Soluble Fluorinated Cardo Copolyimide as an Effective Additive to Photopolymerizable Compositions Based on Di(meth)acrylates: Application for Highly Thermostable Primary Protective Coating of Silica Optical Fiber.

The development of photocurable compositions is in high demand for the manufacture of functional materials for electronics, optics, medicine, energy, etc. The properties of the final photo-cured material are primarily determined by the initial mixture, which needs to be tuned for each application. In this study we propose to use simple systems based on di(meth)acrylate, polyimide and photoinitiator for the preparation of new photo-curable compositions. It was established that a fluorinated cardo copolyimide (FCPI) based on 2,2-bis-(3,4-dicarboxydiphenyl)hexafluoropropane dianhydride, 9,9-bis-(4-aminophenyl)fluorene and 2,2-bis-(4-aminophenyl)hexafluoropropane (1.00:0.75:0.25 mol) has excellent solubility in di(met)acrylates. This made it possible to prepare solutions of FCPI in such monomers, to study the effect of FCPI on the kinetics of their photopolymerization in situ and the properties of the resulting polymers. According to the obtained data, the solutions of FCPI (23 wt.%) in 1,4-butanediol diacrylate (BDDA) and FCPI (15 wt.%) in tetraethylene glycol diacrylate were tested for the formation of the primary protective coatings of the silica optical fibers. It was found that the new coating of poly(BDDA-FCPI23%) can withstand prolonged annealing at 200 °C (72 h), which is comparable or superior to the known most thermally stable photo-curable coatings. The proposed approach can be applied to obtain other functional materials.

10-µJ-level femtosecond pulse generation in the erbium CPA fiber source with microstructured hollow-core fiber assisted delivery and nonlinear frequency conversion.

We report on the development of a chirped pulse amplification (CPA) designed erbium fiber source with a hybrid high-power amplifier, which is composed of erbium-doped and erbium/ytterbium-co-doped double-clad large-mode-area fibers. Stretched pulses from the high-power amplifier with up to 21.9 µJ energy and 198.5 kHz repetition rate are dechirped in the transmission grating pair-based compressor with 73% efficiency, yielding as short as 742 fs duration with 15.8 µJ energy and ≈13M W peak power (maximum average power up to 3.14 W) at the central wavelength of 1.56 µm. Compressed pulses are coupled into microstructured negative-curvature hollow-core fibers with a single row capillary cladding and different core sizes of 34 µm and 75 µm in order to realize femtosecond pulse delivery with a diffraction-limited output beam (M 2≤1.09) and demonstrate ∼200n J Stokes pulse generation at 1712 nm via rotational SRS in pressurized hydrogen (H 2). We believe that the developed system may be a prospect for high-precision material processing and other high-energy and high-peak-power laser applications.

Chlorophyll fluorometry in evaluating photosynthetic performance: key limitations, possibilities, perspectives and alternatives.

Non-destructive methods for the assessment of photosynthetic parameters of plants are widely applied to evaluate rapidly the photosynthetic performance, plant health, and shifts in plant productivity induced by environmental and cultivation conditions. Most of these methods are based on measurements of chlorophyll fluorescence kinetics, particularly on pulse modulation (PAM) fluorometry. In this paper, fluorescence methods are critically discussed in regard to some their possibilities and limitations inherent to vascular plants and microalgae. Attention is paid to the potential errors related to the underestimation of thylakoidal cyclic electron transport and anoxygenic photosynthesis. PAM-methods are also observed considering the color-addressed measurements. Photoacoustic methods are discussed as an alternative and supplement to fluorometry. Novel Fourier modifications of PAM-fluorometry and photoacoustics are noted as tools allowing simultaneous application of a dual or multi frequency measuring light for one sample.

Application of Negative Curvature Hollow-Core Fiber in an Optical Fiber Sensor Setup for Multiphoton Spectroscopy.

In this paper, an application of negative curvature hollow core fiber (NCHCF) in an all-fiber, multiphoton fluorescence sensor setup is presented. The dispersion parameter (D) of this fiber does not exceed the value of 5 ps/nm × km across the optical spectrum of (680-750) nm, making it well suited for the purpose of multiphoton excitation of biological fluorophores. Employing 1.5 m of this fiber in a simple, all-fiber sensor setup allows us to perform multiphoton experiments without any dispersion compensation methods. Multiphoton excitation of nicotinamide adenine dinucleotide (NADH) and flavin adenine dinucleotide (FAD) with this fiber shows a 6- and 9-fold increase, respectively, in the total fluorescence signal collected when compared with the commercial solution in the form of a hollow-core photonic band gap fiber (HCPBF). To the author's best knowledge, this is the first time an NCHCF was used in an optical-fiber sensor setup for multiphoton fluorescence experiments.

Light transmission in negative curvature hollow core fiber in extremely high material loss region.

In this paper we demonstrate the light transmission in a spectral range of 2.5 to 7.9 µm through a silica negative curvature hollow core fiber (NCHCF) with a cladding consisting of eight capillaries. A separation between the cladding capillaries was introduced to remove the additional resonances in the transmission bands. The measured optical loss at 3.39 µm was about 50 dB/km under a few modes waveguide regime.

Demonstration of a waveguide regime for a silica hollow--core microstructured optical fiber with a negative curvature of the core boundary in the spectral region > 3.5 µm.

We present a numerical and experimental demonstration of a waveguide regime in a broad band spectral range for the hollow core microstructured optical fibers (HC MOFs) made of silica with a negative curvature of the core boundary. It is shown that HC MOFs with the cladding consisting only of one row of silica capillaries allows to guide light from the near to mid infrared despite of high material losses of silica in this spectral region. Such result can be obtained by a special arrangement of cladding capillaries which leads to a change in the sign of the core boundary curvature. The change in the sign of the core boundary curvature leads to a loss of simplicity of boundary conditions for core modes and to "localization" and limitation of their interaction with the cladding material in space. Such HC MOFs made of different materials can be potential candidates for solving problem of ultra high power transmission including transmission of CO and CO2 laser radiation.

Demonstration of CO2-laser power delivery through chalcogenide-glass fiber with negative-curvature hollow core.

A technologically simple optical fiber cross-section structure with a negative-curvature hollow-core has been proposed for the delivery of the CO2 laser radiation. The structure was optimized numerically and then realized using Te20As30Se50 (TAS) chalcogenide glass. Guidance of the 10.6 µm СО2-laser radiation through this TAS-glass hollow-core fiber has been demonstrated. The loss at λ=10.6 µm was amounted ~11 dB/m. A resonance behavior of the fiber bend loss as a function of the bend radius has been revealed.

Broadband wavelength conversion in a germanosilicate-core photonic crystal fiber.

A photonic crystal fiber with a germanosilicate core having a nonlinear coefficient of 40 (W km)(-1) near the single dispersion zero at 1.09 microm is fabricated and studied. Broadband parametric wavelength conversion of the Ti:sapphire laser output tunable at 0.8 microm to the 1.55 microm band is obtained at 1.064 microm cw pump. The tuning of the converted signal in the 300 nm range was first realized without variation of the pump wavelength.

High-average-power second-harmonic generation from periodically poled silica fibers.

The generation of 236 mW of second-harmonic power in a 32-cm-long periodically poled silica fiber, corresponding to an average conversion efficiency of 15.2+/-0.5%, is reported. This represents the highest normalized second-harmonic conversion and the highest average second-harmonic power ever reported for a periodically poled silica fiber, to our knowledge. The enhancement is attributed to an improved design of the specialty twin-hole fiber and the extension of the nonlinear interaction length.