Active control of mid-wavelength infrared non-linearity in silicon photonic crystal slab.

Natural materials' inherently weak nonlinear response demands the design of artificial substitutes to avoid optically large samples and complex phase-matching techniques. Silicon photonic crystals are promising artificial materials for this quest. Their nonlinear properties can be modulated optically, paving the way for applications ranging from ultrafast information processing to quantum technologies. A two-dimensional 15-µm-thick silicon photonic structure, comprising a hexagonal array of air holes traversing the slab's thickness, has been designed to support a guided resonance for the light with a wavelength of 4-µm. At the resonance conditions, a transverse mode of the light is strongly confined between the holes in the "veins" of the silicon component. Owing to the confinement, the structure exhibits a ratio of nonlinear to linear absorption coefficients threefold higher than the uniform silicon slab of the same thickness. A customised time-resolved Z-scan method with provisions to accommodate ultrafast pump-probe measurements was used to investigate and quantify the non-linear response. We show that optically pumping free charge carriers into the structure decouples the incoming light from the resonance and reduces the non-linear response. The time-resolved measurements suggest that the decoupling is a relatively long-lived effect on the scale comparable to the non-radiative recombination in the bulk material. Moreover, we demonstrate that the excited free carriers are not the source of the nonlinearity, as this property is determined by the structure design.

Taming non-radiative recombination in Si nanocrystals interlinked in a porous network.

A range of the distinctive physical properties, comprising high surface-to-volume ratio, possibility to achieve mechanical and chemical stability after a tailored treatment, controlled quantum confinement and the room-temperature photoluminescence, combined with mass production capabilities offer porous silicon unmatched capabilities required for the development of electro-optical devices. Yet, the mechanism of the charge carrier dynamics remains poorly controlled and understood. In particular, non-radiative recombination, often the main process of the excited carrier's decay, has not been adequately comprehended to this day. Here we show, that the recombination mechanism critically depends on the composition of surface passivation. That is, hydrogen passivated material exhibits Shockley-Read-Hall type of decay, while for oxidised surfaces, it proceeds by two orders of magnitude faster and exclusively through the Auger process. Moreover, it is possible to control the source of recombination in the same sample by applying a cyclic sequence of hydrogenation-oxidation-hydrogenation processes, and, consequently switching on-demand between Shockley-Read-Hall and Auger recombinations. Remarkably, irregardless of the recombination mechanism, the rate constant scales inversely with the average volume of individual silicon nanocrystals contained in the material. Thus, the type of the non-radiative recombination is established by the composition of the passivation, while its rate depends on the degree of the charge carriers' quantum confinement.

Study of Low Terahertz Radar Signal Backscattering for Surface Identification.

This study explores the scattering of signals within the mm and low Terahertz frequency range, represented by frequencies 79 GHz, 150 GHz, 300 GHz, and 670 GHz, from surfaces with different roughness, to demonstrate advantages of low THz radar for surface discrimination for automotive sensing. The responses of four test surfaces of different roughness were measured and their normalized radar cross sections were estimated as a function of grazing angle and polarization. The Fraunhofer criterion was used as a guideline for determining the type of backscattering (specular and diffuse). The proposed experimental technique provides high accuracy of backscattering coefficient measurement depending on the frequency of the signal, polarization, and grazing angle. An empirical scattering model was used to provide a reference. To compare theoretical and experimental results of the signal scattering on test surfaces, the permittivity of sandpaper has been measured using time-domain spectroscopy. It was shown that the empirical methods for diffuse radar signal scattering developed for lower radar frequencies can be extended for the low THz range with sufficient accuracy. The results obtained will provide reference information for creating remote surface identification systems for automotive use, which will be of particular advantage in surface classification, object classification, and path determination in autonomous automotive vehicle operation.

Tunable compression of THz chirped pulses using a helical graphene ribbon-loaded hollow-core waveguide.

