Simulating Landscape Sediment Transport Capacity by Using a Modified SWAT Model.

Sediment delivery from hillslopes to rivers is spatially variable and may lead to long-term delays between initial erosion and related sediment yield at the watershed outlet. Consideration of spatial variability is important for developing sound strategies for water quality improvement and soil protection at the watershed scale. Hence, the Soil and Water Assessment Tool (SWAT) was modified and tested in this study to simulate the landscape transport capacity of sediment. The study area was the steeply sloped Arroio Lino watershed in southern Brazil. Observed sediment yield data at the watershed outlet were used to calibrate and validate a modified SWAT model. For the calibration period, the modified model performed better than the unaltered SWAT2009 version; the models achieved Nash-Sutcliffe efficiency (NSE) values of 0.7 and -0.1, respectively. Nash-Sutcliffe efficiencies were less for the validation period, but the modified model's NSE was higher than the unaltered model (-1.4 and -12.1, respectively). Despite the relatively low NSE values, the results of this first test are promising because the model modifications lowered the percent bias in sediment yield from 73 to 18%. Simulation results for the modified model indicated that approximately 60% of the mobilized soil is deposited along the landscape before it reaches the river channels. This research demonstrates the modified model's ability to simulate sediment yield in watersheds with steep slopes. The results suggest that integration of the sediment deposition routine in SWAT increases accuracy in steeper areas while significantly improving its ability to predict the spatial distribution of sediment deposition areas. Further work is needed regarding (i) improved strategies for spatially distributed sediment transport measurements (for improving process knowledge and model evaluation) and (ii) extensive model tests in other well instrumented experimental watersheds with differing topographic configurations and land uses.

240Pu/239Pu signatures allow refining the chronology of radionuclide fallout in South America.

Atmospheric nuclear tests (1945-1980) have led to radioactive fallout across the globe. French tests in Polynesia (1966-1974) may influence the signature of fallout in South America in addition to those conducted by USA and former USSR until 1963 in the Northern hemisphere. Here, we compiled the 240Pu/239Pu atom ratios reported for soils of South America and conducted additional measurements to examine their latitudinal distributions across this continent. Significantly lower ratio values were found in the 20-45° latitudinal band (0.04 to 0.13) compared to the rest of the continent (up to 0.20) and attributed to the contribution of the French atmospheric tests to the ultra-trace plutonium levels found in these soils. Based on sediment cores collected in lakes of Chile and Uruguay, we show the added value of measuring 240Pu/239Pu atom ratios to refine the age models of environmental archives in this region of the world.

Investigating the relationships between chemical element concentrations and discharge to improve our understanding of their transport patterns in rural catchments under subtropical climate conditions.

Solute and particulate elemental concentrations (C) exhibit different responses to changes in discharge (Q), and those relationships are not well understood in subtropical agricultural environments. The objective is to describe the transport processes of different chemical elements during a set of contrasted rainfall events (2011-2015) that occurred in a small rural catchment under subtropical climate. The study was carried out in the Lajeado Ferreira Creek catchment (1.23 km2), southern Brazil. To this end, the concentrations in dissolved organic carbon (DOC), Cl-, NO3-, SO4-, ten chemical elements (in either dissolved or particulate forms) and suspended sediment concentrations (SSC) were determined. Metric indices were then calculated to characterize their transport patterns: (i) the best fit slope between log-C and log-Q (ß), (ii) the coefficient of variation of C and Q, (iii) shape of the hysteresis loop and hysteresis index, and (iv) the flushing index. All particulate elements along with the dissolved inorganic phosphorus (PO4-3) were shown to be controlled by the sediment dynamics. Geogenic elements (Fe2+, Zn2+, Cu2+, Mn2+, Si4+) showed a dilution effect with increasing Q values, likely because they were mainly transported with subsurface and base flow. Dissolved elements that are mainly supplied with fertilizers (Na+ and Cl-) as well as DOC showed a dilution effect, although they were mainly transported by surface runoff. Finally, a chemostatic behavior was found for those chemical elements (Mg2+, K+, Ca2+, NO3- and SO42-) that are supplied by more than one flow pathways. The results demonstrate that under subtropical climate conditions, the transport of essential nutrients including PO4-3 and metals (in particulate form), are mainly transported with surface runoff. Accordingly, runoff control on cultivated hillslopes should be improved to reduce the potential contaminant supply to the river and to reduce the potentially deleterious impacts that they may cause in downstream regions.

The identification of sediment sources in a small urban watershed in southern Brazil: an application of sediment fingerprinting.

Soil particles eroded from the land surface and transported into rivers by runoff are considered one of the main components of non-point source pollution in urban watersheds. These particles also serve as a vector for a wide variety of both organic and inorganic constituents. As a result, the identification of sediment sources in an urban watershed is necessary not only to understand erosion dynamics, but also to help implement more effective measures to control and/or remediate non-point source pollution. The present study employs sediment 'fingerprinting' to determine the main sediment sources in a small residential urban watershed (0.83 km2) on the outskirts of Porto Alegre in southern Brazil. Based on an evaluation spanning 12 rainfall events, the results show that paved and unpaved roads and the stream channel itself contribute, on average, 46%, 23%, and 31%, respectively, to the suspended sediment flux in the watershed. Furthermore, the source contributions varied both between events and over the course of a single event. This appears to imply that source contributions, at least to some extent, depend on local precipitation patterns. The results from this study indicate that the level of uncertainty in source ascription tends to decline with increasing numbers of tracers; hence, successful sediment fingerprinting and source ascription in complex hydrologic environments, such as urban watersheds, may require the use of a large number of chemical and/or physical tracers.