A multicaloric cooling cycle that exploits thermal hysteresis.

The giant magnetocaloric effect, in which large thermal changes are induced in a material on the application of a magnetic field, can be used for refrigeration applications, such as the cooling of systems from a small to a relatively large scale. However, commercial uptake is limited. We propose an approach to magnetic cooling that rejects the conventional idea that the hysteresis inherent in magnetostructural phase-change materials must be minimized to maximize the reversible magnetocaloric effect. Instead, we introduce a second stimulus, uniaxial stress, so that we can exploit the hysteresis. This allows us to lock-in the ferromagnetic phase as the magnetizing field is removed, which drastically removes the volume of the magnetic field source and so reduces the amount of expensive Nd-Fe-B permanent magnets needed for a magnetic refrigerator. In addition, the mass ratio between the magnetocaloric material and the permanent magnet can be increased, which allows scaling of the cooling power of a device simply by increasing the refrigerant body. The technical feasibility of this hysteresis-positive approach is demonstrated using Ni-Mn-In Heusler alloys. Our study could lead to an enhanced usage of the giant magnetocaloric effect in commercial applications.

Giant magnetocaloric effect driven by structural transitions.

Magnetic cooling could be a radically different energy solution substituting conventional vapour compression refrigeration in the future. For the largest cooling effects of most potential refrigerants we need to fully exploit the different degrees of freedom such as magnetism and crystal structure. We report now for Heusler-type Ni­Mn­In­(Co) magnetic shape-memory alloys, the adiabatic temperature change ΔT(ad) = −3.6 to −6.2 K under a moderate field of 2 T. Here it is the structural transition that plays the dominant role towards the net cooling effect. A phenomenological model is established that reveals the parameters essential for such a large ΔT(ad). We also demonstrate that obstacles to the application of Heusler alloys, namely the usually large hysteresis and limited operating temperature window, can be overcome by using the multi-response to different external stimuli and/or fine-tuning the lattice parameters, and by stacking a series of alloys with tailored magnetostructural transitions.

Magnetic Refrigeration with Recycled Permanent Magnets and Free Rare-Earth Magnetocaloric La-Fe-Si.

Magnetic refrigeration is an upcoming technology that could be an alternative to the more than 100-year-old conventional gas-vapor compression cooling. Magnetic refrigeration might answer some of the global challenges linked with the increasing demands for readily available cooling in almost every region of the world and the global-warming potential of conventional refrigerants. Important issues to be solved are, for example, the required mass and the ecological footprint of the rare-earth permanent magnets and the magnetocaloric material, which are key parts of the magnetic cooling device. The majority of existing demonstrators use Nd-Fe-B permanent magnets, which account for more than 50% of the ecological footprint, and Gd, which is a critical raw material. This work shows a solution to these problems by demonstrating the world's first magnetocaloric demonstrator that uses recycled Nd-Fe-B magnets as the magnetic field source, and, as a Gd replacement material, La-Fe-Mn-Si for the magnetocaloric heat exchanger. These solutions show that it is possible to reduce the ecological footprint of magnetic cooling devices and provides magnetic cooling as a green solid-state technology that has the potential to satisfy the rapidly growing global demands.