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1.
Angew Chem Int Ed Engl ; 56(21): 5825-5828, 2017 05 15.
Artigo em Inglês | MEDLINE | ID: mdl-28425169

RESUMO

A new hydrogenation catalyst based on a manganese complex of a chiral P,N,N ligand has been found to be especially active for the hydrogenation of esters down to 0.1 mol % catalyst loading, and gives up to 97 % ee in the hydrogenation of pro-chiral deactivated ketones at 30-50 °C.

3.
Chem Commun (Camb) ; 50(78): 11511-3, 2014 Oct 09.
Artigo em Inglês | MEDLINE | ID: mdl-25130565

RESUMO

As part of a programme aimed at exploiting lignin as a chemical feedstock for less oxygenated fine chemicals, several catalytic C-C bond forming reactions utilising guaiacol imidazole sulfonate are demonstrated. These include the cross-coupling of a Grignard, a non-toxic cyanide source, a benzoxazole, and nitromethane. A modified Meyers reaction is used to accomplish a second constructive deoxygenation on a benzoxazole functionalised anisole.

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