Levels, distribution, sources and human exposure pathways of alkylphenol and alkylphenol ethoxylates in indoor dust in Turkiye.

Environmental phenolic chemicals, due to their widespread occurrence and potent estrogenic properties, pose a risk to human exposure. The phenolic organic contaminants alkylphenols (APs) and alkylphenol polyethoxylates (APEs) are used in various household applications, and they may enter to the environment during production and use, potentially appearing in indoor dust. However, little is known about the levels of environmental phenolics in indoor environments. In this study, five of these compounds namely octylphenol (OP), 4-Octylphenol Monoethoxylate (4-OPME), 4-tert-octylphenol (4-t-OP), 4-n-nonylphenol (4-n-NP) and nonylphenol diethoxylate (di-NPE) were analyzed using liquid chromatography-tandem mass spectrometry (LC-MS/MS) in household dust samples (n = 148) collected from Ankara, the capital of Turkiye. OP and 4-OPME was not present in any of the analyzed samples. The median concentrations of the 148 settling dust samples were 35, 520, and 1910 ng g-1 dust for 4-t-OP, 4-n-NP, and di-NPE, respectively. An assessment of the human (children and adults) exposure pathway to APs and APEs, which are recognized as endocrine-disrupting chemicals found in residential dust, revealed that it was approximately 3 times higher for children than for adults at both moderate and heavy exposure levels. The association between chemical exposure, house characteristics, and family lifestyle was investigated using a multivariate logistic regression model. According to the results of this model, while the high concentrations measured for 4-t-OP were not found to be associated with any of the household parameters, high levels of 4-n-NP and di-NPE were associated with the frequency of house cleaning, repairs made during the previous year, residential type, the number of occupants, flooring materials, and the purchase of new household items within the past year. This study provides a basis for prioritizing toxicology and exposure studies for EDCs and mixtures and may offer new tools for exposure assessment in health studies.

A first assessment of microplastic contamination in the snow of Ankara, Turkey.

Microplastics (MPs), affecting aquatic and terrestrial ecosystems, have spread globally. The atmosphere is known as a pollutant acceptor and carrier among other ecosystems. However, the fate and amount of microplastics in the atmosphere have been the subject of less research. Therefore, it is quite important to study the amount and properties of microplastics in atmospheric fallout. The main purpose of this article is to discover microplastics in fresh snow samples collected in three different regions of Ankara and to identify potential sources of supply. The morphologies and compositions of microplastics were analyzed and characterized using scanning electron microscopy (SEM/EDS). µ-Raman spectroscopy was used to reveal the various polymer types of the selected samples. As a result, microplastics were found in all snow samples. Among the nine snow samples examined, 537 particles were recognized as MPs. The average abundance of MPs in snow samples was 59.66 items L-1. Fibers, fragments, films, and circular forms were found in all snow samples. Fragments predominated for all samples (50.08%), followed by films (28.54%), fibers (16.86%), and circulars (4.50%). The proportion of small plastics was quite high when compared to the large plastics captured by snow. Smaller MP particles found in the snow had more variety, suggesting that the microplastics in the snow samples have been broken down by long-range transport and deposition. Six different polymer types were discovered in the snow samples in this study. The most frequently identified polymer was polyethylene (31%), succedded by polystyrene (28%), and polypropylene (21%). Polyethylene terephthalate (12%), polyvinyl chloride (5%), and nylon were present in smaller proportions.

Assessment of house dust trace elements and human exposure in Ankara, Turkey.

One of the impacts of the COVID-19 pandemic is leading people remain at homes longer than ever. Considering the elongation of the time people spend indoors, the potential health risks caused by contaminants including heavy metals in indoor environments have become even more critical. The purpose of this study was to evaluate the levels and sources of heavy metals in indoor dust, to assess the exposure to heavy metals via indoor dust, and to estimate the associated health risk. The highest median value was measured for Zn (263 µg g-1), while the lowest median concentration value was observed for Cd (0.348 µg g-1). The levels of elements measured in the current study were found to be within the ranges reported in the other parts of the world, mostly close to the lower end of the range. House characteristics such as proximity to the main street, presence of pets, number of occupants, and age of the building were the house characteristics influencing the observed higher concentrations of certain heavy metals in houses. Enrichment factor values range between 1.79 (Cr) and 20.4 (Zn) with an average EF value of 8.80 ± 6.80 representing that the targeted elements are enriched (EF>2) in indoor dust in Ankara. Positive matrix factorization results showed that the heavy metals in the house dust in the study area are mainly contributed from sources namely outdoor dust, carpets/furniture, solders, wall paint/coal combustion, and cigarette smoke. Carcinogenic and non-carcinogenic risk values from heavy metals did not exceed the safe limits recommended by EPA. The highest carcinogenic risk level was caused by Cr. The risk through ingestion was higher than inhalation, and the risk levels were higher for children than for adults.

