A review on extraction of polysaccharides from crustacean wastes and their environmental applications.

Disposal of biodegradable waste of seashells leads to an environmental imbalance. A tremendous amount of wastes produced from flourishing shell fish industries while preparing crustaceans for human consumption can be directed towards proper utilization. The review of the present study focuses on these polysaccharides from crustaceans and a few important industrial applications. This review aimed to emphasize the current research on structural analyses and extraction of polysaccharides. The article summarises the properties of chitin, chitosan, and chitooligosaccharides and their derivatives that make them non-toxic, biodegradable, and biocompatible. Different extraction methods of chitin, chitosan, and chitooligosaccharides have been discussed in detail. Additionally, this information outlines possible uses for derivatives of chitin, chitosan, and chitooligosaccharides in the environmental, pharmaceutical, agricultural, and food industries. Additionally, it is essential to the textile, cosmetic, and enzyme-immobilization industries. This review focuses on new, insightful suggestions for raising the value of crustacean shell waste by repurposing a highly valuable material.

Modeling analysis on the effective elimination of toxic pollutant from aquatic environment using pyrolysis assisted palmyra palm male inflorescence.

In this study adsorption of Cd(II) ions using the pyrolysis assisted Palmyra palm male inflorescence (PAPMI) was systematically examined. A batch adsorption study was carried out to determine the type of interactions and removal efficiency which is based on the surface property of PAPMI. The diverse parameters which affect the adsorption performance of PAPMI for Cd(II) ion removal were optimized: biosorbent dose - 1.25 g/L, pH - 6.0, temperature - 303 K, initial cadmium ions concentration - 50 mg/L and contact time - 40 min. Pseudo-first order kinetics and Langmuir isotherm models were more suitable to describe the adsorption kinetics and isotherm, respectively. Therefore, modeling studies portrayed the present Cd(II) ions adsorption on PAPMI as monolayer adsorption occurs on the homogeneous surface and follows the physisorption mechanism. The maximum adsorption capacity of the synthesized PAPMI was examined as 233.2 mg/g from the equilibrium isotherm investigation. Based on the calculated thermodynamic parameters (ΔGo, ΔHo and ΔSo) values, the present Cd(II) ions adsorption on PAPMI was explicated as feasible, and exothermic. The outcome proposed that Palmyra palm male inflorescence can be a suitable adsorbent for expulsion of Cd(II) ions from aqueous environment. In the interim, the utilization of pyrolysis assisted is a viable and fast uptake innovation for the removal of heavy metals from water environment.

Degradation of toxic agrochemicals and pharmaceutical pollutants: Effective and alternative approaches toward photocatalysis.

Emerging concern regarding the remediation of environmental pollution has expanded tremendously in recent years. Pharmaceutical industries and agricultural sectors release an enormous amount of residues containing toxic pollutants at trace levels which poses a serious impact on the environment and human health. To cope with the effect of hazardous and toxic contaminants, numerous methodologies have been developed for the treatment of effluents released from the agrochemical and pharmaceutical industries. Amongst them, photocatalysis has gained much more attention for the degradation of pollutants due to its low cost, higher capability, green and eco-friendly approaches. Photocatalysts are the substrate that plays a key role in pollutant removal through photocatalysis by accelerating the necessary chemical reactions using a light source. In this review, the recent progress on photocatalysis and its fundamental mechanism in agrochemicals and pharmaceutical pollutant degradation was summarized. This review concisely discusses the incorporation of various metal oxides and nanomaterials into semiconductors for the effective degradation of contaminants. The current status and future research on different sectors and the difficulties in the photocatalytic removal of agrochemical and pharmaceutical pollutants are also reviewed in detail.

A review on bioremediation approach for heavy metal detoxification and accumulation in plants.

