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Understanding particle size distribution (PSD) of total suspended sediments in urban runoff is essential for pollutant fate and designing effective stormwater treatment measures. However, the PSDs from different land uses under different weather conditions have yet to be sufficiently studied. This research conducted a six-year water sampling program in 15 study sites to analyze the PSD of total suspended sediments in runoff. The results revealed that the median particle size decreased in the order: paved residential, commercial, gravel lane residential, mixed land use, industrial, and roads. Fine particles less than 125 µm are the dominant particles (over 75%) of total suspended sediments in runoff in Calgary, Alberta, Canada. Roads have the largest percentage of particles finer than 32 µm (49%). Gravel lane residential areas have finer particle sizes than paved residential areas. The results of PSD were compared with previous literature to provide more comprehensive information about PSD from different land uses. The impact of rainfall event types can vary depending on land use types. A long antecedent dry period tends to result in the accumulation of fine particles on urban surfaces. High rainfall intensity and long duration can wash off more coarse particles. The PSD in spring exhibits the finest particles, while fall has the largest percentage of coarse particles. Snowmelt particles are finer for the same land use than that during rainfall events because the rainfall-runoff flows are usually larger than the snowmelt flows.
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Tamanho da Partícula , Chuva , Estações do Ano , Sedimentos Geológicos/análise , Sedimentos Geológicos/química , Movimentos da Água , Monitoramento Ambiental , AlbertaRESUMO
Microplastics (MPs) can be sheltered by bed grains, resulting in a higher threshold of mobilization compared with those moving on a smooth bed. Only one formula considering the sheltering effects has been proposed for the critical shear stress (τc) of MP mobilization by including the densities and sizes of MPs and bed grains, but it is inaccurate for MPs of certain materials such as PS and shows limitations in understanding the sheltering effects. Additionally, no method exists for the critical depth-averaged velocity (Uc). In this study, experiments were conducted measuring both τc and Uc of MPs (made of PA, PVC, and PET) deposited on rough beds of different roughnesses, with a focus on the sheltering effects. A power law relationship between τc and the density and size of MPs was found, and a new formula for estimating τc was proposed for MPs, which reduced the errors by approximately 40% compared with that of the previous formula (27.8%). To explicitly quantify the sheltering effects in MP mobilizations, hiddenness (ΔZ), exposure (ΔH), and longitudinal exposure (ΔX) were introduced, all of which were observed to follow a normal distribution. A semiempirical method for Uc was then proposed incorporating the new measures, which reduced the errors by around 70% compared to the methods developed for estimating the Uc values of sediments.
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The incipient motion threshold of microplastics (MPs), defined as the condition that is just sufficient to initiate MP movement, is key to assessing the transport and fate of MPs in water bodies, yet only a few studies have focused on its prediction. This study experimentally investigated the effects of bed roughness (smooth and rough beds) and MP properties (shapes, sizes, and densities) on the incipient velocity (Ui) and critical shear stress (τc) of exposed MPs in an open-channel flow. For a total of 19 types of MPs, Ui and τc were found to range from 0.06 to 0.21 m/s and 0.01 to 0.075 N/m2, respectively. The commonly used thresholds for sediment transport, for example, critical shield parameter Θc and movability number Λc, were established for MPs based on τc. Based on the experimental data of the literature and this study, it was found that predictions of Θc and Λc for sediments do not apply to MPs. A new explicit formula for Λc was proposed for predicting the incipient motion of MPs by introducing the dimensionless particle diameter (d*) and a new dimensionless parameter related to the particle size, density, and shape. The new formula has an absolute error of 12.3%, which is smaller than the existing formula for MPs (55.6%).
