Stability Analysis of Shear Deformable Inhomogeneous Nanocomposite Cylindrical Shells under Hydrostatic Pressure in Thermal Environment.

In this study, the stability of inhomogeneous nanocomposite cylindrical shells (INCCSs) under hydrostatic pressure in a thermal environment is presented. The effective material properties of the inhomogeneous nanocomposite cylindrical shell are modeled on the basis of the extended mixture rule. Based on the effective material properties, the fundamental relations and stability equations are derived for thermal environments. In this process, the first-order shear deformation theory (FSDT) for the homogeneous orthotropic shell is generalized to the inhomogeneous shell theory. This is accomplished using the modified Donnell-type shell theory. The analytical expressions are obtained for hydrostatic buckling pressure of INCCSs in the framework of FSDT and classical shell theory (CST) by obtaining a solution based on Galerkin's procedure. The numerical examples presented include both comparisons and original results. The last section shows the influences of carbon nanotube (CNT) models, volume fraction, and shell characteristics on the hydrostatic buckling pressure in the thermal environment.

A Study on the Effect of Doping Metallic Nanoparticles on Fracture Properties of Polylactic Acid Nanofibres via Molecular Dynamics Simulation.

All-atom molecular dynamics simulations are conducted to elucidate the fracture mechanism of polylactic acid nanofibres doped with metallic nanoparticles. Extensional deformation is applied on polymer nanofibres decorated with spherical silver nanoparticles on the surface layer. In the obtained stress-strain curve, the elastic, yield, strain softening and fracture regions are recognized, where mechanical parameters are evaluated by tracking the stress, strain energy and geometrical evolutions. The energy release rate during crack propagation, which is a crucial factor in fracture mechanics, is calculated. The results show that the presence of doping nanoparticles improves the fracture properties of the polymer nanofibre consistently with experimental observation. The nanoparticles bind together polymer chains on the surface layer, which hinders crack initiation and propagation. The effect of the distribution of nanoparticles is studied through different doping decorations. Additionally, a discussion on the variation of internal energy components during uniaxial tensile loading is provided to unravel the deformation mechanism of nanoparticle-doped nanofibres.

Buckling Behavior of Sandwich Cylindrical Shells Covered by Functionally Graded Coatings with Clamped Boundary Conditions under Hydrostatic Pressure.

The buckling behavior of sandwich shells with functionally graded (FG) coatings operating under different external pressures was generally investigated under simply supported boundary conditions. Since it is very difficult to determine the approximation functions satisfying clamped boundary conditions and to solve the basic equations analytically within the framework of first order shear deformation theory (FOST), the number of publications on this subject is very limited. An analytical solution to the buckling problem of FG-coated cylindrical shells under clamped boundary conditions subjected to uniform hydrostatic pressure within the FOST framework is presented for the first time. By mathematical modeling of the FG coatings, the constitutive relations and basic equations of sandwich cylindrical shells within the FOST framework are obtained. Analytical solutions of the basic equations in the framework of the Donnell shell theory, obtained using the Galerkin method, is carried out using new approximation functions that satisfy clamped boundary conditions. Finally, the influences of FG models and volume fractions on the hydrostatic buckling pressure within the FOST and classical shell theory (CT) frameworks are investigated in detail.

On the Solution of Thermal Buckling Problem of Moderately Thick Laminated Conical Shells Containing Carbon Nanotube Originating Layers.

This study presents the solution for the thermal buckling problem of moderately thick laminated conical shells consisting of carbon nanotube (CNT) originating layers. It is assumed that the laminated truncated-conical shell is subjected to uniform temperature rise. The Donnell-type shell theory is used to derive the governing equations, and the Galerkin method is used to find the expression for the buckling temperature in the framework of shear deformation theories (STs). Different transverse shear stress functions, such as the parabolic transverse shear stress (Par-TSS), cosine-hyperbolic shear stress (Cos-Hyp-TSS), and uniform shear stress (U-TSS) functions are used in the analysis part. After validation of the formulation with respect to the existing literature, several parametric studies are carried out to investigate the influences of CNT patterns, number and arrangement of the layers on the uniform buckling temperature (UBT) using various transverse shear stress functions, and classical shell theory (CT).