Pulse shaping is important for communications, spectroscopy, and other applications that require high peak power and pulsed operation, such as radar systems. Unfortunately, pulse shaping remains largely elusive for terahertz (THz) frequencies. To address this void, a comprehensive study on the dispersion tunability properties of THz chirped pulses traveling through a dielectric-lined hollow-core waveguide loaded with a helical graphene ribbon is presented. It is demonstrated that there is an optimal compression waveguide length over which THz chirped pulses reach the maximum compression. The optimal length is dependent on the chirp pulse duration. It is shown that by applying an electrostatic controlling gate voltage (Vg) of 0 and 30 V on the helical graphene ribbon, the temporal input pulses of width 8 and 12 ps, propagating through two different lengths, can be tuned by 5.9% and 8%, respectively, in the frequency range of 2.15-2.28 THz.

The Interplay of Symmetry and Scattering Phase in Second Harmonic Generation from Gold Nanoantennas.

Nonlinear phenomena are central to modern photonics but, being inherently weak, typically require gradual accumulation over several millimeters. For example, second harmonic generation (SHG) is typically achieved in thick transparent nonlinear crystals by phase-matching energy exchange between light at initial, ω, and final, 2ω, frequencies. Recently, metamaterials imbued with artificial nonlinearity from their constituent nanoantennas have generated excitement by opening the possibility of wavelength-scale nonlinear optics. However, the selection rules of SHG typically prevent dipole emission from simple nanoantennas, which has led to much discussion concerning the best geometries, for example, those breaking centro-symmetry or incorporating resonances at multiple harmonics. In this work, we explore the use of both nanoantenna symmetry and multiple harmonics to control the strength, polarization and radiation pattern of SHG from a variety of antenna configurations incorporating simple resonant elements tuned to light at both ω and 2ω. We use a microscopic description of the scattering strength and phases of these constituent particles, determined by their relative positions, to accurately predict the SHG radiation observed in our experiments. We find that the 2ω particles radiate dipolar SHG by near-field coupling to the ω particle, which radiates SHG as a quadrupole. Consequently, strong linearly polarized dipolar SHG is only possible for noncentro-symmetric antennas that also minimize interference between their dipolar and quadrupolar responses. Metamaterials with such intra-antenna phase and polarization control could enable compact nonlinear photonic nanotechnologies.

High density micro-pyramids with silicon nanowire array for photovoltaic applications.

We use a metal assisted chemical etch process to fabricate silicon nanowire arrays (SiNWAs) onto a dense periodic array of pyramids that are formed using an alkaline etch masked with an oxide layer. The hybrid micro-nano structure acts as an anti-reflective coating with experimental reflectivity below 1% over the visible and near-infrared spectral regions. This represents an improvement of up to 11 and 14 times compared to the pyramid array and SiNWAs on bulk, respectively. In addition to the experimental work, we optically simulate the hybrid structure using a commercial finite difference time domain package. The results of the optical simulations support our experimental work, illustrating a reduced reflectivity in the hybrid structure. The nanowire array increases the absorbed carrier density within the pyramid by providing a guided transition of the refractive index along the light path from air into the silicon. Furthermore, electrical simulations which take into account surface and Auger recombination show an efficiency increase for the hybrid structure of 56% over bulk, 11% over pyramid array and 8.5% over SiNWAs.

Droplet impact on doubly re-entrant structures.

Doubly re-entrant pillars have been demonstrated to possess superior static and dynamic liquid repellency against highly wettable liquids compared to straight or re-entrant pillars. Nevertheless, there has been little insight into how the key structural parameters of doubly re-entrant pillars influence the hydrodynamics of impacting droplets. In this work, we carried out numerical simulations and experimental studies to portray the fundamental physical phenomena that can explain the alteration of the surface wettability from adjusting the design parameters of the doubly re-entrant pillars. On the one hand, three-dimensional multiphase flow simulations of droplet impact were conducted to probe the predominance of the overhang structure in dynamic liquid repellency. On the other hand, the numerical results of droplet impact behaviours are agreed by the experimental results for different pitch sizes and contact angles. Furthermore, the dimensions of the doubly re-entrant pillars, including the height, diameter, overhang length and overhang thickness, were altered to establish their effect on droplet repellency. These findings present the opportunity for manipulations of droplet behaviours by means of improving the critical dimensional parameters of doubly re-entrant structures.

