quenching.

Silane-Functionalized Carbon Dots and Their Polymerized Hybrids: From Optoelectronics to Biotherapy.

Nanomaterials usually manifest unique properties in solutions but will be undermined in the solid state. It is necessary to incorporate them into substrates or hybrid them with other functional materials for multiple devices and applications. Though there are a variety of methods to inherit their intrinsic properties like fluorescent and mechanical performance, most nanohybrid materials would lose their transparency irreversibly when construct solid-state devices. As a hot topic of nanomaterials in recent years, scientific works found a type of carbon dots using silane coupling agents as precursors that can overcome the shortcoming. These carbon dots, called silane-functionalized carbon dots (SiCDs), are catching increasing interest due to their versatility. Silane coupling agents endow SiCDs with the ability to disperse in solvents or polymerize with matrices by blending or covalent bonds without loss of transparency and decline of performance. The distinguishing features make SiCDs an ideal high transmittance, high doping concentration nanomaterial. The synergistic effect of SiCDs and hybridized sol-gel solid structures can not only hold the optical features of CDs but also enhance their original physical and chemical performance. This highlight focuses on the connection between SiCDs and organosilanes. Plus, preparation methods, applications, and prospective of SiCDs are mentioned.

Liquid and solid-state tunable fluorescent carbon dots for trace water detection.

We synthesized a type of sulfur and nitrogen co-doped carbon dot, which can achieve tunable fluorescence both in solutions and solid matrices, that is dominated by the surface state. Moreover, it can be used to detect trace water in a variety of organic solvents, especially in acetone with a limit of detection as low as 0.042%.

Defects and Structural Limitation-Induced Carbon Dots-Silica Hybrid Materials with Ultralong Room Temperature Phosphorescence.

Carbon dots-based room temperature phosphorescent (RTP) materials have attracted widespread attention owing to their excellent optical properties. However, there still is a challenge to fabricate carbon dots-based materials simultaneously showing long RTP lifetime and high phosphorescent quantum yield. Herein, we have designed a kind of carbon dots-silica hybrid material that can produce RTP emission with ultralong lifetime and also high phosphorescent quantum yield (1.3 s and 11.22%). Both chemical and optical analytical characterizations indicate the source of the outstanding RTP performance as the synergistic strategy of abundant electron traps, highly rigid network, and stable covalent bond. The findings provide a new design idea to achieve novel carbon dots-based RTP materials, showing broad application prospects in optical anticounterfeiting, optoelectronics, and others.

Fluorescence Emission of Polyethylenimine-Derived Polymer Dots and Its Application to Detect Copper and Hypochlorite Ions.

Polymer dots with nonconjugated groups that are facile to synthesize and environmentally friendly generally attract substantial interest. However, their fluorescence-emitting mechanisms are not clear. In this paper, nonconjugated polymer dots (N-PDs) are synthesized by amidation reaction between polyethylenimine (PEI) and citric acid (CA), then self-assemble into rice-like dots in aqueous phase with a high fluorescence quantum yield. Such nitrogen-containing nonconjugated compounds N-PDs are believed to be inherently fluorescent, and the reported reasons for fluorescence-emitting are discussed. Importantly, these N-PDs can be used as an excellent fluorescent probe to detect Cu2+ and ClO- in aqueous solutions. Cu2+ could combine with the PEI moiety of the N-PDs to form a copper amine complex and then quench the fluorescence by an internal filtration effect. ClO- could oxidize the hydroxyl groups on the surface of the N-PDs to form a positive charge, blocking electron transfer between the hydroxyl groups and the chromophore groups. Finally, the sensor was successfully applied to the detection of Cu2+ and ClO- in environmental water samples.