Dynamic Characterization of Hexagonal Microstructured Materials with Voids from Discrete and Continuum Models.

The mechanical response of materials such as fiber and particle composites, rocks, concrete, and granular materials, can be profoundly influenced by the existence of voids. The aim of the present work is to study the dynamic behavior of hexagonal microstructured composites with voids by using a discrete model and homogenizing materials, such as micropolar and classical Cauchy continua. Three kinds of hexagonal microstructures, named regular, hourglass, and skew, are considered with different length scales. The analysis of free vibration of a panel described as a discrete system, as a classical and as a micropolar continuum, and the comparison of results in terms of natural frequencies and modes show the advantage of the micropolar continuum in describing dynamic characteristics of orthotropic composites (i.e., regular and hourglass microstructures) with respect to the Cauchy continuum, which gives a higher error in frequency evaluations for all three hexagonal microstructured materials. Moreover, the micropolar model also satisfactorily predicts the behavior of skewed microstructured composites. Another advantage shown here by the micropolar continuum is that, like the discrete model, this continuum is able to present the scale effect of microstructures, while maintaining all the advantages of the field description. The effect of void size is also investigated and the results show that the first six frequencies of the current problem decrease by increasing in void size.

Evaluating the X-ray-Shielding Performance of Graphene-Oxide-Coated Nanocomposite Fabric.

Exposure to ionizing radiation (IR) during diagnostic medical procedures brings certain risks, especially when experiencing recurrent exposures. The fabrication of nano-based composites, doped with different nanoparticles, have been suggested as effective shielding materials to replace conventional lead-based ones in material sciences and nanotechnology. In this study, commercially available fabrics, used to produce scrubs and gowns for clinical staff, are modified utilizing graphene oxide (GO) nanoparticles using a layer-by-layer (LBL) technique. GO was obtained from graphite through environmentally friendly technology by using a modified-improved Hummers' method without NaNO3. Lightweight, flexible, air- and water-permeable shielding materials are produced that are wearable in all-day clinical practice. The nanoparticles are kept to a minimum at 1 wt%; however, utilizing the LBL technique they are distributed evenly along the fibers of the fabrics to achieve as much shielding effect as possible. The evaluation of samples is accomplished by simulating real-time routine clinical procedures and the radiographic programs and devices used daily. The GO-coated nanocomposite fabrics demonstrated promising results for X-ray shielding.

The Effect of Different Morphologies of WO3/GO Nanocomposite on Photocatalytic Performance.

Tungsten trioxide/graphene oxide (WO3/GO) nanocomposites have been successfully synthesized using in situ and ex situ chemical approaches. Graphite and tungsten carbide (WC) were employed to perform in situ synthesis, and WO3 and GO were employed to perform the ex situ synthesis of WO3/GO nanocomposites. GO, which was required for ex situ synthesis, is synthesized via the modified and improved Hummers method. XRD, SEM/EDS, and FTIR are used for the characterization of the nanocomposite. From the XRD of the WO3/GO nanocomposites, it was observed that WO3 distributed uniformly on graphene oxide sheets or was incorporated between the sheets. The photocatalytic activities of WO3/GO nanocomposites were evaluated by methylene blue (MB) adsorption and visible light photocatalytic degradation activities by UV-vis spectroscopy. The results showed that the efficiency of the photocatalytic activity of the nanocomposite depends on different synthesis methods and the morphology resulting from the changed method. WO3/GO nanocomposites synthesized by both methods exhibited much higher photocatalytic efficiencies than pure WO3, and the best degradation efficiencies for MB was 96.30% for the WO3/GO in situ synthesis nanocomposite.

Stress Field Evaluation in Orthotropic Microstructured Composites with Holes as Cosserat Continuum.

