Influence of chlorine on co-processing of hazardous wastes in brick kilns.

Brick kiln co-treatment is a novel industrial hazardous wastes (IHWs) utilization process. However, the effects of chlorine (Cl) in wastes on heavy metals (HMs) during this process are overlooked. This study investigated the stabilization/solidification (S/S) and volatilization, as well as long and short-term leaching, of HMs in Cl-containing bricks. The results indicated enhanced formations of stable mineral phases (NiFe2O4, Ni2SiO4, Cd3Al2Si3O12, CdSiO3, FeCr2O4, Cr2O3, CuFe2O4, and CuAl2O4) in bricks at a low sintering temperature (800 °C) due to the affinity between Cl and HMs. By comparing HM concentrations before and after sintering in bricks, the study observed that Cl's presence significantly elevated the volatilization rates for Cd and Cu by 30.8% and 14.2%, respectively. In contrast, the effect on volatilization for Ni and Cr was not significant. Additionally, utilizing the NEN 7375 method, the cumulative leaching rates of Ni, Cd, Cr, and Cu over a 64-day experiment under extremely acidic conditions were 0.22%, 7.18%, 0.01%, and 1.46%, respectively. Similarly, higher short-term leaching rates of Cd (4.03%) and Cu (5.73%) than those of Ni (0.94%) and Cr (0.08%) were observed. This finding might be attributed to the lower stability of the Cd and Cu solid phases under acidic environments compared to those of Ni and Cr. Surface wash-off, dissolution, and diffusion were the processes governing HM leaching from bricks. The 10-year projections revealed a minimal release of HMs during future extended leaching, implying the successful S/S of HMs. This study provides a reference for assessing the environmental impacts of brick kiln co-processing of Cl-containing IHWs.

Thermal utilization techniques and strategies for secondary aluminum dross: A review.

Secondary aluminum ash (SAD) disposal is challenging, particularly in developing countries, and presents severe eco-environmental risks. This paper presents the treatment techniques, mechanisms, and effects of SAD at the current technical-economic level based on aluminum ash's resource utilization and environmental properties. Five recovery techniques were summarized based on aluminum's recoverability in SAD. Four traditional utilization methods were outlined as per the utilization of alumina in SAD. Three new utilization methods of SAD were summarized based on the removability (or convertibility) of aluminum nitride in SAD. The R-U-R (recoverability, utilizability, and removability) theory of SAD was formed based on several studies that helped identify the fingerprint of SAD. Furthermore, the utilization strategies of SAD, which supported the recycling of aluminum ash, were proposed. To form a perfect fingerprint database and develop various relevant techniques, future research must focus on an extensive examination of the characteristics of aluminum ash. This research will be advantageous for addressing the resource and environmental challenges of aluminum ash.

Evolution of physicochemical and leaching characteristics of municipal solid waste incineration fly ash in China under ultra-low emission standard.

The physical and chemical characteristics of fly ash has changed significantly under ultra-low emission system and the current leaching system is no longer suitable for high alkalinity fly ash. This work investigated the pH values and evolution of physical and chemical characteristics of fly ash from 24 typical municipal solid waste incineration plants in China. The pH value of the leaching solution obtained by HJ/T 300-2007 presented two different acid and alkali characteristics, where high and low alkalinity fly ash accounted for 54.17% and 45.83%, respectively. The alkali content in fly ash increased significantly after ultra-low emission standard, increasing by 18.24% compared with before the implementation of GB 18485-2014. The leaching behavior of high alkalinity fly ash showed the illusion that they could enter the landfill only by the addition of a small amount of chelating agent or even without stabilization treatment, and its long-term landfill risk is significant. The phase change of high alkalinity fly ash and pH value change of the leaching solution after carbonation were the key factors for the leaching concentration change of heavy metals. Therefore, it is recommended to improve the existing leaching system or conduct accelerated carbonization experiments to scientifically evaluate the long-term leaching characteristics of high alkalinity fly ash, and to reduce the risk of heavy metal release from high alkalinity FA after entering the landfill site.