Nowadays, the accumulation of toxic heavy metals in soil and water streams is considered a serious environmental problem that causes various harmful effects on plants and animals. Phytoremediation is an effective, green, and economical bioremediation approach by which the harmful heavy metals in the contaminated ecosystem can be detoxified and accumulated in the plant. Hyperaccumulators exude molecules called transporters that carry and translocate the heavy metals present in the soil to different plant parts. The hyperaccumulator plant genes can confine higher concentrations of toxic heavy metals in their tissues. The efficiency of phytoremediation relies on various parameters such as soil properties (pH and soil type), organic matters in soil, heavy metal type, nature of rhizosphere, characteristics of rhizosphere microflora, etc. The present review comprehensively discusses the toxicity effect of heavy metals on the environment and different phytoremediation mechanisms for the transport and accumulation of heavy metals from polluted soil. This review gave comprehensive insights into plants tolerance for the higher heavy metal concentration their responses for heavy metal accumulation and the different mechanisms involved for heavy metal tolerance. The current status and the characteristic features that need to be improved in the phytoremediation process are also reviewed in detail.

A review on recent advancements in recovery of valuable and toxic metals from e-waste using bioleaching approach.

This review is intent on the environmental pollution generated from printed circuit boards and the methods employed to retrieve valuable and hazardous metals present in the e-wastes. Printed circuit boards are the key components in the electronic devices and considered as huge e-pollutants in polluting our surroundings and the environment as a whole. Composing of toxic heavy metals, it causes serious health effects to the plants, animals and humans in the environment. A number of chemical, biological and physical approaches were carried out to recover the precious metals and to remove the hazardous metals from the environment. Chemical leaching is one of the conventional PCBs recycling methods which was carried out by using different organic solvents and chemicals. Need of high cost for execution, generation of secondary wastes in the conventional methods, forces to discover the advanced recycling methods such as hydrometallurgical, bio-metallurgical and bioleaching processes to retrieve the valuable metals generate through e-wastes. Among them, bioleaching process gain extra priority due to its higher efficiency of metal recovery from printed circuit boards. There are different classes of microorganisms have been utilized for precious metal recovery from the PCBs through bioleaching process such as chemolithoautotrophy, heterotrophy and different fungal species including Aspergillus sp. and Penicillium sp. The current status and scope for further studies in printed circuit boards recycling are discussed in this review.

Sustainable strategy on microbial fuel cell to treat the wastewater for the production of green energy.

Microbial fuel cell (MFC) is one of the promising alternative energy systems where the catalytic conversion of chemical energy into electrical energy takes places with the help of microorganisms. The basic configuration of MFC consists of three major components such as electrodes (anode and cathode), catalyst (microorganism) and proton transport/exchange membrane (PEM). MFC classified into four types based on the substrate utilized for the catalytic energy conversion process such as Liquid-phase MFC, Solid-phase MFC, Plant-MFC and Algae-MFC. The core performance of MFC is organic substrate oxidation and electron transfer. Microorganisms and electrodes are the key factors that decide the efficiency of MFC system for electricity generation. Microorganism catalysis degradation of organic matters and assist the electron transfer to anode surface, the conductivity of anode material decides the rate of electron transport to cathode through external circuit where electrons are reduced with hydrogen and form water with oxygen. Not limited to electricity generation, MFC also has diverse applications in different sectors including wastewater treatment, biofuel (biohydrogen) production and used as biosensor for detection of biological oxygen demand (BOD) of wastewater and different contaminants concentration in water. This review explains different types of MFC systems and their core performance towards energy conversion and waste management. Also provides an insight on different factors that significantly affect the MFC performance and different aspects of application of MFC systems in various sectors. The challenges of MFC system design, operations and implementation in pilot scale level and the direction for future research are also described in the present review.

Recent advances and sustainable development of biofuels production from lignocellulosic biomass.

Many countries in the world are facing the demand for non-renewable fossil fuels because of overpopulation and economic boom. To reduce environmental pollution and zero carbon emission, the conversion of biomass into biofuels has paid better attention and is considered to be an innovative approach. A diverse raw material has been utilized as feedstock for the production of biofuel, depending on the availability of biomass, cost-effectiveness, and their geographic location. Among the different raw materials, lignocellulosic biomass has fascinated many researchers around the world. The current review discovers the potential application of lignocellulosic biomass for the production of biofuels. Various pretreatment methods have been widely used to increase the hydrolysis rate and accessibility of biomass. This review highlights recent advances in pretreatment methodologies for the enhanced production of biofuels. Detailed descriptions of the mechanism of biomass processing pathway, optimization, and modeling study have been discussed.

A comprehensive review on sources, analysis and toxicity of environmental pollutants and its removal methods from water environment.