It is known that the presence of microstructures in solids such as joints and interfaces has an essential influence on the studies of the development of advanced materials, rock mechanics, civil engineering, and so on. However, microstructures are often neglected in the classical local (Cauchy) continuum model, resulting in inaccurate descriptions of the behavior of microstructured materials. In this work, in order to show the impact of microstructures, an implicit 'non-local' model, i.e., micropolar continuum (Cosserat), is used to numerically investigate the effects of direction and scale of microstructures on the tension problem of a composite plate with a circular hole. The results show that distributions of field variables (such as displacements and stresses) have an obvious directionality with respect to the microstructures' direction. As the scale of microstructures increases, such a direction effect becomes more evident. Unlike the isotropic material where stress concentration occurs at the vertex of the hole and the stress concentration factor is close to 3, for the microstructured composite, the stress concentration can be observed at any location depending on the microstructures' directions, and the concentration factor can exceed 3 to a maximum close to 9 as the increasing scale of microstructures. In addition, differences in the mechanical behavior between Cosserat and Cauchy models can be also observed; such differences are more evident for the material showing a pronounced orthotropic nature.

Sustainable and Ecofriendly Chemical Design of High Performance Bio-Based Thermosets for Advanced Applications.

High performance thermosetting resins are targeted in many exigent applications, such as aerospace and marine fields, for the development of lightweight structural composites. Till now, these industries only rely on petroleum-based materials for their supposedly better performances. However, the latest developments in the field suggest otherwise. In fact, many reports confirmed that sustainable and ecofriendly thermosetting polymers can display similar or even better performances. Additionally, exploring alternative renewable feedstock's to meet the ever increasing demands of these industries is an essential step towards sustainable development. Aiming to unravel the potential of these materials, the present review summarizes the most relevant chemical routes allowing the preparation of fully or partially bio-based thermosetting resins. Meanwhile, the overall performances of these exceptional materials are also compared with their petroleum-based counterparts.

Dynamic Characterization of Microstructured Materials Made of Hexagonal-Shape Particles with Elastic Interfaces.

This work aims to present the dynamic character of microstructured materials made of hexagonal-shape particles interacting with elastic interfaces. Several hexagonal shapes are analyzed to underline the different constitutive behavior of each texture. The mechanical behavior at the macro scale is analyzed by considering a discrete model assumed as a benchmark of the problem and it is compared to a homogenized micropolar model as well as a classical one. The advantages of the micropolar description with respect to the classical one are highlighted when internal lengths and anisotropies of microstuctured materials are taken into consideration. Comparisons are presented in terms of natural frequencies and modes of vibrations.

Time-History Analysis of Composite Materials with Rectangular Microstructure under Shear Actions.

It has been demonstrated that materials with microstructure, such as particle composites, show a peculiar mechanical behavior when discontinuities and heterogeneities are present. The use of non-local theories to solve this challenge, while preserving memory of the microstructure, particularly of internal length, is a challenging option. In the present work, composite materials made of rectangular rigid blocks and elastic interfaces are studied using a Cosserat formulation. Such materials are subjected to dynamic shear loads. For anisotropic media, the relative rotation between the local rigid rotation and the microrotation, which corresponds to the skewsymmetric part of strain, is crucial. The benefits of micropolar modeling are demonstrated, particularly for two orthotropic textures of different sizes.

Critical Temperatures for Vibrations and Buckling of Magneto-Electro-Elastic Nonlocal Strain Gradient Plates.

An analytical method is presented in this work for the linear vibrations and buckling of nano-plates in a hygro-thermal environment. Nonlinear von Kármán terms are included in the plate kinematics in order to consider the instability phenomena. Strain gradient nonlocal theory is considered for its simplicity and applicability with respect to other nonlocal formulations which require more parameters in their analysis. Present nano-plates have a coupled magneto-electro-elastic constitutive equation in a hygro-thermal environment. Nano-scale effects on the vibrations and buckling behavior of magneto-electro-elastic plates is presented and hygro-thermal load outcomes are considered as well. In addition, critical temperatures for vibrations and buckling problems are analyzed and given for several nano-plate configurations.

Modeling and Solution of Large Amplitude Vibration Problem of Construction Elements Made of Nanocomposites Using Shear Deformation Theory.

