Measurement of pore volume, connectivity and clogging of pervious concrete reactive barrier used to treat acid mine drainage.

It has recently been shown that pervious concrete is a promising, effective technology as a permeable reactive barrier system for treatment of acid mine drainage (AMD). However, pore clogging also occurs simultaneously during AMD treatment. In the present study, mixtures of pervious concrete were made and used in a column experiment during which pore clogging occurred in the samples. Pore volume, connectivity and other parameters of pervious concrete were evaluated using five (5) different methods comprising the volumetric method (VM), linear-traverse method (LTM), image analysis (IA), falling head permeability test and X-ray microcomputed tomography. It was found that pervious concrete effectively removed from AMD, about 90 to 99% of various heavy metals including Al, Fe, Zn, Mn and Mg. Cr concentration significantly increased in the treated effluent, owing to leaching from cementitious materials used in mixtures. The VM and LTM gave statistically similar pore volume results, while IA's values were 20 to 30% higher than those of the conventional methods. The falling head permeability test and IA were found to be effective in quantifying pore clogging effects. Pervious concrete exhibited high pore connectivity of 95.0 to 99.7%, which underlies its efficacious hydraulic conductivity.

Pervious concrete reactive barrier for removal of heavy metals from acid mine drainage - column study.

This paper presents a column study conducted to investigate the potential use of pervious concrete as a reactive barrier for treatment of water impacted by mine waste. The study was done using acid mine drainage (AMD) collected from a gold mine (WZ) and a coalfield (TDB). Pervious concrete mixtures consisting of Portland cement CEM I 52.5R with or without 30% fly ash (FA) were prepared at a water-cementitious ratio of 0.27 then used to make cubes which were employed in the reactor columns. It was found that the removal efficiency levels of Al, Fe, Mn, Co and Ni were 75%, 98%, 99%, 94% and 95% for WZ; 87%, 96%, 99%, 98% and 90% for TDB, respectively. The high rate of acid reduction and metal removal by pervious concrete is attributed to dissolution of portlandite which is a typical constituent of concrete. The dominant reaction product in all four columns was gypsum, which also contributed to some removal of sulphate from AMD. Formation of gypsum, goethite, and Glauber's salt were identified. Precipitation of metal hydroxides seems to be the dominant metal removal mechanism. Use of pervious concrete offers a promising alternative treatment method for polluted or acidic mine water.