Natural and human anthropogenic activities increase the concentration of the toxic pollutant in the water environment; they could cause harmful effects even in their lower concentration. In humans, toxic pollutants damage the structural and functional properties of essential organs including the heart, liver, kidneys, reproductive systems and pancreas. To avoid the toxicity of the pollutant, they should be removed from the water environment. Since various conventional water/wastewater treatment technologies including precipitation, ion exchange, flocculation, filtration, electrodialysis and membrane separation are employed to reduce the concentration of the pollutant, they have various difficulties in implementation, efficiency and ecological perspective. Therefore, several researchers are now focusing on alternative and eco-friendly approach called biosorption to remove toxic contaminants from the water environment. The biosorption innovation is one of the acclaimed systems for water treatment. The noteworthy endeavours have been made throughout the years to grow profoundly particular and effective biosorbent materials that are more effective, abundantly available, and cost-effective. Biosorption is effectively executed by utilizing both living and dead biomasses of bacteria, fungi and algae. Moreover, agro-waste materials are also utilized as biosorbents due to their excellent surface properties, abundant availability and cost-effectiveness. A variety of physical and chemical treatments enhances the biosorption capabilities of biosorbents via modifying their surface properties. In this review, biosorption mechanism, influencing parameters and application of biosorbent materials towards the removal of toxic pollutants are discussed. The future research opportunities for sustainable wastewater treatment were also explained.

A review on synthesis methods and recent applications of nanomaterial in wastewater treatment: Challenges and future perspectives.

Freshwater has been incessantly polluted by various activities such as rapid industrialization, fast growth of population and agricultural activities. Water pollution is considered as one the major threatens to human health and aquatic bodies which causes various severe harmful diseases including gastrointestinal disorders, asthma, cancer, etc. The polluted wastewater could be treated by different conventional and advanced methodologies. Amongst them, adsorption is the most utilized low cost, efficient technique to treat and remove the harmful pollutants from the wastewater. The efficiency of adsorption mainly depends on the surface properties such as functional group availability and surface area of the adsorbents used. Since various waste-based carbon derivatives are utilized as adsorbents for harmful pollutants removal; nanomaterials are employed as effective adsorbents in recent times due to its excellent surface properties. This review presents an overview of the different types of nanomaterials such as nano-particles, nanotubes, nano-sheets, nano-rods, nano-spheres, quantum dots, etc. which have been synthesized by different chemical and green synthesis methodologies using plants, microorganisms, biomolecules and carbon derivatives, metals and metal oxides and polymers. By concentrating on potential research difficulties, this study offers a new viewpoint on fundamental field of nanotechnology for wastewater treatment applications. This review paper critically reviewed the synthesis of nanomaterials more importantly green synthesis and their applications in wastewater treatment to remove the harmful pollutants such as heavy metals, dyes, pesticides, polycyclic aromatic hydrocarbons, etc.

Insights on synthesis and applications of graphene-based materials in wastewater treatment: A review.

Graphene has excellent unique thermal, chemical, optical, and mechanical properties such as high thermal conductivity, high chemical stability, optical transmittance, high current density, higher surface area, etc. Due to their outstanding properties, the attention towards graphene-based materials and their derivatives in wastewater treatment has been increased in recent times. Different graphene-based materials such as graphene oxides, graphene quantum dots, graphene nanoplatelets, graphene nanoribbons and other graphene-based nanocomposites are synthesized through chemical vapor deposition, mechanical and electrochemical exfoliation of graphite. In this review, the specifics about the graphenes and their derivatives, the synthesis strategy of graphene-based materials are described. This review critically explained the applications of graphene-based materials in wastewater treatment. Graphene-based materials were utilized as adsorbents, electrodes, and photocatalysts for the efficient removal of toxic pollutants such as heavy metals, dyes, pharmaceutics, antibiotics, phenols, polycyclic aromatic hydrocarbons have been highlighted and discussed. Herein, the potential scope of graphene-based material in the field of wastewater treatment is critically reviewed. In addition, a brief perspective on future research directions and difficulties in the synthesis of graphene-based material are summarized.

Mixed biosorbent of agro waste and bacterial biomass for the separation of Pb(II) ions from water system.