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Microplásticos , Poluentes Químicos da Água , Monitoramento Ambiental , Sedimentos Geológicos , Plásticos , Água , Poluentes Químicos da Água/análiseRESUMO
Urban stormwater models such as PCSWMM are important tools for evaluating urban stormwater quantity and quality. However, due to the lack of consideration of land covers, traditional catchment delineation methods have defects in model precision, parameter transferability and assessment of contribution from individual land cover types. This paper used PCSWMM model as a foundation, built a new land-cover based (LCB) model and made a systematic comparison with the traditional watershed delineation tool (WDT) model to study the impacts of land cover on the simulation of stormwater runoff and pollutant loading. The models were applied to two urban catchments in Calgary, Canada. The results revealed that the LCB model performed better than the WDT model in hydrological simulation, and land cover consideration can considerably improve model accuracy. The two models showed comparable performances in simulation of total suspended solids (TSS), total nitrogen (TN), and total phosphorus (TP) loading. The LCB model parameters could be regionalized based on land cover types. The hydrologic-hydraulic parameters can be satisfactorily transferred from neighboring gauged catchments to similar ungauged catchments. The transferring of water quality parameters did not perform as satisfactory. The LCB model could quantitively evaluate the contribution to runoff and pollutant loads of different land covers. Roads and roofs were found to be the major contributors to urban runoff and pollutants in the two urban catchments. Green space became important only during large storms events and its contribution could be ignored during dryer years.
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Poluentes Ambientais , Poluentes Químicos da Água , Monitoramento Ambiental , Hidrologia , Fósforo/análise , Chuva , Movimentos da Água , Poluentes Químicos da Água/análise , Qualidade da ÁguaRESUMO
Stratification is one of the fundamental physical processes that may have a significant impact on water quality in stormwater wet ponds. However, the role of thermal and chemical stratifications in governing water quality processes is not fully understood. This is in part due to the lack of detailed field measurements of sufficient governing parameters over time periods that span a wide range of environmental conditions. To fill this gap, a comprehensive 2-year field program was undertaken in two stormwater wet ponds in Calgary, Alberta, Canada, during the ice-free season from May to November in 2018 and 2019. At different locations in each pond, thermal and chemical stratifications were observed, thermocline depth and strength were determined, and continuous water velocity profiles were measured. In addition, the effect of local weather conditions on stratification, thermocline, and hydrodynamics was investigated. The results showed that the ponds had vertical water temperature differences >1 °C for 99% of the time, May to August. In addition, salt-laden inflows from road deicing salts led to strong chemical stratification up to five times stronger in the sediment forebays than in the main cells in spring. Wind-induced surface currents were insignificant, scaling at 0.3% of the wind speed with negligible impact on vertical mixing in the ponds. Our results demonstrate that the ponds' strong and prolonged stratification decreased pollutant retention capacity and caused the water at depth to become anoxic, degrading the quality of the water discharged downstream. Hence, additional consideration of stratification is required when designing new stormwater ponds.
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Lagoas , Poluentes Químicos da Água , Alberta , Sais , Poluentes Químicos da Água/análise , Qualidade da ÁguaRESUMO
Establishing the origin and function of unusual traits in fossil taxa provides a crucial tool in understanding macroevolutionary patterns over long periods of time. Ceratopsian dinosaurs are known for their exaggerated and often elaborate horns and frills, which vary considerably between species. Many explanations have been proposed for the origin and evolution of these 'ornamental' traits, from predator defence to socio-sexual dominance signalling and, more recently, species recognition. A key prediction of the species recognition hypothesis is that two or more species possessing divergent ornamental traits should have been at least partially sympatric. For the first time to our knowledge, we test this hypothesis in ceratopsians by conducting a comparison of the morphological characters of 46 species. A total of 350 ceratopsian cladistic characters were categorized as either 'internal', 'display' (i.e. ornamental) or 'non display'. Patterns of diversity of these characters were evaluated across 1035 unique species pairs. Display characters were found to diverge rapidly overall, but sympatric species were not found to differ significantly in their ornamental disparity from non-sympatric species, regardless of phylogenetic distance. The prediction of the species recognition hypothesis, and thus the idea that ornamentation evolved as a species recognition mechanism, has no statistical support among known ceratopsians.