Terahertz epsilon-near-zero graded-index lens.

An epsilon-near-zero graded-index converging lens with planar faces is proposed and analyzed. Each perfectly-electric conducting (PEC) waveguide comprising the lens operates slightly above its cut-off frequency and has the same length but different cross-sectional dimensions. This allows controlling individually the propagation constant and the normalized characteristic impedance of each waveguide for the desired phase front at the lens output while Fresnel reflection losses are minimized. A complete theoretical analysis based on the waveguide theory and Fermat's principle is provided. This is complemented with numerical simulation results of two-dimensional and three-dimensional lenses, made of PEC and aluminum, respectively, and working in the terahertz regime, which show good agreement with the analytical work.

Terahertz wave transmission in flexible polystyrene-lined hollow metallic waveguides for the 2.5-5 THz band.

A low-loss and low-dispersive optical-fiber-like hybrid HE11 mode is developed within a wide band in metallic hollow waveguides if their inner walls are coated with a thin dielectric layer. We investigate terahertz (THz) transmission losses from 0.5 to 5.5 THz and bending losses at 2.85 THz in a polystyrene-lined silver waveguides with core diameters small enough (1 mm) to minimize the number of undesired modes and to make the waveguide flexible, while keeping the transmission loss of the HE11 mode low. The experimentally measured loss is below 10 dB/m for 2 < ν < 2.85 THz (~4-4.5 dB/m at 2.85 THz) and it is estimated to be below 3 dB/m for 3 < ν < 5 THz according to the numerical calculations. At ~1.25 THz, the waveguide shows an absorption peak of ~75 dB/m related to the transition between the TM11-like mode and the HE11 mode. Numerical modeling reproduces the measured absorption spectrum but underestimates the losses at the absorption peak, suggesting imperfections in the waveguide walls and that the losses can be reduced further.

Multiresonant broadband optical antennas as efficient tunable nanosources of second harmonic light.

We report the experimental realization of efficient tunable nanosources of second harmonic light with individual multiresonant log-periodic optical antennas. By designing the nanoantenna with a bandwidth of several octaves, simultaneous enhancement of fundamental and harmonic fields is observed over a broad range of frequencies, leading to a high second harmonic conversion efficiency, together with an effective second order susceptibility within the range of values provided by widespread inorganic crystals. Moreover, the geometrical configuration of the nanoantenna makes the generated second harmonic signal independent from the polarization of the fundamental excitation. These results open new possibilities for the development of efficient integrated nonlinear nanodevices with high frequency tunability.

A computationally-inexpensive strategy in CT image data augmentation for robust deep learning classification in the early stages of an outbreak.

Coronavirus disease 2019 (COVID-19) has spread globally for over three years, and chest computed tomography (CT) has been used to diagnose COVID-19 and identify lung damage in COVID-19 patients. Given its widespread, CT will remain a common diagnostic tool in future pandemics, but its effectiveness at the beginning of any pandemic will depend strongly on the ability to classify CT scans quickly and correctly when only limited resources are available, as it will happen inevitably again in future pandemics. Here, we resort into the transfer learning procedure and limited hyperparameters to use as few computing resources as possible for COVID-19 CT images classification. Advanced Normalisation Tools (ANTs) are used to synthesise images as augmented/independent data and trained on EfficientNet to investigate the effect of synthetic images. On the COVID-CT dataset, classification accuracy increases from 91.15% to 95.50% and Area Under the Receiver Operating Characteristic (AUC) from 96.40% to 98.54%. We also customise a small dataset to simulate data collected in the early stages of the outbreak and report an improvement in accuracy from 85.95% to 94.32% and AUC from 93.21% to 98.61%. This study provides a feasible Low-Threshold, Easy-To-Deploy and Ready-To-Use solution with a relatively low computational cost for medical image classification at an early stage of an outbreak in which scarce data are available and traditional data augmentation may fail. Hence, it would be most suitable for low-resource settings.