Recent advances in organic waste pyrolysis and gasification in a CO2 environment to value-added products.

The persistent combustion of fossil fuels has resulted in a widespread greenhouse effect attributable to the continual elevation of carbon dioxide (CO2) levels in the atmosphere. Recent research indicates that utilizing CO2 as a pyrolysis gasification medium diminishes CO2 emissions and concurrently augments the value of the resultant pyrolysis gasification products. This paper reviews recent advancements in the pyrolysis gasification of organic solid wastes under a CO2 atmosphere. Meanwhile, the mechanisms of CO2 influence in the pyrolysis and gasification processes were also discussed. In comparison to noble gases, CO2 exhibits reactivity with char at≥710 °C, resulting in additional mass loss of the sample. In addition, CO2 was able to increase the specific surface area and stability of biochar and reduce biooil toxicity by lowering the content of cyclic compounds in the biooil, while CO2 was able to react with GPRs with some volatile products (e.g., light hydrocarbons) to increase biogas yield. Finally, CO2 also prevents catalyst deactivation by reducing secondary coke formation. We also recommend directing future attention toward utilizing unpurified CO2 in pyrolysis and gasification. This review aims to expand the utilization of CO2 and advocate for applying pyrolysis gasification products.

Roles of red mud in remediation of contaminated soil in mining areas: Mechanisms, advances and perspectives.

Red mud (RM) is a kind of strong alkaline solid waste produced from the aluminum industry, which contributes significantly to environmental pollution and can cause severe health issues.Currently, RM is widely recognized as a potential material for soil remediation because of its rich metal oxide content, such as Fe/Al oxides. However, there is no comprehensive description on the roles of RM in passivation remediation of contaminated soil in mining areas. This review summarizes the mechanisms of passivation of heavy metals (HMs) in contaminated soil by RM, including precipitation, adsorption and ion exchange. Besides the effects of adding RM on soil physicochemical properties, heavy metal forms and ecological environment are further elaborated. Moreover, using the co-hydrothermal carbonization of RM and biomass for enhancing the efficiency of contaminated soil remediation is proposed as the main prospective research. This paper provides technical references for the resource utilization of RM and the treatment of heavy metal-contaminated soil.

Pyrolytic kinetics, reaction mechanisms and gas emissions of waste automotive paint sludge via TG-FTIR and Py-GC/MS.

The present study experimentally quantified the pyrolysis behaviors of waste solvent-based automotive paint sludge (OAPS) and water-based automotive paint sludge (WAPS) at four different heating rates using thermogravimetric-Fourier transform infrared (TG-FTIR) spectrometry and pyrolysis-gas chromatography-mass (Py-GC/MS) spectrometry analyses. Flynn-Wall-Ozawa (FWO) and Kissinger-Akahira-Sunose (KAS) methods combined with the master-plots method were employed to investigate the pyrolysis kinetics and reaction mechanisms of waste automotive paint sludge. Three reaction stages and three reaction peaks in stage 2 were distinguished for both OAPS and WAPS degradation. The average activation energy (Ea) estimates for OAPS (FWO: 179.09 kJ/mol; KAS: 168.28 kJ/mol) were slightly higher than WAPS (FWO: 175.90 kJ/mol; KAS: 164.80 kJ/mol) according to FWO and KAS methods. The main pyrolysis reaction mechanisms of both OAPS and WAPS closely matched with the order-based model corresponding to 3rd and 2nd order random nucleation on an individual particle. The evolved gas species of CH4, CO2, phenols, NH3, H2O, and CO from OAPS and WAPS pyrolysis were identified by TG-FTIR. According to Py-GC/MS, hydrocarbons (47.2%) and O-components (42.7%) were relatively large after OAPS and WAPS pyrolysis, respectively. Melamine was the most abundant N-component product after pyrolysis of OAPS (5.8%) and WAPS (4.8%).