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Evolução Biológica , Dinossauros/classificação , Dinossauros/genética , Simpatria , Animais , Biodiversidade , Dinossauros/anatomia & histologia , Fósseis , Cornos/anatomia & histologia , Modelos Estatísticos , Fenótipo , Filogenia , Análise de Regressão , Crânio/anatomia & histologiaRESUMO
Emerging epidemiological evidence reveals a link between lung disease and exposure to indoor pollutants such as perfluorinated compounds (PFCs). PFC exposure during critical developmental stages may increase asthma susceptibility. Thus, in a murine model, we tested the hypothesis that early life and continued exposure to two ubiquitous household PFCs, perfluorooctanoic acid (PFOA) and perflurooctanesulfonic acid (PFOS), can induce lung dysfunction that exacerbates allergen-induced airway hyperresponsiveness (AHR) and inflammation. Balb/c mice were exposed to PFOA or PFOS (4 mg/kg chow) from gestation day 2 to 12 wk of age by feeding pregnant and nursing dams, and weaned pups. Some pups were also sensitized and challenged with ovalbumin (OVA). We assessed lung function and inflammatory cell and cytokine expression in the lung and examined bronchial goblet cell number. PFOA, but not PFOS, without the OVA sensitization/challenge induced AHR concomitant with a 25-fold increase of lung macrophages. PFOA exposure did not affect OVA-induced lung inflammatory cell number. In contrast, PFOS exposure inhibited OVA-induced lung inflammation, decreasing total cell number in lung lavage by 68.7%. Interferon-γ mRNA in the lung was elevated in all PFC-exposed groups. Despite these effects, neither PFOA nor PFOS affected OVA-induced AHR. Our data do not reveal PFOA or PFOS exposure as a risk factor for more severe allergic asthma-like symptoms, but PFOA alone can induce airway inflammation and alter airway function.
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Poluentes Atmosféricos/toxicidade , Ácidos Alcanossulfônicos/toxicidade , Asma/imunologia , Caprilatos/toxicidade , Fluorocarbonos/toxicidade , Células Caliciformes/imunologia , Pulmão/imunologia , Exposição Materna/efeitos adversos , Animais , Asma/induzido quimicamente , Asma/patologia , Feminino , Células Caliciformes/patologia , Interferon gama/imunologia , Pulmão/patologia , Camundongos , Camundongos Endogâmicos BALB C , GravidezRESUMO
A new taxon of chasmosaurine ceratopsid demonstrates unexpected disparity in parietosquamosal frill shape among ceratopsid dinosaurs early in their evolutionary radiation. The new taxon is described based on two apomorphic squamosals collected from approximately time equivalent (approximately 77 million years old) sections of the upper Judith River Formation, Montana, and the lower Dinosaur Park Formation of Dinosaur Provincial Park, Alberta. It is referred to Chasmosaurinae based on the inferred elongate morphology. The typical chasmosaurine squamosal forms an obtuse triangle in dorsal view that tapers towards the posterolateral corner of the frill. In the dorsal view of the new taxon, the lateral margin of the squamosal is hatchet-shaped with the posterior portion modified into a constricted narrow bar that would have supported the lateral margin of a robust parietal. The new taxon represents the oldest chasmosaurine from Canada, and the first pre-Maastrichtian ceratopsid to have been collected on both sides of the Canada-US border, with a minimum north-south range of 380 km. This squamosal morphology would have given the frill of the new taxon a unique dorsal profile that represents evolutionary experimentation in frill signalling near the origin of chasmosaurine ceratopsids and reinforces biogeographic differences between northern and southern faunal provinces in the Campanian of North America.