The main purpose of the study is to investigate the vibration behaviors of carbon nanotube (CNT) patterned double-curved construction elements using the shear deformation theory (SDT). After the visual and mathematical models of CNT patterned double-curved construction elements are created, the large amplitude stress-strain relationships and basic dynamic equations are derived using the first order shear deformation theory (FSDT). Then, using the Galerkin method, the problem is reduced to the nonlinear vibration of nanocomposite continuous systems with quadratic and cubic nonlinearities. Applying the Grigolyuk method to the obtained nonlinear differential equation, large-amplitude frequency-amplitude dependence is obtained. The expressions for nonlinear frequencies of homogenous and inhomogeneous nanocomposite construction members such as plates, panels, spherical and hyperbolic-paraboloid (hypar) shells in the framework of FSDT are found in special cases. The accuracy of the results of the current study has been confirmed by comparing them with the reliable results reported in the literature. Original analyses are carried out to examine the effects of nonlinearity, CNT patterns and volume fraction changes on frequencies in the framework of shear deformation and classical shell theories.

Influences of Elastic Foundations and Material Gradient on the Dynamic Response of Polymer Cylindrical Pipes Patterned by Carbon Nanotube Subjected to Moving Pressures.

Composite materials are frequently used in the construction of rail, tunnels, and pipelines as well as in the construction of aircraft, ships, and chemical pipelines. When such structural elements are formed from new-generation composites, such as CNT-reinforced composites, and their interaction with the ground, there is a need to renew the dynamic response calculations under moving pressures and to create new mathematical solution methods during their design. The aim of this study was to analyze the influences of elastic foundations (EFs) and material gradient on the dynamic response of infinitely long carbon nanotube (CNT)-based polymer pipes under combined static and moving pressures. The CNT-based polymer pipes resting on the EFs were exposed to the axial and moving pressures. The uniform and heterogeneous reinforcement distributions of CNTs, which varied linearly throughout the thickness of polymer pipes, were considered. After setting the problem, the fundamental equations derived to find new analytical expressions for dynamic coefficients and critical velocity, which are dynamic characteristics of cylindrical pipes reinforced by the uniform and linear distributions of CNTs, were solved in the framework of the vibration theory. Finally, numerical computations were performed to examine the effects of EFs on the critical parameters depending on the characteristics of the pipes, the speed of moving pressures, the shape of the distribution of CNTs, and the change in volume fractions.

Homogenization and Equivalent Beam Model for Fiber-Reinforced Tubular Profiles.

The current work presents a study on hollow cylinder composite beams, since hollow cylinder cross-sections are one of the principal geometry in many engineering fields. In particular, the present study considers the use of these profiles for scaffold design in offshore engineering. Composite beams cannot be treated as isotropic ones due to couplings mainly present among traction, torsion, bending and shear coefficients. This research aims to present a simple approach to study composite beams as they behave like isotropic ones by removing most complexities related to composite material design (e.g., avoid the use of 2D and 3D finite element modeling). The work aims to obtain the stiffness matrix of the equivalent beam through an analytical approach which is valid for most of the laminated composite configurations present in engineering applications. The 3D Euler-Bernoulli beam theory is considered for obtaining the correspondent isotropic elastic coefficients. The outcomes show that negligible errors occur for some equivalent composite configurations by allowing designers to continue using commercial finite element codes that implement the classical isotropic beam model.

Failure Analysis of Ultra High-Performance Fiber-Reinforced Concrete Structures Enhanced with Nanomaterials by Using a Diffuse Cohesive Interface Approach.

Recent progresses in nanotechnology have clearly shown that the incorporation of nanomaterials within concrete elements leads to a sensible increase in strength and toughness, especially if used in combination with randomly distributed short fiber reinforcements, as for ultra high-performance fiber-reinforced concrete (UHPFRC). Current damage models often are not able to accurately predict the development of diffuse micro/macro-crack patterns which are typical for such concrete structures. In this work, a diffuse cohesive interface approach is proposed to predict the structural response of UHPFRC structures enhanced with embedded nanomaterials. According to this approach, all the internal mesh boundaries are regarded as potential crack segments, modeled as cohesive interfaces equipped with a mixed-mode traction-separation law suitably calibrated to account for the toughening effect of nano-reinforcements. The proposed fracture model has been firstly validated by comparing the failure simulation results of UHPFRC specimens containing different fractions of graphite nanoplatelets with the available experimental data. Subsequently, such a model, combined with an embedded truss model to simulate the concrete/steel rebars interaction, has been used for predicting the load-carrying capacity of steel bar-reinforced UHPFRC elements enhanced with nanoplatelets. The numerical outcomes have shown the reliability of the proposed model, also highlighting the role of the nano-reinforcement in the crack width control.

