Expeditious preparation of ß-sec-alkyl vicinal amino alcohols used for chiral ligand synthesis.

An economical route providing quick access to chiral ß-amino alcohols bearing one ß-sec-alkyl group was developed. This protocol starts with commercially available and cheap chiral sources such as derivatives of L-serine and L-threonine. A series of vicinal amino alcohols with high optical purity were prepared in good yields through 4 or 6 operationally simple steps. Two different strategies (three routes) were designed for the synthesis of amino alcohols bearing ß-sec-alkyl groups with various steric hindrance.

The Performance of Satellite-Based Links for Measurement-Device-Independent Quantum Key Distribution.

Measurement-device-independent quantum key distribution (MDI-QKD) protocol has high practical value. Satellite-based links are useful to build long-distance quantum communication network. The model of satellite-based links for MDI-QKD was proposed but it lacks practicality. This work further analyzes the performance of it. First, MDI-QKD and satellite-based links model are introduced. Then considering the operation of the satellite the performance of their combination is studied under different weather conditions. The results may provide important references for combination of optical-fiber-based links on the ground and satellite-based links in space, which is helpful for large-scale quantum communication network.