Electrochemical transformation of individual nanoparticles revealed by coupling microscopy and spectroscopy.

Although extremely sensitive, electrical measurements are essentially unable to discriminate complex chemical events involving individual nanoparticles. The coupling of electrochemistry to dark field imaging and spectroscopy allows the triggering of the electrodissolution of an ensemble of Ag nanoparticles (by electrochemistry) and the inference of both oxidation and dissolution processes (by spectroscopy) at the level of a single nanoparticle. Besides the inspection of the dissolution process from optical scattering intensity, adding optical spectroscopy reveals chemical changes through drastic spectral changes. The behaviours of single NPs and NP agglomerates are differentiated: in the presence of thiocyanate ions, the transformation of Ag single nanoparticles to AgSCN is investigated in the context of plasmonic coupling with the electrode; tentative interpretations for optically unresolved groups of nanoparticles are proposed.

Deciphering the Elementary Steps of Transport-Reaction Processes at Individual Ag Nanoparticles by 3D Superlocalization Microscopy.

Transport-reaction processes at individual Ag nanoparticles (NPs) are studied using electrochemistry coupled with in situ 3D light scattering microscopy. Electrochemistry is used to trigger a (i) diffusiophoretic transport mode capable of accelerating and preconcentrating NPs toward an electrode and (ii) subsequent diffusion-controlled oxidation of NPs. Individual NP dissolution rate, analyzed using optical modeling, suggests the intervention of insoluble products. New insights into diverse NPs behaviors highlight the strength of coupled optical-electrochemical 3D microscopies for single-NP studies.

Excitability in a semiconductor laser with saturable absorber.

We show that a monolithic and compact vertical cavity laser with intracavity saturable absorber can emit short excitable pulses. These calibrated optical pulses can be excited as a response to an input perturbation whose amplitude is above a certain threshold. Subnanosecond excitable response is promising for applications to novel all-optical devices for information processing or logical gates.

Precursor forms of cavity solitons in nonlinear semiconductor microresonators.

We study the transverse nonlinear dynamics of bulk and multi-quantum well AlGaAs microresonators, in the mixed dispersive and saturable absorptive regime, slightly below the band-gap edge energy. With a Gaussian beam excitation we observe strongly localized states of various shapes, bright or dark in reflection. Their dynamics appears to be ruled by strong thermally induced nonlinear mechanisms, acting as a dressing mechanism for electronic nonlinearities. Precursor forms of cavity solitons are also identified.

Optical bistability in a GaAs-based polariton diode.

We report on a new type of optical nonlinearity in a polariton p-i-n microcavity. Abrupt switching between the strong and weak coupling regime is induced by controlling the electric field within the cavity. As a consequence, bistable cycles are observed for low optical powers (2-3 orders of magnitude less than for Kerr induced bistability). Signatures of switching fronts propagating through the whole 300 x 300 microm2 mesa surface are evidenced.