Adsorption of Pb(II) ions in aqueous systems by newly developed mixed biomass has been explored. Mixed biomass was prepared from agro-waste (raw Banyan tree bark, RBTB) and bacterial biomass (Pannonibacter phragmitetus). Chemical modification by sulphuric acid treatment of raw banyan tree bark (SMBTB) was accomplished for the effective separation of toxic Pb(II) ions from the aquatic system. FTIR, SEM and EDX analysis was utilized to deduce sorption characteristics of mixed biomass. Pb(II) ions maximal removal has occurred at pH-6.0, lead (II) ions concentration-25 mg/L, time and mixed biomass dosage (60 min and 3.5 g/L for RBTB - Pannonibacter phragmitetus; 30 min and 1.5 g/L for SMBTB - Pannonibacter phragmitetus) and temperature (30 °C). Data from equilibrium isotherm and kinetic analysis was best suited to the Langmuir model and pseudo-first-order kinetics. The spontaneous and exothermic nature of Pb(II) ions removal was described by thermodynamic parameters. The mixed biomass proved to be an effective and potential mixed biosorbent for toxic lead removal from solutions.

Adsorption characteristics of magnetic nanoparticles coated mixed fungal biomass for toxic Cr(VI) ions in aquatic environment.

In this research, the adsorptive removal of Cr(VI) ions from the aquatic environment have been studied using newly synthesized magnetic nanoparticles coated mixed fungal biomass (MNP-FB). Two fungal biomass such as Aspergillus fumigatus and Aspergillus niger were isolated, screened, and utilized as a precursor for making an adsorbent. Molecular characterization of isolated fungal species was recognized using 18S rRNA sequencing. The characterization studies of the MNP-FB were evaluated using Fourier Transform Infrared Spectrophotometer (FTIR) and Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) analyses. Optimization studies were studied to check the effect of different operating variables such as pH (2.0-9.0), equilibrium time (10-90 min), MNP-FB dosage (0.1-1.0 g/L), temperature (30-60 °C) and concentration of Cr(VI) ions (50-500 mg/L). Additionally, Freundlich isotherm model fits well for the adsorption of Cr(VI) ion using MNP-FB. The adsorption kinetics was interpreted well by Pseudo-first order model. The thermodynamic study concluded that Cr(VI) ions removal by MNP-FB was exothermic and appreciative at low temperatures. The monolayer adsorption efficiency of MNP-FB for Cr(VI) ions was measured as 249.9 mg/g. The current results reveal that MNP-FB has considered being a proficient and economically suitable material for the Cr(VI) ions removal from the water environment.

A review on catalytic-enzyme degradation of toxic environmental pollutants: Microbial enzymes.

Industrialization and other human anthropogenic activities cause serious threats to the environment. The toxic pollutants can cause detrimental diseases on diverse living beings in their respective ecosystems. Bioremediation is one of the efficient remediation methods in which the toxic pollutants are removed from the environment by the application of microorganisms or their biologically active products (enzymes). Typically, the microorganisms in the environment produce various enzymes to immobilize and degrade the toxic environmental pollutants by utilizing them as a substrate for their growth and development. Both the bacterial and fungal enzymes can degrade the toxic pollutants present in the environment and convert them into non-toxic forms through their catalytic reaction mechanism. Hydrolases, oxidoreductases, dehalogenases, oxygenases and transferases are the major classes of microbial enzymes responsible for the degradation of most of the toxic pollutants in the environment. Recently, there are different immobilizations and genetic engineering techniques have been developed to enhance enzyme efficiency and diminish the process cost for pollutant removal. This review focused on enzymatic removal of toxic pollutants such as heavy metals, dyes, plastics and pesticides in the environment. Current trends and further expansion for efficient removal of toxic pollutants through enzymatic degradation are also reviewed in detail.

Adsorptive removal of Pb(II) ions onto surface modified adsorbents derived from Cassia fistula seeds: Optimization and modelling study.