Development and validation of diffusion-controlled model for predicting polycyclic aromatic hydrocarbons from baking-free brick derived from oil - based drilling cuttings.

Investigating the release of organic pollutants from bricks made from solid waste is essential. Based on Fick's laws of diffusion, the diffusion model and diffusion-degradation model of polycyclic aromatic hydrocarbon (PAH) emission from the bricks were deduced. The degradation and 64-day emission of PAHs in solid bricks made of oil-based drill cuttings were observed experimentally. The emission and degradation characteristics of 14 PAHs were obtained and fitted with the diffusion and diffusion-degradation models. The emission of most of the PAHs from the bricks at the beginning was in good agreement with the diffusion model, except for benzo[a]anthracene, pyrene, benzo[b]fluoranthene, benzo[k]fluoranthene, and benzo[a]pyrene. However, the emission of PAHs after some time was significantly lower than the theoretical value of the diffusion model. Moreover, fitting with the diffusion-degradation model gave better results, indicating that a joint diffusion-degradation mechanism controlled the emission of PAHs. Therefore, the diffusion-degradation model can better predict the long-term emission of PAHs in bricks made of oil-based drill cuttings.

Occurrence and formation pathways analysis of PBDD/Fs from 2,4,6-tribromophenol under thermal reaction conditions.

Polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs) are highly toxic and persistent compounds that provoke a wave of publicity. Bromophenols are important precursors for forming PBDD/Fs, and their reaction path has always been a research hotspot. In this study, the formation characteristic of PBDD/Fs from 2,4,6-TBP were studied. The yields of 2,3,7,8-substituted PBDD/Fs and 2,4,6,8-TBDF for the different thermal products ranged from 0.067 to 10.3 ng/g and 0.207-9.68 ng/g, respectively. The effects of adding Cu, Fe, and Sb2O3 were investigated and found to be more inclined to accelerate the formation of ortho-substituted PBDD/Fs than 2,3,7,8-PBDD/Fs. The formation pathways of 2,3,7,8-substituted PBDD/Fs and 2,4,6,8-TBDF were also proposed. 2,4,6,8-TBDF is generated in the C-C coupling reactions of some radical intermediates from the debromination of 2,4,6-TBP. The 2,3,7,8-PBDD/Fs are produced through more complex debromination, bromine substitution, and bromine rearrangement reactions. In addition, various catalytic effects on PBDD/F formation pathways were found, and the catalytic effect of Cu by the Ullmann reaction was the highest, while bromophenol oxidation by Fe was the highest. These results proved that both 2,3,7,8-substituted and non-2,3,7,8-substituted PBDD/Fs would be generated from 2,4,6-TBP, and the effects of the catalyst on the Br substituted position of 2,3,7,8-substituted PBDD/Fs were much lower than the Br-substituted position on bromophenol.

How to predict emissions of volatile organic compounds from solid building materials? A critical review on mass transfer models.

Volatile organic compounds (VOCs) emitting from solid building materials can cause adverse human health and environmental climate effects. It's more cost effective and powerful for mass-transfer emission models to describe the emission characteristic of VOCs than emission chamber studies. In this review, the existing main physical mechanism-based models for predicting VOCs emissions from dry solid building materials have been discussed, as well as their differences and similarities. Ignoring internal diffusion and porosity of solid materials, single-phase model is generally quite safe for use in actual condition. Conversely, porous media model is good for understanding VOC-transfer principles in porous materials. Additionally, the porous media model and the single-phase model can be transformed mutually because their model parameters are correlative. The availability of emission models is largely determined by the reliable and useful model parameters. Therefore, substantial technologies and novel methods have been developed for parameter estimation, which have also been reviewed in this paper. How to readily and rapidly obtain model parameters is a future development direction. In addition, applying emission models to predict and control VOCs emission from other solid waste materials is another future research prospect.

Emissions of BTEXs, NMHC, PAHs, and PCDD/Fs from Co-processing of Oil-based Drilling Cuttings in Brick Kilns.