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Dinossauros/anatomia & histologia , Fósseis , Crânio/anatomia & histologia , Alberta , Animais , Dinossauros/classificação , MontanaRESUMO
The joint effect of mixed land uses and rainfall event types was studied using a two-year field monitoring program in four urban catchments in Calgary, Alberta, Canada. Event mean concentration (EMC) and event pollutant load (EPL) were employed to evaluate the total suspended sediment (TSS), nitrogen and phosphorus. The correlation analysis showed that most nitrogen and phosphorus components (except for NO2-/NO3- and TDP) predominantly exist in particulate form in the study areas. The correlation for EPL was notably stronger than EMC, which can be attributed to varying rainfall characteristics. The differences in EMCs and EPLs of TSS, nitrogen and phosphorus across catchments indicated that the complexity and spatial distribution of mixed land use can influence the generation and transportation of pollutants in urban runoff. The impacts of rainfall characteristics on stormwater quality are integrated rather than driven by a single rainfall characteristic. Brief but intense events tended to elevate TSS, nitrogen and phosphorus concentrations, especially in complex land-use catchments. Events with long antecedent dry days and short duration also resulted in increased pollutant concentrations, while events with long duration and low intensity could result in higher EPLs. The effect of mixed land use on water quality can vary depending on rainfall event types. Seasonal variations were found in EMC and EPL of TSS, nitrogen and phosphorus, with higher values in the spring and summer than the fall. Seasonal variations are mainly influenced by rainfall conditions, temperature and anthropogenic activities (e.g. lawn fertilization and de-icing with sands). MLR considering rainfall characteristics is an effective method for predicting stormwater quality within a single catchment. Considering complexity and spatial distribution of mixed land use can improve the accuracy of the harmonized MLR model. This research provided insights into understanding the complexities introduced by mixed land use and rainfall event types in urban stormwater quality.
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The Late Cretaceous of western North America supported diverse dinosaur assemblages, though understanding patterns of dinosaur diversity, evolution, and extinction has been historically limited by unequal geographic and temporal sampling. In particular, the existence and extent of faunal endemism along the eastern coastal plain of Laramidia continues to generate debate, and finer scale regional patterns remain elusive. Here, we report a new centrosaurine ceratopsid, Lokiceratops rangiformis, from the lower portion of the McClelland Ferry Member of the Judith River Formation in the Kennedy Coulee region along the Canada-USA border. Dinosaurs from the same small geographic region, and from nearby, stratigraphically equivalent horizons of the lower Oldman Formation in Canada, reveal unprecedented ceratopsid richness, with four sympatric centrosaurine taxa and one chasmosaurine taxon. Phylogenetic results show that Lokiceratops, together with Albertaceratops and Medusaceratops, was part of a clade restricted to a small portion of northern Laramidia approximately 78 million years ago. This group, Albertaceratopsini, was one of multiple centrosaurine clades to undergo geographically restricted radiations, with Nasutuceratopsini restricted to the south and Centrosaurini and Pachyrostra restricted to the north. High regional endemism in centrosaurs is associated with, and may have been driven by, high speciation rates and diversity, with competition between dinosaurs limiting their geographic range. High speciation rates may in turn have been driven in part by sexual selection or latitudinally uneven climatic and floral gradients. The high endemism seen in centrosaurines and other dinosaurs implies that dinosaur diversity is underestimated and contrasts with the large geographic ranges seen in most extant mammalian megafauna.
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Dinossauros , Fósseis , Filogenia , Dinossauros/anatomia & histologia , Dinossauros/classificação , Animais , Montana , Evolução Biológica , Rios , BiodiversidadeRESUMO
Tyrannosaurid dinosaurs dominated as predators in the Late Cretaceous of Laurasia, culminating in the evolution of the giant Tyrannosaurus rex, both the last and largest tyrannosaurid. Where and when Tyrannosaurini (T. rex and kin) originated remains unclear. Competing hypotheses place tyrannosaurin origins in Asia, or western North America (Laramidia). We report a new tyrannosaurin, Tyrannosaurus mcraeensis, from the Campanian-Maastrichtian Hall Lake Formation of New Mexico, based on a fossil previously referred to T. rex. T. mcraeensis predates T. rex by ~ 6-7 million years, yet rivaled it in size. Phylogenetic analysis recovers T. mcraeensis as sister to T. rex and suggests Tyrannosaurini originated in southern Laramidia. Evolution of giant tyrannosaurs in southern North America, alongside giant ceratopsians, hadrosaurs, and titanosaurs suggests large-bodied dinosaurs evolved at low latitudes in North America.
