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1.
Soft Matter ; 19(33): 6298-6304, 2023 Aug 23.
Artigo em Inglês | MEDLINE | ID: mdl-37555339

RESUMO

As a two-phase system, foams are widely applied in the industry and exist ubiquitously in our daily lives. For this reason, studying them and investigating the parameters that affect their properties is crucial for the development of new and improved foam-based products. In this paper, we create 2D foam using an ordered fluid, the smectic liquid crystal (LC), and discuss the experimental parameters that affect their fabrication, including temperature and confining conditions. Then, we examine the influence of the injected airflow rate and drainage on their structure, size, liquid fraction, and stability. Finally, we compare their behavior to that of low-viscosity liquid foams and discuss the difference between them. Our findings indicate that surface tension is the dominant parameter in LC foam systems. Despite the strong elasticity of LCs, surface tension plays a crucial role in determining the properties of elastic foams. These results provide valuable insights that can be applied to different industrial applications. For instance, they may find relevance in the fields of cosmetics, thermal insulation, oil recovery, and sensing, where the fabrication of foams with high-viscosity fluids is required.

2.
Nanotechnology ; 34(36)2023 Jun 27.
Artigo em Inglês | MEDLINE | ID: mdl-37285825

RESUMO

We report structural and nonlinear optical properties of 20 nm gold (Au) nanoparticles (NPs) that are dispersed in planar degenerate (non-oriented) and planar oriented nematic liquid crystals (LCs) (4'-Pentyl-4-biphenylcarbonitrile-5CB). Taking advantage of elastic forces in the planar oriented nematic LC, we aligned AuNPs parallel to the 5CB director axis. In the case of planar degenerate, 5CB is not aligned and has no preferred orientation, forcing the AuNPs to disperse randomly. Results show that the linear optical absorption coefficient for the planar oriented 5CB/AuNPs mixture is larger than the corresponding planar degenerate sample. The nonlinear absorption coefficients are greatly enhanced in planar oriented samples at relatively high concentrations which can be attributed to plasmon coupling between the aligned AuNPs. This study demonstrates the utility of LCs for developing the assembly of NPs with enhanced optical properties which may offer important insight and technological advancement for novel applications, including photonic nanomaterials and optoelectronic devices.

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