Oil-based drilling cuttings (OBDC) produced from shale gas development is a hazardous waste that have high calorific values and should be disposed of properly. Burning bricks with OBDC is a promising co-disposal method; however, organic pollutants emitted during this process have not received sufficient attention. In this study, the composition and combustion characteristics of OBDC were determined, and the emissions of typical organic pollutants when burning bricks with the addition of OBDC were investigated; these included benzene series compounds (BTEXs), non-methane total hydrocarbons (NMHC), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs). The results showed that OBDC comprised large amounts of alkanes and aromatic hydrocarbons, and combusted mainly in the temperature range of 145-450 °C with an ignition temperature of 145 °C. The co-processing 10% OBDC increased the concentrations of toluene, NMHC, and PAHs in the flue gases by ∼1000%, ∼500%, and 200%, respectively, compared to the control experiment; however, their emission concentrations were within the limits set by the Integrated emission standards of air pollutants of Chongqing. It is worth noting that 26.443 ng/Nm3 PCDD/Fs with a total toxicity of 0.709 ng I-TEQ/Nm3 was generated from the co-processing 10% OBDC, which was ascribed to the high content of chlorine and aromatic hydrocarbons in the OBDC-promoted PCDD/Fs formed during the burning and cooling processes. Though PCDD/Fs in flue gas exceeded the 0.5 ng I-TEQ/Nm3 limit prescribed in the Pollution control standard for hazardous wastes incineration of China, the realistic emission of PCDD/Fs is expected to meet with this emission limit after desulfurization treatment as PCDD/Fs can be absorbed by gypsum. It is recommended that a lower amount of OBDC is added to reduce PCDD/F formation at the source and to take more efficient air pollution control system in order to reach a stricter emission limit of 0.1 ng I-TEQ/Nm3 in EU and USA. Cycling flue gas may also be an effective method to reduce other organic pollutants. Under these conditions, co-processing OBDC in brick kilns can be achieved without serious environmental pollution, making it a potential method for disposal and utilization.

Characterizing the emission behaviors of cumulative VOCs from automotive solvent-based paint sludge.

Volatile organic compounds (VOCs) diffused from paint sludge are potential hazard contributing significantly to environmental pollution and exposure to them can cause severe health issues. In this paper, a diffusion-controlled model was firstly developed for characterizing the emission behaviors of cumulative VOCs from automotive solvent-based paint sludge based on the worst field management scenario. The presented model is characterized by two key parameters: the diffusion coefficient (Dm) and the initial emittable concentration (Cm,0), which can be simultaneously obtained by our proposed ER-history method. Four major components were detected including 1-butanol, butyl acetate and 1,2,4-trimethylbenzene and 1-ethyl-4-methylbenzene. In addition, the model was validated by using environmental data in a ventilated test chamber, proving that the model is reliable and convincing. However, relative deviations of 1-butanol and butyl acetate are larger than those of 1,2,4-trimethylbenzene and 1-ethyl-4-methylbenzene, indicating that the model is more accurate for predicting hydrophobic VOCs release than those of hydrophilic VOCs. Besides, an increase in Cm,0 and Dm tends to enhance VOCs cumulation release. Our studies provide new insight into experimental designs for rapid model parameters measurement and a sound basis for estimating VOCs cumulative release from paint sludge as well as for hazardous waste.

Quantifying material flow of oily sludge in China and its implications.

Oily sludge is classified as hazardous waste. If not treated properly, it can cause negative impacts on human health and the ecological environment. However, the current lack of macro and micro scientific understanding of the treatment of oily sludge hinders its sound management. In this study, at the microlevel, we selected two of the most common treatment processes of oily sludge and establish a database through data collection and estimation. Material flow analysis was adopted to reveal the generation, pretreatment, recycling, and disposal processes of mechanical separation and incineration. At the macrolevel, this article predicted the material flow of China's whole process management of oily sludge and analyzed the typical flow characteristics of valuable resources in the whole process to guide the formulation of relevant policies in the future. The annual generation of oily sludge in China was between 4.45 and 6.22 Tg, and the average comprehensive utilization rate was approximately 36%. We are still far away from a sound management system despite new legislative revisions. Close supervision and technical processes should be further enhanced shortly.

