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1.
Environ Res ; 251(Pt 1): 118457, 2024 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-38382666

RESUMO

Because of their high electrocatalytic activity, sensitivity, selectivity, and long-term stability in electrochemical sensors and biosensors, numerous nanomaterials are being used as suitable electrode materials thanks to developments in nanotechnology. Electrochemical sensors and biosensors are two areas where two-dimensional layered materials (2DLMs) are finding increasing utility due to their unusual structure and physicochemical features. Nanosensors, by their unprecedented sensitivity and minute scale, can probe deeper into the structural integrity of piles, capturing intricacies that traditional tools overlook. These advanced devices detect anomalies, voids, and minute defects in the pile structure with unparalleled granularity. Their effectiveness lies in detection and their capacity to provide real-time feedback on pile health, heralding a shift from reactive to proactive maintenance methodologies. Harvesting data from these nanosensors, data was incorporated into a probabilistic model, executing the reliability index calculations through Monte Carlo simulations. Preliminary outcomes show a commendable enhancement in the predictability of vertical bearing capacity, with the coefficient of variation dwindling by up to 12%. The introduction of nanosensors facilitates instantaneous monitoring and fortifies the long-term stability of pile foundations. This study accentuates the transformative potential of nanosensors in geotechnical engineering.


Assuntos
Nanotecnologia , Reprodutibilidade dos Testes , Técnicas Eletroquímicas/métodos , Técnicas Eletroquímicas/instrumentação , Método de Monte Carlo , Materiais de Construção/análise , Nanoestruturas
2.
J Mol Graph Model ; 132: 108832, 2024 Jul 19.
Artigo em Inglês | MEDLINE | ID: mdl-39059055

RESUMO

Selecting an appropriate anode material (AM) has been considered to be a crucial initial step in advancing high-performance batteries. Within this piece of research, we examine the suitability of the BC6NA monolayer (referred to as BC6NAML) as an AM by first-principles calculations. The BC6NAML exhibits metallic behavior consistently, even with varying concentrations of Na atoms, making it an ideal choice for battery usages. Our findings revealed that the theoretical storage capacity for Na-adhered BC6NAML was 406.36 mAhg-1, surpassing graphite, TiO2, BC6NA, and numerous other 2D materials. The BC6NAML also demonstrates a diffusion barrier of 0.39 eV and favorable diffusivity of Na-ions. Although the open-circuit voltage (OCV) of BC6NAML was temperate and lower compared to the OCV of other AMs like TiO2, our results suggested that it is possible to utilize BC6NAML as one of the encouraging host materials for sodium-ion batteries (SIBs). Consequently, this investigation into the potential anodic application of BC6NAML proves valuable for future experimental studies into sodium storage for SIBs.

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