1.
Chem Commun (Camb)
; 58(92): 12855-12858, 2022 Nov 17.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36317533
RESUMO
Theory and solution NMR indicate that all-syn 1,3,5-trifluorocyclohexane 5 adopts the expected tri-equatorial conformation, however in the solid state the more polar triaxial conformation is observed. This and the favoured conformations of substituted (Me, OMe, NH(CO)Me, NHBoc) derivatives of 5 are investigated to explore triaxial C-F preferences.