A field study of dioxins during co-processing of hazardous waste in multicomponent slurry gasifier.

A field test was conducted to study the emission and distribution characteristics of dioxins during co-processing of hazardous waste in a multicomponent slurry gasifier (MCSG). The toxicity equivalent concentrations of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) in all exhaust gas, waste water, and solid waste under both blank condition (i.e., feedstock was normal coal-water slurry) and test condition (i.e., feedstock mixed with hazardous waste and labeling reagents) were analyzed. Results showed that organic matter was fully degraded in the MCSG. The dioxin amount in the black water flash steam increased with the addition of hazardous waste and chlorine in the feedstock, and octachlorodibenzo-p-dioxins (OCDD) with the largest increase is the most easily formed monomer in dioxins. The dioxin amount in all samples was far below the standard limit in China and other countries. This indicates the low environmental risk from dioxins during the co-processing process. The dioxin distribution trend in solid, liquid, and gas phase during co-processing did not change: 86.63%-94.18%, 0.02%-0.13%, and 5.8%-13.23% of PCDDs were distributed in the exhaust gas, waste water, and solid waste, respectively, while 6.10%-22.95%, 0.59%-0.80%, and 76.45%-93.10% of PCDFs were distributed in the exhaust gas, waste water, and solid waste, respectively.

Pathways and influential factors study on the formation of PBDD/Fs during co-processing BDE-209 in cement kiln simulation system.

The thermal processes of cement kilns are sources of polybrominated dibenzofurans and dioxins (PBDD/Fs); however, when co-processing decabromodiphenyl ether (BDE-209) soil in cement kilns, very few reports have investigated the mechanism of PBDD/Fs formation from BDE-209. Therefore, the pathways and factors that influence the formation of PBDD/Fs were investigated using Box-Behnken design (BBD) of the response surface methodology (RSM) at lab-scale. The PBDEs, HBr/Br2 and PBDD/Fs emissions in flue gas from the simulated thermal process were analyzed using gas chromatography/mass spectroscopy (GC/MS), high-resolution gas chromatography/high-resolution mass spectrometry (HRGC/HRMS), and ion chromatography (IC). Density functional theory (DFT) was also used to further discuss the formation of PBDD/Fs. The major products of BDE-209 thermal decomposition in flue gas were 97.1% HBr/Br2 (a.v. 26.6%/70.6%) > 2.7% PBDEs >0.2% PBDD/Fs. Formation of precursors were the main pathways for PBDD/Fs, and those precursors were dominated by higher-brominated PBDEs (heptã deca-BDEs); debromination of BDE-209 was also a crucial pathway for the formation of PBDD/Fs throughout the thermal process. Interestingly, it was easier to form HpBDD/Fs from OBDD/Fs than from PBDEs. The O2 percentage and interaction factors of O2 percentage, temperature, and CaCO3 percentage have the largest influence on PBDD/Fs emissions and formation.

Occurrence and Distribution of Phthalates in Sanitary Napkins from Six Countries: Implications for Women's Health.

Chemicals in feminine hygiene products can exert adverse health effects as a result of strong absorptive capacity of the vagina and vulva. However, little information is available on phthalates in sanitary napkins. We measured the concentrations of 15 phthalates in sanitary napkins collected from six countries and found total concentrations in the range of 1733-11942 ng/g. Di(isobutyl)phthalate (DiBP), bis(2-ethylhexyl)phthalate (DEHP), and di-n-butyl phthalate (DnBP) were the dominant congeners, representing a median of 27.3, 26.7, and 20.4% of the total median phthalate concentrations across all countries, respectively. The phthalates likely originated mainly from the introduction in the manufacturing process, and some may have been from the use of plastic or paper materials. The estimated intake (at the 90th percentile) of DiBP, DnBP, and DEHP from sanitary napkins approximately represented 6.35-23.6, 3.35-9.90, and 1.06-9.57%, respectively, of the total exposure, indicating that sanitary napkins are a relevant source of exposure to these chemicals. The calculated health risks of phthalates in sanitary napkins were generally low, but the carcinogenic risks in some samples exceeded acceptable levels. More research is required to investigate the contaminations in sanitary napkins and those associated with risks to women.