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Dinossauros , Gigantismo , Animais , Filogenia , Fósseis , América do Norte , New Mexico , Dinossauros/anatomia & histologia , Evolução BiológicaRESUMO
The fossil record of centrosaurine ceratopsids is largely restricted to the northern region of western North America (Alberta, Montana and Alaska). Exceptions consist of single taxa from Utah (Diabloceratops) and China (Sinoceratops), plus otherwise fragmentary remains from the southern Western Interior of North America. Here, we describe a remarkable new taxon, Nasutoceratops titusi n. gen. et sp., from the late Campanian Kaiparowits Formation of Utah, represented by multiple specimens, including a nearly complete skull and partial postcranial skeleton. Autapomorphies include an enlarged narial region, pneumatic nasal ornamentation, abbreviated snout and elongate, rostrolaterally directed supraorbital horncores. The subrectangular parietosquamosal frill is relatively unadorned and broadest in the mid-region. A phylogenetic analysis indicates that Nasutoceratops is the sister taxon to Avaceratops, and that a previously unknown subclade of centrosaurines branched off early in the group's history and persisted for several million years during the late Campanian. As the first well-represented southern centrosaurine comparable in age to the bulk of northern forms, Nasutoceratops provides strong support for the provincialism hypothesis, which posits that Laramidia-the western landmass formed by inundation of the central region of North America by the Western Interior Seaway-hosted at least two coeval dinosaur communities for over a million years of late Campanian time.
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Dinossauros/anatomia & histologia , Fósseis , Crânio/anatomia & histologia , Animais , Dinossauros/classificação , Filogenia , UtahRESUMO
Understanding the impact of rainfall characteristics on urban stormwater quality is important for stormwater management. Even though significant attempts have been undertaken to study the relationship between rainfall and urban stormwater quality, the knowledge developed may be difficult to apply in commercial stormwater management models. A data mining framework was proposed to study the impacts of rainfall characteristics on stormwater quality. A rainfall type-based calibration approach was developed to improve water quality model performance. Specifically, the relationship between rainfall characteristics and stormwater quality was studied using principal component analysis and correlation analysis. Rainfall events were classified using a K-means clustering method based on the selected rainfall characteristics. A rainfall type-based (RTB) model was independently calibrated for each rainfall type to obtain optimal parameter sets of stormwater quality models. The results revealed that antecedent dry days, average rainfall intensity, and rainfall duration were the most critical rainfall characteristics affecting the event mean concentrations (EMCs) of total suspended solids, total nitrogen, and total phosphorus, while total rainfall was found to be of negligible importance. The K-means method effectively clustered the rainfall events into four types that could represent the rainfall characteristics in the study areas. The rainfall type-based calibration approach can considerably improve water quality model accuracy. Compared to the traditional continuous simulation model, the relative error of the RTB model was reduced by 11.4 % to 16.4 % over the calibration period. The calibrated stormwater quality parameters can be transferred to adjacent catchments with similar characteristics.
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Poluentes Químicos da Água , Poluentes Químicos da Água/análise , Monitoramento Ambiental/métodos , Chuva , Movimentos da Água , Qualidade da ÁguaRESUMO
Stratification in constructed urban stormwater wetlands is one of the fundamental physical processes that affect hydrodynamics, transport and fate of stormwater pollutants. Adverse effects of stratification include decreasing pollutant retention capacity, causing the water at lower depths to become anoxic, degrading water quality and increasing stress on the downstream aquatic communities. The current study reports on a comprehensive field monitoring program of stratification and hydrodynamics in two ice-free seasons (May - October) in two constructed urban stormwater wetlands in Calgary, Canada, with different inlet, outlet, morphometric and vegetation designs. Despite their small sizes of 0.5 and 1.2 ha and shallow water depths of 0.8 m, stratification was strong and persistent in the wetlands. The response of stratification and mixing to atmospheric forcings (e.g., air temperature, atmospheric instability, rainfall depth, wind speed) and the impact of design characteristics (inlet/outlet design, water depth, surface area and aquatic vegetation) were examined and discussed. Thermal stratification, defined as a vertical temperature gradient >1 °C/m, was found to be significantly higher (up to ten times) near the inlets and last longer (up to twice) than in the main cells and the outlet basins due to the relatively cold summer inflows. The wetland with twice the permanent water volume and surface area and half the length-to-width ratio had denser submerged aquatic vegetation, higher (by up to 2 °C) water temperature and more severe (up to eight times) thermal stratification. Strong densimetric stratification and low wind stress on the water surface caused hypoxic conditions near the bed, potentially adversely affecting water quality and downstream aquatic communities.