Madelung Formalism for Electron Spill-Out in Nonlocal Nanoplasmonics.

Current multiscale plasmonic systems pose a modeling challenge. Classical macroscopic theories fail to capture quantum effects in such systems, whereas quantum electrodynamics is impractical given the total size of the experimentally relevant systems, as the number of interactions is too large to be addressed one by one. To tackle the challenge, in this paper we propose to use the Madelung form of the hydrodynamic Drude model, in which the quantum effect electron spill-out is incorporated by describing the metal-dielectric interface using a super-Gaussian function. The results for a two-dimensional nanoplasmonic wedge are correlated to those from nonlocal full-wave numerical calculations based on a linearized hydrodynamic Drude model commonly employed in the literature, showing good qualitative agreement. Additionally, a conformal transformation perspective is provided to explain qualitatively the findings. The methodology described here may be applied to understand, both numerically and theoretically, the modular inclusions of additional quantum effects, such as electron spill-out and nonlocality, that cannot be incorporated seamlessly by using other approaches.

Dual-band double-negative-index fishnet metamaterial at millimeter-waves.

An effective negative refractive index (NRI) is demonstrated and experimentally verified for the first two propagation bands of a fishnet-like metamaterial at millimeter-wave frequencies. The dual-band NRI behavior is achieved by engineering the diffraction order (±1, ±1) associated with the internal mode supported between holey layers to correspond with the second propagation band. In addition to the experimental interferometric technique that accounts for the handedness of the propagation, numerical results are given to predict the dual-band effective NRI and to confirm dual-band negative refraction for a prism composed of the proposed metamaterial.

Hybrid reflection retrieval method for terahertz dielectric imaging of human bone.

Terahertz imaging is becoming a biological imaging modality in its own right, alongside the more mature infrared and X-ray techniques. Nevertheless, extraction of hyperspectral, biometric information of samples is limited by experimental challenges. Terahertz time domain spectroscopy reflection measurements demand highly precise alignment and suffer from limitations of the sample thickness. In this work, a novel hybrid Kramers-Kronig and Fabry-Pérot based algorithm has been developed to overcome these challenges. While its application is demonstrated through dielectric retrieval of glass-backed human bone slices for prospective characterisation of metastatic defects or osteoporosis, the generality of the algorithm offers itself to wider application towards biological materials.

Millimeter-wave phase resonances in compound reflection gratings with subwavelength grooves.

Experimental evidence of phase resonances in a dual-period reflection structure comprising three subwavelength grooves in each period is provided in the millimeter-wave regime. We have analyzed and measured the response of these structures and show that phase resonances are characterized by a minimum in the reflected response, as predicted by numerical calculations. It is also shown that under oblique incidence these structures exhibit additional phase resonances not present for normal illumination because of the potentially permitted odd field distribution. A satisfactory agreement between the experimental and numerical reflectance curves is obtained. These results confirm the recent theoretical predictions of phase resonances in reflection gratings in the millimeter-wave regime, and encourage research in this subject due to the multiple potential applications, such as frequency selective surfaces, backscattering reduction and complex-surface-wave-based sensing. In addition, it is underlined here that the response becomes much more complex than the mere infinite analysis when one considers finite periodic structures as in the real experiment.

Experimental signature of a topological quantum dot.

Topological insulator nanoparticles (TINPs) host topologically protected Dirac surface states, just like their bulk counterparts. For TINPs of radius <100 nm, quantum confinement on the surface results in the discretization of the Dirac cone. This system of discrete energy levels is referred to as a topological quantum dot (TQD) with energy level spacing on the order of Terahertz (THz), which is tunable with material-type and particle size. The presence of these discretized energy levels in turn leads to a new electron-mediated phonon-light coupling in the THz range, and the resulting mode can be observed in the absorption cross-section of the TINPs. We present the first experimental evidence of this new quantum phenomenon in Bi2Te3 topological quantum dots, remarkably observed at room temperature.

