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As lithium-ion batteries continue to climb to even higher energy density, they meanwhile cause serious concerns on their stability and reliability during operation. To make sure the electrode materials, particularly cathode materials, are stable upon extended cycles, surface modification becomes indispensable to minimize the undesirable side reaction at the electrolyte-cathode interface, which is known as a critical factor to jeopardizing the electrode performance. This Review is targeted at a precise surface control of cathode materials with focus on the synthetic strategies suitable for a maximized surface protection ensured by a uniform and conformal surface coating. Detailed discussions are taken on the formation mechanism of the designated surface species achieved by either wet-chemistry routes or instrumental ones, with attention to the optimized electrochemical performance as a result of the surface control, accordingly drawing a clear image to describe the synthesis-structure-performance relationship to facilitate further understanding of functional electrode materials. Finally, perspectives regarding the most promising and/or most urgent developments for the surface control of high-energy cathode materials are provided.
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K-ion batteries (KIBs) are now drawing increasing research interest as an inexpensive alternative to Li-ion batteries (LIBs). However, due to the large size of K+, stable electrode materials capable of sustaining the repeated K+ intercalation/deintercalation cycles are extremely deficient especially if a satisfactory reversible capacity is expected. Herein, we demonstrated that the structural engineering of carbon into a hollow interconnected architecture, a shape similar to the neuron-cell network, promised high conceptual and technological potential for a high-performance KIB anode. Using melamine-formaldehyde resin as the starting material, we identify an interesting glass blowing effect of this polymeric precursor during its carbonization, which features a skeleton-softening process followed by its spontaneous hollowing. When used as a KIB anode, the carbon scaffold with interconnected hollow channels can ensure a resilient structure for a stable potassiation/depotassiation process and deliver an extraordinary capacity (340 mAh g-1 at 0.1 C) together with a superior cycling stability (no obvious fading over 150 cycles at 0.5 C).
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Hollow nanostructures of metal oxides have found broad applications in different fields. Here, we reported a facile and versatile synthetic protocol to prepare hollow metal oxide nanospheres by modulating the chemical properties in solid nanoparticles. Our synthesis design starts with the precipitation of urea-containing metal oxalate, which is soluble in water but exists as solid nanospheres in ethanol. A controlled particle hydrolysis is achieved through the heating-induced urea decomposition, which transforms the particle composition in an outside-to-inside style: The reaction starts from the surface and then proceeds inward to gradually form a water-insoluble shell of basic metal oxalate. Such a reaction-induced solubility difference inside nanospheres becomes highly efficient to create a hollow structure through a simple water wash process. A following high temperature treatment forms hollow nanospheres of different metal oxides with structural features suited to their applications. For example, a high performance anode for Li-ion intercalation pseudocapacitor was demonstrated with the hollow and mesoporous Nb2O5 nanospheres.
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Hollow hybrid microspheres have found great potential in different areas, such as drug delivery, nanoreactors, photonics, and lithium-ion batteries. Here, we report a simple and scalable approach to construct high-quality hollow hybrid microspheres through a previously unexplored growth mechanism. Starting from uniform solid microspheres with low crystallinity, we identified that a hollowing process can happen through the progressive inward crystallization process initiated on the particle surface: the gradual encroachment of the crystallization frontline toward the core leads to the depletion of the center and forms the central cavity. We showed that such a synthetic platform was versatile and can be applicable for a large variety of materials. By using the production of Li4Ti5O12-carbon hollow hybrid microspheres as an example, we demonstrated that high-performance anode materials could be achieved through synthesis and structure control. We expect that our findings offer new perspectives in different areas ranging from materials chemistry, energy storage devices, catalysis, to drug delivery.
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BACKGROUND: This study evaluates the effect of bowel preparation to colonoscopy time interval on quality of bowel preparation and outcomes of colonoscopy. METHODS: Studies were identified after a literature search in electronic databases and were selected for inclusion based on precise eligibility criteria. Meta-analyses of proportions were performed to achieve overall bowel preparation adequacy and adenoma/polyp detection rates. Odds ratios depicting associations between bowel preparation quality and bowel preparation to colonoscopy time were pooled to achieve an overall estimate. RESULTS: Twenty studies (10 341 individuals subjected to colonoscopy) were included. Bowel preparation adequacy rate was higher with shorter (94% [95% CI: 91, 97]) than with longer (84% [95% CI: 79, 89]) interval between bowel preparation and colonoscopy. In a subgroup analysis, <5, 6-10, 11-20, and >20 hours intervals were associated with 94% [95% CI: 92, 97], 92% [95% CI: 86, 96], 85% [95% CI: 77, 91], and 85% [95% CI: 75, 92] adequacy rates, respectively. A pooled analysis of odds ratios also showed that bowel preparations adequacy was significantly better with shorter bowel preparation to colonoscopy time (odds ratio 1.69 [95% CI: 1.23, 2.15]). There was no significant difference in adenoma detection rate between shorter (18% [95% CI: 9, 29]) and longer (19% [95% CI: 15, 22]) bowel preparation to colonoscopy intervals. Polyp detection rate was higher with shorter (47% [95% CI: 27, 68]) than with longer (30% [95% CI: 24, 38]) bowel preparation to colonoscopy interval. CONCLUSION: A shorter interval between bowel preparation and colonoscopy led to a higher bowel preparation adequacy rate which was also associated with a higher polyp detection rate.