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Wet ponds have been extensively used for controlling stormwater pollutants, such as sediment and nutrients, in urban watersheds. The removal of pollutants relies on a combination of physical, chemical, and biological processes. It is crucial to assess the performance of wet ponds in terms of removal efficiency and develop an effective modeling scheme for removal efficiency prediction to optimize water quality management. To achieve this, a two-year field program was conducted at two wet ponds in Calgary, Alberta, Canada to evaluate the wet ponds' performance. Additionally, machine learning (ML) algorithms have been shown to provide promising predictions in datasets with intricate interactions between variables. In this study, the generalized linear model (GLM), partial least squares (PLS) regression, support vector machine (SVM), random forest (RF), and K-nearest neighbors (KNN) were applied to predict the outflow concentrations of three key pollutants: total suspended solids (TSS), total nitrogen (TN), and total phosphorus (TP). Generally, the concentrations of inflow pollutants in the two study ponds are highly variable, and a wide range of removal efficiencies are observed. The results indicate that the concentrations of TSS, TN, and TP decrease significantly from the inlet to outlet of the ponds. Meanwhile, inflow concentration, rainfall characteristics, and wind are important indicators of pond removal efficiency. In addition, ML algorithms can be an effective approach for predicting outflow water quality: PLS, GLM, and SVM have shown strong potential to capture the dynamic interactions in wet ponds and predict the outflow concentration. This study highlights the complexity of pollutant removal dynamics in wet ponds and demonstrates the potential of data-driven outflow water quality prediction.
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Modern birds are typified by the presence of feathers, complex evolutionary innovations that were already widespread in the group of theropod dinosaurs (Maniraptoriformes) that include crown Aves. Squamous or scaly reptilian-like skin is, however, considered the plesiomorphic condition for theropods and dinosaurs more broadly. Here, we review the morphology and distribution of non-feathered integumentary structures in non-avialan theropods, covering squamous skin and naked skin as well as dermal ossifications. The integumentary record of non-averostran theropods is limited to tracks, which ubiquitously show a covering of tiny reticulate scales on the plantar surface of the pes. This is consistent also with younger averostran body fossils, which confirm an arthral arrangement of the digital pads. Among averostrans, squamous skin is confirmed in Ceratosauria (Carnotaurus), Allosauroidea (Allosaurus, Concavenator, Lourinhanosaurus), Compsognathidae (Juravenator), and Tyrannosauroidea (Santanaraptor, Albertosaurus, Daspletosaurus, Gorgosaurus, Tarbosaurus, Tyrannosaurus), whereas dermal ossifications consisting of sagittate and mosaic osteoderms are restricted to Ceratosaurus. Naked, non-scale bearing skin is found in the contentious tetanuran Sciurumimus, ornithomimosaurians (Ornithomimus) and possibly tyrannosauroids (Santanaraptor), and also on the patagia of scansoriopterygids (Ambopteryx, Yi). Scales are surprisingly conservative among non-avialan theropods compared to some dinosaurian groups (e.g. hadrosaurids); however, the limited preservation of tegument on most specimens hinders further interrogation. Scale patterns vary among and/or within body regions in Carnotaurus, Concavenator and Juravenator, and include polarised, snake-like ventral scales on the tail of the latter two genera. Unusual but more uniformly distributed patterning also occurs in Tyrannosaurus, whereas feature scales are present only in Albertosaurus and Carnotaurus. Few theropods currently show compelling evidence for the co-occurrence of scales and feathers (e.g. Juravenator, Sinornithosaurus), although reticulate scales were probably retained on the mani and pedes of many theropods with a heavy plumage. Feathers and filamentous structures appear to have replaced widespread scaly integuments in maniraptorans. Theropod skin, and that of dinosaurs more broadly, remains a virtually untapped area of study and the appropriation of commonly used techniques in other palaeontological fields to the study of skin holds great promise for future insights into the biology, taphonomy and relationships of these extinct animals.
