1.
Chem Commun (Camb)
; 59(85): 12727-12730, 2023 Oct 24.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37800404
RESUMO
A library of cyclometallated iridium(III) complexes with a strong H-bonding motif in their ancillary ligand was synthesized, characterized and their photophysical properties measured. Demonstrated herein is a general synthetic high yield procedure for these compounds. We ascribe these yields to the use of an intermediary primer ligand. This de novo strategy circumnavigates the standard synthetic issues of H-bond rich ligand precursors (self-aggregation and poor solubility in organic solvents).