Cassia fistula seeds has been utilized for the abstraction of Pb(II) ions from the aqueous environment. Raw Cassia fistula seeds (RCF) and three different surface modified (physically treated - PMCF and chemically treated - HMCF and SMCF) adsorbent material were taken for investigation. The adsorption properties of these materials and their contact amongst the Pb(II) ion and sorbent materials were characterized by FTIR and SEM analysis. The parameters influencing the adsorption capacity of varied adsorbents were evaluated: maximum solution pH for Pb(II) is 5.0; interactive time is 30 min; dosage is 8.0 g/L for RCF, 4.0 g/L for HMCF, 2.5 g/L for PMCF and 1.0 g/L for SMCF. The modelling study reveals that Freundlich isotherm and Pseudo first order kinetics fits well and the utmost adsorption measurements for the varied adsorbents were found to be 13.22, 28.28, 48.66 and 129.3 mg/g, respectively.

Effective water/wastewater treatment methodologies for toxic pollutants removal: Processes and applications towards sustainable development.

Release of pollutants due to inflating anthropogenic activities has a conspicuous effect on the environment. As water is uniquely vulnerable to pollution, water pollution control has received a considerable attention among the most critical environmental challenges. Diverse sources such as heavy metals, dyes, pathogenic and organic compounds lead to deterioration in water quality. Demand for the pollutant free water has created a greater concern in water treatment technologies. The pollutants can be mitigated through physical, chemical and biological methodologies thereby alleviating the health and environmental effects caused. Diverse technologies for wastewater treatment with an accentuation on pre-treatment of feedstock and post treatment are concisely summed up. Pollutants present in the water can be removed by processes some of which include filtration, reverse osmosis, degasification, sedimentation, flocculation, precipitation and adsorption. Membrane separation and adsorption methodologies utilized to control water pollution and are found to be more effective than conventional methods and established recovery processes. This audit relatively features different methodologies that show remarkable power of eliminating pollutants from wastewater. This review describes recent research development on wastewater treatment and its respective benefits/applications in field scale were discussed. Finally, the difficulties in the enhancement of treatment methodologies for pragmatic commercial application are recognized and the future viewpoints are introduced.

Ultrasonic assisted agro waste biomass for rapid removal of Cd(II) ions from aquatic environment: Mechanism and modelling analysis.

In this research, dragon fruit peel, an agro-waste was used to prepare the new adsorbent for the removal of Cd(II) ions from the aquatic environment. The characterization techniques of SEM, FTIR and EDX for the prepared materials have been studied. The influential parameters for Cd(II) ions were experimented and identified the probable conditions for the maximum adsorption of Cd(II) ions. The investigations on isotherms, kinetics, and thermodynamics for Cd(II) ions removal were examined. Adsorption isotherm data was well discussed with Langmuir model based on the obtained good correlation coefficient and error values. Moreover, it follows the pseudo-first-order and exothermic process. The values of monolayer adsorption capacity of surface-modified dragon fruit peel (SMDFP) and ultrasonic-assisted dragon fruit peel (UADFP) was determined to be 7.469 and 24.76 mg/g at an equilibrium condition, respectively. This study exposed that ultrasonic-assisted dragon fruit peel can be a suitable adsorbent for Cd(II) ions removal from the water environment.

A review on algal-bacterial symbiotic system for effective treatment of wastewater.

Industrialization, urbanization and other anthropogenic activities releases different organic and inorganic toxic chemicals into the environment which prompted the water contamination in the environment. Different physical and chemical techniques have been employed to treat the contaminated wastewater, among them biological wastewater treatment using algae has been studied extensively to overwhelm the constraints related to the usually utilized wastewater treatment techniques. The presence of bacterial biota in the wastewater will form a bond with algae and act as a natural water purification system. The removal efficiency of single algae systems was very low in contrast with that of algal-bacterial systems. Heterotrophic microorganisms separate natural organic matter that is discharged by algae as dissolved organic carbon (DOC) and discharges CO2 that the algae can take up for photosynthesis. Algae bacteria associations offer an exquisite answer for tertiary and scrape medicines because of the capacity of micro-algae to exploit inorganic compounds for their development. Furthermore, for their ability to evacuate noxious contaminants, in this way, it does not prompt optional contamination. The present review contribute the outline of algae-bacteria symbiotic relationship and their applications in the wastewater treatment. The role of algae and bacteria in the wastewater treatment have been elucidated in this review. Moreover, the efforts have been imparted the importance of alage-bacteria consortium and its applications for various pollutant removal from the environment.