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Escamas de Animais , Carcinoma de Células Escamosas , Dinossauros , Animais , Evolução Biológica , Aves , Dinossauros/anatomia & histologia , Plumas/anatomia & histologia , Fósseis , Osteogênese , FilogeniaRESUMO
Atmospheric aerosols play a crucial role in climate change, especially in the Himalayas and Tibetan Plateau. Here, we present the seasonal and diurnal characteristics of aerosol vertical profiles measured using a Mie lidar, along with surface black carbon (BC) measurements, at Mt. Qomolangma (QOMS), in the central Himalayas, in 2018-2019. Lidar-retrieved profiles of aerosols showed a distinct seasonal pattern of aerosol loading (aerosol extinction coefficient, AEC), with a maximum in the pre-monsoon (19.8 ± 22.7 Mm-1 of AEC) and minimum in the summer monsoon (7.0 ± 11.2 Mm-1 of AEC) seasons. The diurnal variation characteristics of AEC and BC were quite different in the non-monsoon seasons with enriched aerosols being maintained from 00:00 to 10:00 in the pre-monsoon season. The major aerosol types at QOMS were identified as background, pollution, and dust aerosols, especially during the pre-monsoon season. The occurrence of pollution events influenced the vertical distribution, seasonal/diurnal patterns, and types of aerosols. Source contribution of BC based on the weather research and forecasting chemical model showed that approximately 64.2% ± 17.0% of BC at the QOMS originated from India and Nepal in South Asia during the non-monsoon seasons, whereas approximately 47.7% was from local emission sources in monsoon season. In particular, the high abundance of BC at the QOMS in the pre-monsoon season was attributed to biomass burning, whereas anthropogenic emissions were the likely sources during the other seasons. The maximum aerosol concentration appeared in the near-surface layer (approximately 4.3 km ASL), and high concentrations of transported aerosols were mainly found at 4.98, 4.58, 4.74, and 4.88 km ASL in the pre-monsoon, monsoon, post-monsoon, and winter seasons, respectively. The investigation of the vertical profiles of aerosols at the QOMS can help verify the representation of aerosols in the air quality model and satellite products and regulate the anthropogenic disturbance over the Tibetan Plateau.
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Poluentes Atmosféricos , Aerossóis/análise , Poluentes Atmosféricos/análise , Monitoramento Ambiental , Índia , Estações do Ano , Fuligem/análiseRESUMO
The potential origins of stability in branched alkanes are investigated, paying close attention to two recent hypotheses: geminal steric repulsion and protobranching. All alkane isomers through C(6)H(14) along with heptane and octane were investigated at the MPW1B95/6-311++G(d,p) level. Their geminal steric repulsion, total steric repulsion, and orbital interactions were evaluated by using natural bond orbital analysis. All measures of steric repulsion fail to explain the stability of branched alkanes. The extra stability of branched alkanes and protobranching, in general, is tied to stabilizing geminal sigma-->sigma* delocalization, particularly of the type that involves adjacent C-C bonds and, thus, preferentially stabilizes branched alkanes. This picture is corroborated by valence bond calculations that attribute the effect to additional ionic structures (e.g., CH(3) (+) :CH(2) :CH(3) (-) and CH(3):(-) CH(2): CH(3) (+) for propane) that are not possible without protobranching.