Scale Effects in Orthotropic Composite Assemblies as Micropolar Continua: A Comparison between Weak- and Strong-Form Finite Element Solutions.

The aim of the present work was to investigate the mechanical behavior of orthotropic composites, such as masonry assemblies, subjected to localized loads described as micropolar materials. Micropolar models are known to be effective in modeling the actual behavior of microstructured solids in the presence of localized loads or geometrical discontinuities. This is due to the introduction of an additional degree of freedom (the micro-rotation) in the kinematic model, if compared to the classical continuum and the related strain and stress measures. In particular, it was shown in the literature that brick/block masonry can be satisfactorily modeled as a micropolar continuum, and here it is assumed as a reference orthotropic composite material. The in-plane elastic response of panels made of orthotropic arrangements of bricks of different sizes is analyzed herein. Numerical simulations are provided by comparing weak and strong finite element formulations. The scale effect is investigated, as well as the significant role played by the relative rotation, which is a peculiar strain measure of micropolar continua related to the non-symmetry of strain and work-conjugated stress. In particular, the anisotropic effects accounting for the micropolar moduli, related to the variation of microstructure internal sizes, are highlighted.

Investigation of the Flow Properties of CBM Based on Stochastic Fracture Network Modeling.

Coal contains a large number of fractures, whose characteristics are difficult to describe in detail, while their spatial distribution patterns may follow some macroscopic statistical laws. In this paper, several fracture geometric parameters (FGPs) were used to describe a fracture, and the coal seam was represented by a two-dimensional stochastic fracture network (SFN) which was generated and processed through a series of methods in MATLAB. Then, the processed SFN image was able to be imported into COMSOL Multiphysics and converted to a computational domain through the image function. In this way, the influences of different FGPs and their distribution patterns on the permeability of the coal seam were studied, and a finite element model to investigate gas flow properties in the coal seam was carried out. The results show that the permeability of the coal seam increased with the rising of fracture density, length, aperture, and with the decrease of the angle between the fracture orientation and the gas pressure gradient. It has also been found that large-sized fractures have a more significant contribution to coal reservoir permeability. Additionally, a numerical simulation of CBM extraction was carried out to show the potential of the proposed approach in the application of tackling practical engineering problems. According to the results, not only the connectivity of fractures but also variations of gas pressure and velocity can be displayed explicitly, which is consistent well with the actual situation.

Linear Static Behavior of Damaged Laminated Composite Plates and Shells.

A mathematical scheme is proposed here to model a damaged mechanical configuration for laminated and sandwich structures. In particular, two kinds of functions defined in the reference domain of plates and shells are introduced to weaken their mechanical properties in terms of engineering constants: a two-dimensional Gaussian function and an ellipse shaped function. By varying the geometric parameters of these distributions, several damaged configurations are analyzed and investigated through a set of parametric studies. The effect of a progressive damage is studied in terms of displacement profiles and through-the-thickness variations of stress, strain, and displacement components. To this end, a posteriori recovery procedure based on the three-dimensional equilibrium equations for shell structures in orthogonal curvilinear coordinates is introduced. The theoretical framework for the two-dimensional shell model is based on a unified formulation able to study and compare several Higher-order Shear Deformation Theories (HSDTs), including Murakami's function for the so-called zig-zag effect. Thus, various higher-order models are used and compared also to investigate the differences which can arise from the choice of the order of the kinematic expansion. Their ability to deal with several damaged configurations is analyzed as well. The paper can be placed also in the field of numerical analysis, since the solution to the static problem at issue is achieved by means of the Generalized Differential Quadrature (GDQ) method, whose accuracy and stability are proven by a set of convergence analyses and by the comparison with the results obtained through a commercial finite element software.