Simultaneous removal of Cu(II) and reactive green 6 dye from wastewater using immobilized mixed fungal biomass and its recovery.

Immobilized fungal biomass (Aspergillus niger and Aspergillus flavus) was prepared and analysed for the simultaneous removal of Cu(II) ion and Reactive Green 6 dye from aqueous phase. Different characterization analysis was utilized to exploit the adsorption characteristics of fungal biomass. Batch biosorption tests, performed to investigate the factors influencing biosorption process inferred optimal values of 25 mg/L of adsorbate with equilibrium time of 60 min, 2.5 g of immobilized fungal biomass, temperature of 303 K and pH of 5.0 for the maximal removal of pollutants. The obtained experimental data was utilized to evaluate the kinetic, thermodynamic and equilibrium models. Langmuir isotherm model has higher correlation coefficient [Cu(II) ion = 0.8625 and RG 6 dye = 0.8575] with small values of errors (RMSE = 3.746 and SSE = 56.12 for Cu(II) ion; RMSE = 4.872 and SSE = 11.87 for RG 6 dye). Kinetic studies performed to evaluate the adsorption rate mechanism of this present study indicated that pseudo-first order and pseudo-second order kinetics to be most fitting model for removal of Cu(II) ions and Reactive green dye respectively. Thermodynamic analysis inferred the spontaneous, random, and exothermic nature of the biosorption process based on ΔGo, ΔHo, and ΔSo values respectively. The prepared biomass can be an alternative for the elimination of toxic pollutants from wastewater.

A review on biosynthesis of metal nanoparticles and its environmental applications.

Nanotechnology has become one of the emerging multi-disciplinary fields receiving universal attention and playing a substantial role in agriculture, environment and pharmacology. In spite of various techniques employed for nanoparticle synthesis such as laser ablation, mechanical milling, spinning and chemical deposition, usage of hazardous chemicals and expensiveness of the process makes it unsuitable for the continuous production. Hence the necessity of sustainable, economic and environment friendly approach development have increased in recent years. Microbial synthesis of nanoparticles connecting microbiology and nanotechnology is one of the green techniques employed for sustainable production. Gold, silver and other metal nanoparticles like platinum, palladium, molybdenum nanoparticles biosynthesis by bacteria, fungi, yeast and algae have been reported in the present review. On account of microbial rich community, several microbes have been explored for the production of nanoparticles. Nanoparticles are also employed for environmental remediation processes such as pollutant removal and detection of contaminants. Lack of monodispersity and prolonged duration of synthesis are the limitations of bio-synthesis process which can be overcome by optimization of methods of microbial cultivation and its extraction techniques. The current review describes the different microbes involved in the synthesis of nanoparticles and its environmental applications.

Sequestration of toxic Pb(II) ions using ultrasonic modified agro waste: Adsorption mechanism and modelling study.

Treating the effluents from industries by using biological and agricultural wastes is an emerging field of research. In this study, three different biosorbents are prepared from tamarind seeds such as; raw, sulphuric acid-modified and ultrasonic-assisted surface-modified tamarind seed powder has been utilized to expel the Pb (II) ions from synthetic solution. The surface characteristics of the newly synthesized raw and surface modified agro-waste biomass were studied by FTIR and SEM. An experimental study was carried out to investigate the effect of different parameters on adsorption of Pb(II) ions using raw, sulphuric acid-modified and ultrasonic-assisted surface-modified tamarind seeds. The maximum Pb(II) ions adsorption was found at pH - 6.0, temperature - 303 K, biosorbent dosage - 3.5 g/L and contact time - 60 min for raw tamarind seeds and 30 min for sulphuric acid-modified and ultrasonic-assisted surface-modified tamarind seeds. The adsorption mechanism was described by Langmuir isotherm and pseudo-first order kinetic model. Among the three biosorbents, ultrasonic-assisted surface-modified tamarind seeds show higher adsorption capacity (18.86 mg/g) of Pb(II) ions removal from the synthetic solution. The thermodynamic study declared that the present Pb(II) ions adsorption onto the prepared biosorbents was spontaneous, exothermic and followed physical adsorption process. Results have shown that tamarind seed was found to be the best adsorbent in the expulsion of Pb(II) ions from the wastewater environment.