Chilling Prospect: Climate Change Effects of Mismanaged Refrigerants in China.

The global community has responded to the dual threats of ozone depletion and climate change from refrigerant emissions (e.g., chlorofluorocarbons, CFCs, and hydrofluorocarbons, HFCs) in refrigerators and air conditioners (RACs) by agreeing to phase out the production of the most damaging chemicals and replacing them with substitutes. Since these refrigerants are "banked" in products during their service life, they will continue to impact our environment for decades to come if they are released due to mismanagement at the end of life. Addressing such long-term impacts of refrigerants requires a dynamic understanding of the RACs' life cycle, which was largely overlooked in previous studies. Based on field surveys and a dynamic model, we reveal the lingering ozone depletion potential (ODP) and significant global warming potential (GWP) of scrap refrigerants in China, the world's largest producer (62%) and consumer (46%) of RACs in 2015, which comes almost entirely from air conditioners rather than refrigerators. If the use and waste management of RACs continue with the current trend, the total GWP of scrap refrigerants in China will peak by 2025 at a level of 135.2 ± 18.9 Mt CO2e (equal to approximately 1.2% ± 0.2% of China's total greenhouse gas emissions or the national total of either The Netherlands and Czech Republic in 2015). Our results imply an urgent need for improving the recycling and waste management of RACs in China.

Spatial distribution of and seasonal variations in endosulfan concentrations in soil, air, and biota around a contaminated site.

Soil, air, tree bark, rice, wheat, invertebrates, and chicken tissues around a typical endosulfan-contaminated site were analyzed in each season in each of two years. The total endosulfan (the sum of α-, ß-endosulfan and endosulfan sulfate) were significantly different in soil and air samples collected in the four seasons (P < 0.01) and the mean concentrations were 6.53 ng/g dry weight (d.w.) and 2.40 ng/m3, respectively, in autumn, 3.32 ng/g d.w. and 2.48 ng/m3, respectively, in winter, 2.10 ng/g d.w. and 0.93 ng/m3, respectively, in spring, and 1.03 ng/g d.w. and 0.83 ng/m3, respectively, in summer. The total endosulfan concentrations in tree bark, rice, wheat, and invertebrates were 23.0-278 (mean 95.5) ng/g d.w., 7.36-35.5 (mean 17.4) ng/g d.w., 34.3-158 (mean 83.1) ng/g d.w., and 401-4354 (mean 2125) ng/g lipid weight, respectively. The total endosulfan concentrations in the chicken gizzard, heart, liver, and meat samples were 552, 212, 699, and 221 ng/g lipid weight, respectively. The endosulfan concentrations in soil, air, and biota around the site were strongly influenced by endosulfan emissions from the site, and the concentrations had decreased to half the initial concentrations six months after endosulfan production stopped. The invertebrate and chicken bioconcentration and biomagnification factors indicated that endosulfan accumulated in the invertebrates and chicken tissues was slightly biomagnified by chickens.

Odor impact assessment of trace sulfur compounds from working faces of landfills in Beijing, China.