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Catárticos , Colonoscopia , Humanos , Adenoma/diagnóstico , Catárticos/uso terapêutico , Colonoscopia/estatística & dados numéricos , Razão de Chances , Pólipos/diagnóstico , Fatores de Tempo , Resultado do TratamentoRESUMO
The sluggish kinetic of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) severely hampers the commercial application of electrochemical water splitting, promoting the urgent exploration of high-efficient bifunctional electrocatalysts. Heteroatom doping and structure engineering have been identified as the most effective strategies to boost the catalytic activity of electrocatalysts. Herein, Mn doping and hollow structure were integrated in the design of Co-based transition metal phosphide catalyst to prepare Mn-CoP/Co2P nanotubes (denoted as Mn-CP NTs) by a facile template-free method. Confirmed by characterization analysis, the introduced Mn species were in high dispersion in the regular CoP/Co2P hollow tubular framework. Such a favorable design in composition and structure effectively boosted the catalytic activity of Mn-CP NTs toward electrochemical water splitting. The Mn-CP NTs showed superior HER and OER activity demonstrated by the low overpotentials of 82 mV (vs HER) and 309 mV (vs OER) at the current density of 10 mA cm-2, as well as the satisfactory durability. When used as both cathode and anode in electrolyzer for overall water splitting, only a low cell voltage of 1.67 V was required for the Mn-CP NTs to drive 10 mA cm-2, accompanied with excellent stability confirmed by over 50 h test.
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A self-hollowing process was demonstrated for the creation of hollow MoS2 nanospheres starting from their amorphous solid precursor, which were spontaneously transformed into a hollow structure during the rearrangement of crystal lattices initiated by a high-temperature treatment, forming hollow-structured materials favorable for their application in sodium ion batteries.
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We have reported an efficient synthetic protocol to build different hollow hybrid nanocomposites with tunable compositions, such as Au/TiO2, Pt/ZrO2, and Au/CexTi1-xO2. The noble metal nanoparticles were well encapsulated in a wall composed of the designated transition metal oxides, showing promising potential as stable catalysts as demonstrated by Pt/ZrO2 for methane combustion.
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A surface doping strategy is demonstrated for the stabilization of LiMn2O4, which is achieved by the surface solid reaction between the LiMn2O4 particle and its ZnO nanoshell. The surface treated sample shows a much improved high temperature performance with evidently suppressed Mn dissolution.
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Surface cobalt doping is an effective and economic way to improve the electrochemical performance of cathode materials. Herein, by tuning the precipitation kinetics of Co2+, we demonstrate an aqueous-based protocol to grow uniform basic cobaltous carbonate coating layer onto different substrates, and the thickness of the coating layer can be adjusted precisely in nanometer accuracy. Accordingly, by sintering the cobalt-coated LiNi0.5Mn1.5O4 cathode materials, an epitaxial cobalt-doped surface layer will be formed, which will act as a protective layer without hindering charge transfer. Consequently, improved battery performance is obtained because of the suppression of interfacial degradation.
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We identified that the growth kinetics of ZrO2 could be well-tuned in a CH3COOH-CH3COONa based buffer solution, which provided an efficient way to build uniform ZrO2 nanoshells on various substrates. Using this synthetic strategy, yolk-shell structured Pd@ZrO2 is demonstrated as a promising catalyst for methane oxidation.
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This communication reports that the TiO2@polydopamine nanocomposite with a core-shell structure could be a highly active photocatalyst working under visible light. A very thin layer of polydopamine at around 1 nm was found to be critical for the degradation of Rhodamine B.
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Pd nanoparticles were successfully introduced into the channels of mesoporous silica MCM-41 with their dispersion well-tuned. We identified the dual role played by CTAB, which was critical for both the micelle template and Pd grafting, leading to the formation of a highly active Pd-MCM-41 nanocomposite for catalysing the Suzuki reaction.
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Nanopartículas Metálicas/química , Nanocompostos/química , Paládio/química , Dióxido de Silício/química , Catálise , Nanocompostos/ultraestrutura , PorosidadeRESUMO
Yolk-shell structured nanomaterials have shown interesting potential in different areas due to their unique structural configurations. A successful construction of such a hybrid structure relies not only on the preparation of the core materials, but also on the capability to manipulate the outside wall. Typically, for Al2O3, it has been a tough issue in preparing it into a uniform nanoshell, making the use of Al2O3-based yolk-shell structures a challenging but long-awaited task. Here, in benefit of our success in the controlled formation of Al2O3 nanoshell, we demonstrated that yolk-shell structures with metal confined inside a hollow Al2O3 nanosphere could be successfully achieved. Different metals including Au, Pt, Pd have been demonstrated, forming a typical core@void@shell structure. We showed that the key parameters of the yolk-shell structure such as the shell thickness and the cavity size could be readily tuned. Due to the protection of a surrounding Al2O3 shell, the thermal stability of the interior metal nanoparticles could be substantially improved, resulting in promising performance for the catalytic CO oxidation as revealed by our preliminary test on Au@Al2O3.