Multiple comparisons of organic, microbial, and fine particulate pollutants in typical indoor environments: diurnal and seasonal variations.

UNLABELLED: This study was performed to investigate the possible sources as well as seasonal and diurnal variations of indoor air pollutants in widely used four different environments (house, office, kindergarten, and primary school) in which people spend most of their time. Bioaerosol levels and species, volatile organic compound (VOC) levels, and PM2.5 (particulate matter with an aerodynamic diameter < or = 2.5 microm) levels were determined in different parts of these environments in parallel with outdoor sampling. Air pollution samplings were carried out in each microenvironment during five subsequent days in both winter and summer in Ankara, Turkey. The results indicated that bioaerosol, VOC, and PM2.5 levels were higher in the winter than in the summer. Moreover PM2.5 and bioaerosol levels showed remarkable daily and diurnal variations, whereas a good correlation was found between the VOC levels measured in the morning and in the afternoon. Bacteria levels were, in general, higher than fungi levels. Among the VOCs, toluene was the most predominant, whereas elevated n-hexane levels were also observed in the kindergarten and the primary school, probably due to the frequent wet cleaning during school days. According to factor analysis, several factors were found to be significantly influencing the indoor air quality (IAQ), and amongst them, VOC-based products used indoors ranked first. The overall results indicate that grab sampling in naturally ventilated places may overestimate or underestimate the IAQ due to the inhomogeneous composition of indoor air caused by irregular exchanges with the outdoor air according to the season and/or occupants' habits. IMPLICATIONS: Seasonal and diurnal variations of VOCs, PM2.5, bioaerosols in house, office, and schools were observed, in which PM2.5 and bioaeorosols showed marked both intra- and interday variability, but VOCs did not. VOC-containing products were the most common source of air pollutants affecting the indoor air quality. External factors affecting the indoor air quality were season and indirectly ventilation. A grab sample cannot be representative in evaluating the air quality of a naturally ventilated environment precisely.

Existence of SARS-CoV-2 RNA on ambient particulate matter samples: A nationwide study in Turkey.

Coronavirus disease 2019 (COVID-19) is caused by the SARS-CoV-2 virus and has been affecting the world since the end of 2019. The disease led to significant mortality and morbidity in Turkey, since the first case was reported on March 11th, 2020. Studies suggest a positive association between air pollution and SARS-CoV-2 infection. The aim of the present study was to investigate the role of ambient particulate matters (PM), as potential carriers for SARS-CoV-2. Ambient PM samples in various size ranges were collected from 13 sites including urban and urban-background locations and hospital gardens in 10 cities across Turkey between 13th of May and 14th of June 2020 to investigate the possible presence of SARS-CoV-2 RNA on ambient PM. A total of 203 daily samples (TSP, n = 80; PM2.5, n = 33; PM2.5-10, n = 23; PM10µm, n = 19; and 6 size segregated PM, n = 48) were collected using various samplers. The N1 gene and RdRP gene expressions were analyzed for the presence of SARS-CoV-2, as suggested by the Centers for Disease Control and Prevention (CDC). According to real time (RT)-PCR and three-dimensional (3D) digital (d) PCR analysis, dual RdRP and N1 gene positivity were detected in 20 (9.8%) samples. Ambient PM-bound SARS-CoV-2 was analyzed quantitatively and the air concentrations of the virus ranged from 0.1 copies/m3 to 23 copies/m3. The highest percentages of virus detection on PM samples were from hospital gardens in Tekirdag, Zonguldak, and Istanbul, especially in PM2.5 mode. Findings of this study have suggested that SARS-CoV-2 may be transported by ambient particles, especially at sites close to the infection hot-spots. However, whether this has an impact on the spread of the virus infection remains to be determined.