Broadband spoof plasmons and subwavelength electromagnetic energy confinement on ultrathin metafilms.

A complementary split ring resonator (CSRR)-based metallic layer is proposed as a route to mimic surface plasmon polaritons. A numerical analysis of the textured surface is carried out and compared to previous prominent topologies such as metal mesh, slit array, hole array, and Sievenpiper mushroom surfaces, which are studied as well from a transmission line perspective. These well-documented geometries suffer from a narrowband response, alongside, in most cases, metal thickness constraint (usually of the order of lambda/4) and non-subwavelength modal size as a result of the large dimensions of the unit cell (one dimensions is at least of the order of lambda/2). All of these limitations are overcome by the proposed CSRR-based surface. Besides, a planar waveguide is proposed as a proof of the potential of this CSRR-based metallic layer for spoof surface plasmon polariton guiding. Fundamental aspects aside, the structure under study is easy to manufacture by simple PCB techniques and it is expected to provide good performance within the frequency band from GHz to THz.

Polarized left-handed extraordinary optical transmission of subterahertz waves.

In this paper we design and measure a metamaterial polarizing device working in the sub-terahertz range. The polarizer is based on a modified version of our previous miniaturized Stacked Hole Array (SHA) structure, an arrangement that combines Extraordinary Optical Transmission (EOT) and Left-Handed Metamaterial (LHM) propagation even under Fresnel illumination. Here, we use a self complementary screen by connecting the holes of an EOT structure. Importantly, EOT remains and simultaneously total reflection is obtained for the orthogonal component. Moreover, by computing the dispersion diagram, we demonstrate that LHM propagation can be achieved for the principal polarization within the stop band of the orthogonal component, which propagates in other bands as a standard forward wave. Finally, we check our conjectures by measuring the transmission and reflection coefficients of screens milled on a low-loss microwave substrate. Measurements have been taken for 1 to 6 stacked wafers and they show clearly that the stack acts as a polarizer with left-handed characteristic. Our results open the way to design of novel polarization control metamaterials at Terahertz wavelengths.

Extraordinary transmission and left-handed propagation in miniaturized stacks of doubly periodic subwavelength hole arrays.

Metallic plates embedded between dielectric slabs and perforated by rectangular arrays of subwavelength holes with a dense periodicity in one of the directions support extraordinary transmission (ET) phenomena, viz. strong peaks in the transmittance frequency dependence. Stacks of such perforated plates support ET phenomena with propagation along the stack axis that is characterized by the left handed behavior. The incorporation of the dielectric materials and dense periodicity allows significantly reducing the illuminated area of the perforated plate required experimentally to observe the ET phenomena as compared to the areas required in the case of free standing rectangular hole arrays. This facilitates the experimental investigation of ET under excitation in the Fresnel zone of Gaussian beams.

Generation of radially-polarized terahertz pulses for coupling into coaxial waveguides.

Coaxial waveguides exhibit no dispersion and therefore can serve as an ideal channel for transmission of broadband THz pulses. Implementation of THz coaxial waveguide systems however requires THz beams with radially-polarized distribution. We demonstrate the launching of THz pulses into coaxial waveguides using the effect of THz pulse generation at semiconductor surfaces. We find that the radial transient photo-currents produced upon optical excitation of the surface at normal incidence radiate a THz pulse with the field distribution matching the mode of the coaxial waveguide. In this simple scheme, the optical excitation beam diameter controls the spatial profile of the generated radially-polarized THz pulse and allows us to achieve efficient coupling into the TEM waveguide mode in a hollow coaxial THz waveguide. The TEM quasi-single mode THz waveguide excitation and non-dispersive propagation of a short THz pulse is verified experimentally by time-resolved near-field mapping of the THz field at the waveguide output.