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1.
J Environ Manage ; 230: 128-150, 2019 Jan 15.
Artigo em Inglês | MEDLINE | ID: mdl-30286344

RESUMO

Treatment of toxic and emerging pollutants (T&EPs) is increasing the threats to the survival of conventional wastewater treatment (WWTs) technologies. The high installation and operational costs of advanced treatment technologies have shifted the research interest to the development of economical and reliable technology for management of T&EPs. Thus, recently biogenic nanoparticles (BNPs) fabricated using microbes/microorganisms are getting tremendous research interest due to their unique properties (i.e. high specific surface area, desired morphology, catalytic reactivity) for the biodegradation and biosorption of T&EPs. In addition, BNPs can be manufactured using metal contaminated water which indicates a hidden potential for resource recovery and utilization. Therefore, the present study discusses the adsorptive and catalytic performance of BNPs in the removal of T&EPs from water (W) and wastewater (WW). In addition, inspired by the superior performance of BNPs in advance WWT, a model of BNPs based WWT resource recovery and utilization process is also proposed. Finally, main issues i.e. mass production, leaching, poisoning/toxicity, regeneration, reusability and fabrication costs and process optimization are discussed which are main hinders in the transfer of BNPs based WWT technologies from laboratory to commercial scale.


Assuntos
Nanopartículas , Águas Residuárias , Água/metabolismo , Adsorção , Biodegradação Ambiental
2.
J Environ Manage ; 234: 273-289, 2019 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-30634120

RESUMO

Current research is based on an innovative approach of the fabrication of encapsulated sustainable, green, phytogenic magnetic nanoparticles (PMNPs), to inhibit the generation of secondary pollutants (Iron/Feo) during water treatment applications. These novel bio-magnetic membrane capsules (BMMCs) were prepared using two-step titration gel crosslink method, with polyvinyl alcohol and sodium alginate matrix as the model encapsulating materials to eliminate potentially toxic metals (Pb2+ and Cd2+) from water. The development of BMMCs was characterized by FTIR, XRD, XPS, SEM, VSM, TGA and EDX techniques. The effects of various operating parameters, adsorbent dose, contact time, solution pH, temperature, initial concentration of metals cations and co-existing ions were studied. The hysteresis loops have illustrated an excellent super-paramagnetic nature, demonstrating the smooth encapsulation of PMNPs without losing their magnetic properties. The maximum monolayer adsorptive capacities estimated at pH 6.5 by the Langmuir isotherm model were 548 and 610.67 mg/g for Pb2+ and Cd2+, respectively. The novel BMMCs did not only control oxidation of PMNPs but also sustained the adsorptive removal over a wide range of pH (3-8), and the electrostatic interaction and ion-exchange were the core adsorption mechanisms. The BMMCs could easily be regenerated using 25% HNO3 as an eluent for successful usage in seven repeated cycles. Therefore, the BMMCs as a material can be used as an excellent sorbent or composite material to remove toxic metals Pb2+ and Cd2+, showing strong potential for improving water and wastewater treatment technologies.


Assuntos
Nanopartículas de Magnetita , Poluentes Químicos da Água , Purificação da Água , Adsorção , Cádmio , Concentração de Íons de Hidrogênio , Cinética , Chumbo , Água
3.
J Basic Microbiol ; 57(8): 643-652, 2017 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-28464298

RESUMO

Magnetotactic bacteria (MTB) have started to be employed for the biosynthesis of magnetic nanoparticles, due to the rapidly increasing demand for nanoparticles in biomedical, biotechnology and environmental protection. MBT are the group of prokaryotes that have the ability to produce bio-magnetic minerals or bio-magnetic crystals of either magnetite (Fe3 O4 ) or greigite (Fe3 S4 ) in numerous shapes and size ranges, known as magnetosomes (MS). MS compel MTB to respond to the applied external magnetic field. However, it is extremely difficult to grow MTB and produce high yield of MS under artificial environmental conditions, thus creating a major hurdle to relocate MTB technology from laboratory scale to industrial or commercial level. Therefore, to best of our knowledge this review is the first attempt to highlight existing research developments about the laboratory scale and mass production of MS by MTB. Moreover, the optimum culture media and environmental conditions used for the cultivation of MTB were also considered. Finally, future research is encouraged for the improvement of MS yield which will result in the development of advanced nanotechnology/magnetotechnology.


Assuntos
Bactérias/crescimento & desenvolvimento , Bactérias/isolamento & purificação , Magnetossomos/metabolismo , Bactérias/metabolismo , Técnicas Bacteriológicas , Meios de Cultura , Óxido Ferroso-Férrico/metabolismo , Ferro/metabolismo , Magnetismo , Nanopartículas/química , Nanotecnologia , Filogenia , Sulfetos/metabolismo
4.
Cureus ; 15(9): e45481, 2023 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-37859881

RESUMO

Introduction Traditionally, injuries have often been perceived as random and inevitable 'accidents'. However, in the current context, both intentional and unintentional injuries are preventable. Among these, neck injuries can be particularly complex, encompassing homicidal, suicidal, or accidental causes. Despite extensive research on the different modes and patterns of cut-throat injuries in the general population, this study aims to look deeper into this phenomenon within a unique context. Our investigation is centered in the Eastern part of India, among a tribal-dominated population who live with their traditional culture. Method In this prospective observational study, 50 cut-throat patients were included, who reported to the emergency department and then were referred to the ENT department. Parameters such as age, sex, anatomical location, mode of cut-throat injury, prior substance abuse, psychiatric issues, socioeconomic level, and length of hospital stay were considered for analysis. Results The majority (n=40, 80%) of patients belonged to tribal communities and most were young adults. Cut-throat injuries were predominantly caused by suicide (n=36, 72%) and homicide (n=12, 24%). Among tribals, 85% (n=34) of the cases were suicidal. Among suicidal cases, 86.11% (n=31) had a history of substance abuse while 22.22% (n=8) had a history of psychiatric illnesses. Conclusion In Eastern India, among the tribal-dominated population, suicide emerges as the predominant mode of cut-throat injuries, which is notably distinct from patterns observed in the general population of developing countries. These were often associated with substance abuse. Future interventions and public health efforts in these regions should consider these factors in the development of targeted strategies aimed at prevention and support for at-risk individuals.

5.
J Saudi Heart Assoc ; 32(2): 194-199, 2020.
Artigo em Inglês | MEDLINE | ID: mdl-33154915

RESUMO

Chylothorax after coronary artery bypass grafting is a rare complication and leads to increased mortality and morbidity. Because of the rarity of this complication, its management is debatable. We present the case of a 41 years old male patient who had a left sided chylothorax after coronary artery bypass grafting. The patient was managed conservatively with low fat diet and drainage of the chylothorax. A thorough search of the literature published on the subject was done and treatment strategies employed by various authors were studied. Various treatment options are conservative management with chest tube drainage, octreotide and low-fat diet or diet containing medium chain triglycerides. Invasive options are video assisted thoracoscopy and thoracotomy with or without ligation of thoracic duct. An account of the management strategies employed by various authors is presented in this report.

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