Odor pollution from landfills is causing a growing number of public complaints and concerns. Compared with hydrogen sulfide (H2S) and ammonia (NH3), odor impacts of trace sulfur compounds (TSCs) are arousing concerns due to their low odor threshold values (OTVs). Working face on landfill sites has been claimed as major source of odor impacts. This study estimated the odor impacts of fugitive TSCs from the working face of a large typical municipal solid waste (MSW) landfill in Beijing, China. A modified wind tunnel system was introduced to estimate emission rates of TSCs, which is a basic requirement for odor impact assessment. The odor activity value (OAV) method was introduced for odor evaluation. Fieldwork in the selected landfill was conducted from 2014 to 2015. Methyl mercaptan (CH3SH), dimethyl sulfide, dimethyl disulfide (DMDS), and carbon disulfide (CS2) were the TSCs studied in this work. The spatial concentration distributions of the TSCs were calculated on the basis of the Gaussian dispersion model in a "normal case" scenario and a "worst case" scenario. DMDS showed the highest emission rate (7.18 µg m-2 s-1), and CH3SH was the dominant odorous compound with an average emission rate of 4.58 µg m-2 s-1. The dispersion modeling indicated that the odor impact distances of the TSCs in the studied landfill for the normal case and worst case scenarios were 495 ±â€¯96 m and 9230 m at the downwind regions, respectively. Results of this study can benefit the formulation of strategies for odor control and abatement in landfill sites.

Contamination and health risks of heavy metals in street dust from a coal-mining city in eastern China.

We collected street dust from Huainan, a typical coal-mining city in China, to investigate the contamination features and health risks of heavy metals. Concentrations of Co, Cr, Cu, Pb, As, and Sb were generally low to moderate, while pollution levels of Cd and Hg were moderate to high. Concentrations of Cd and Hg were associated with considerable health risks at 64.3% and 58.6% of sites, respectively. In particular, about a fifth of samples had associated high risks as a result of Hg contamination levels. Relative to other urban areas, the street dust from the mining area had no more severe metal pollution, which might be partly attributed to the deposition of coal dust onto street dusts. A source assessment indicated that metals in dust form Huainan were mainly derived from vehicular-related activities, industrial emissions, weathering of coal dust and natural soils, and coal combustion. Although the health risk levels from exposure to individual metals in dusts were low, the non-carcinogenic risks from multiple metals to local children exceeded the acceptable level (1.0), suggesting that the overall risk from exposure to multiple metals in dust is concerning.

A full-scale study on thermal degradation of polychlorinated dibenzo- p-dioxins and dibenzofurans in municipal solid waste incinerator fly ash and its secondary air pollution control in China.

Degradation of polychlorinated dibenzo- p-dioxins and dibenzofurans in municipal solid waste incinerator fly ash is beneficial to its risk control. Fly ash was treated in a full-scale thermal degradation system (capacity 1 t d-1) to remove polychlorinated dibenzo- p-dioxins and dibenzofurans. Apart from the confirmation of the polychlorinated dibenzo- p-dioxin and dibenzofuran decomposition efficiency, we focused on two major issues that are the major obstacles for commercialising this decomposition technology in China, desorption and regeneration of dioxins and control of secondary air pollution. The toxic equivalent quantity values of polychlorinated dibenzo- p-dioxins and dibenzofurans decreased to <6 ng kg-1 and the detoxification rate was ⩾97% after treatment for 1 h at 400 °C under oxygen-deficient conditions. About 8.49% of the polychlorinated dibenzo- p-dioxins and dibenzofurans in toxic equivalent quantity (TEQ) of the original fly ash were desorbed or regenerated. The extreme high polychlorinated dibenzo- p-dioxin and dibenzofuran levels and dibenzo- p-dioxin and dibenzofuran congener profiles in the dust of the flue gas showed that desorption was the main reason, rather than de novo synthesis of polychlorinated dibenzo- p-dioxins and dibenzofurans in the exhaust pipe. Degradation furnace flue gas was introduced to the municipal solid waste incinerator economiser, and then co-processed in the air pollution control system. The degradation furnace released relatively large amounts of cadmium, lead and polychlorinated dibenzo- p-dioxins and dibenzofurans compared with the municipal solid waste incinerator, but the amounts emitted to the atmosphere did not exceed the Chinese national emission limits. Thermal degradation can therefore be used as a polychlorinated dibenzo- p-dioxin and dibenzofuran abatement method for municipal solid waste incinerator source in China.