Supercontinuum generation in As2S3 chalcogenide waveguide pumped by all-fiber structured dual-femtosecond solitons.

Supercontinuum sources with high compactness are essential for applications such as optical sensing, airborne detection and communication systems. In the past decades, the adoption of bulky optical parametric amplifier to pump various chalcogenide glass waveguides are widely reported for on-chip mid-infrared supercontinuum generation, but this usually leads to a large volume of the whole system, and is not practical. Therefore, integrating advanced femtosecond fiber lasers with optical waveguides using nano-fabrication technology are highly desired. However, the scarcity of compact pump sources and the dispersion-matched high-nonlinearity waveguide in short wavelength regions have hindered the advancement of integrated supercontinuum source performances in the near and mid-infrared region. In this study, we demonstrate a broadband supercontinuum source from As2S3 waveguide pumped by a compact dual-femtosecond solitons pulse source. The laser is completely fiber structured, and its wavelength can be readily tuned from 2 to 2.3 µm using Raman soliton self-frequency shift technology in a Tm3+-doped fiber amplifier. Furthermore, the As2S3 waveguide is designed with controllable dispersion and high nonlinearity for a broadband supercontinuum generation. These results will advance the development of on-chip supercontinuum sources based on chalcogenide waveguides.

Design and fabrication of large-mode-area multicore chalcogenide fiber with low bending loss.

Multicore fiber (MCF) has a larger mode-area (LMA) compared to traditional single-core fiber, making it easy to get a mode area of more than 3000 µm2 with an optimized MCF structure. Here, a fine-structured 19-core fiber based on chalcogenide glass was fabricated using a combined method involving extrusion, drilling, and rod-in-tube for the first time. The fiber has a minimum transmission loss of 1.8 dB/m at 6.7 µm. When the bending radius exceeds 6 cm, a low bending loss of about 0.6 dB appears, and the experimental data are in good agreement with the simulation results. In addition, the supermode characteristics of the 19-core fiber are analyzed from both perspectives of simulation and experiment, and these results are perfectly in good agreement. We believe it opens a new way to develop high-power and bend-resisting fiber with such kind of multicore structure.

High-Q lasing in Nd3+-doped phosphate glass microsphere resonators.

Nd3+-doped glasses are the most widely used laser gain media. However, Nd3+-doped non-silica microsphere lasers generally have lower quality (Q) factors due to the presence of non-radiative energy-loss impurities in traditional glass systems. In this work, we report the first, to the best of our knowledge, Nd3+-doped phosphate glass microsphere laser with the highest Q-factor of 1.54 × 106 among all Nd3+-doped non-silica glass microsphere lasers. Whispering gallery modes in the 1020-1120-nm band can be obtained for a typical microsphere with a diameter of 82.57 µm. When the pump power exceeds the threshold of 0.17 mW, single- and multi-mode microsphere lasing can be generated under 808-nm laser diode (LD) pumping. Typical Q-factors of the phosphate glass microspheres can reach 106, which is at least an order of magnitude higher than those of other Nd3+-doped non-silica glass microsphere lasers. The Nd3+-doped phosphate glass microsphere laser reported in this work can be considered as an active optical/photonic device with low pump thresholds.

A simplified mid-infrared anti-resonant chalcogenide fiber with fewest resonant peaks.

High-power laser delivery in the mid-infrared via hollow-core fibers is attractive, but it is too difficult to be fabricated using chalcogenide glasses. Here, we designed a mid-infrared hollow-core anti-resonant chalcogenide fiber (HC-ARCF) with a simplified Kagome cladding micro-structure for the first time. Then, the fiber was firstly fabricated through a precision mechanical drilling and pressured fiber drawing method. Ultra-thin walls of 2µm in the fiber lead to the fewest resonance peaks in the 2-5µm among all reported HC-ARCFs. All the fundamental mode, the second-order mode, tube mode and node mode in the fiber were excited and observed at 1550 nm. The power and spectral properties of the core and cladding of HC-ARCF are studied for the first time. The fiber can deliver high-power of 4.84 W without damage with core-coupling, while the threshold of the node in the cladding is only 3.5 W. A broadening of the output spectrum from 1.96 to 2.41µm due to the high nonlinearity at the node was successfully observed under short-pulse laser pumping at 2µm. The potentials of the fiber used for mid-infrared high-power laser delivery via core, or nonlinear laser generation via node, were thus demonstrated.

Single-mode suspended large-core chalcohalide fiber with a low zero-dispersion wavelength for supercontinuum generation.

Chalcogenide glass possesses outstanding advantages, such as supercontinuum generation, but its nonlinear applications were limited by large zero-dispersion wavelength (ZDW). Traditional suspended-core fibers can shift the ZDW to near IR with a tiny core size of less than 5 µm but a large evanescent wave loss exists in these fibers. In this paper, we prepared a novel suspended-core fiber (SCF) based on chalcohalide glasses for the first time via the extrusion method, in which the ZDW of the fundamental mode in the fiber with a core size of larger than 30 µm was successfully shifted to 2.6 µm. We also calculated confinement loss (CL) of propagation modes and fundamental mode energy ratio in the fiber. We found that the minimum CL ratio of the high order modes (LP11) to the CL of the fundamental mode is 124, indicating that the single-mode operation condition is satisfied when the wavelength is more than 4.6 µm. The lowest transmission loss is 1.2 dB/m at 6.5 µm. An ultra-broad supercontinuum spectrum, covering from 1.6 to 12 µm was generated in this suspended-core fiber pumped by a 5 µm femtosecond laser. Such a wide SC in the chalcogenide SCF is due to the large core size. All these results demonstrate the potential to use the large core SCF in the application of a mid-IR laser.

High-efficiency tunable femtosecond solitons generation from 1.9 to 2.35 µm in a thulium-doped fiber amplifier via precise seed-pulse management.

We demonstrate the tunable Raman femtosecond solitons generation with a record-breaking power of 1.2 W at 2.3 µm and an ever-reported highest Raman soliton energy conversion efficiency of 99% via precise seed-pulse management in the thulium-doped single-mode fiber amplifier. We find that the central wavelength and the chirp of the incident pulses could dramatically affect the red-shifted soliton energy, locations, conversion efficiency, and the threshold power in fundamental Raman soliton generation. For the first time, we experimentally illustrated how the seed pulse with Kelly sidebands could affect the Raman solitons generation in this amplifier, and obtained the detailed regularity between the parameters of incident pulses and the properties of the generated solitons. This work provides useful guidance for Raman soliton-based high-power mid-infrared femtosecond laser fabrication.

Se-H-free As2Se3 fiber and its spectral applications in the mid-infrared.

The complete removal of the impurities like Se-H in Se-based chalcogenide glasses has been challenging in the development of highly transparent chalcogenide glass fiber. In this paper, several purification methods, including dynamic distillation, static distillation, and combined distillation method, were adopted with an aim of purifying arsenic selenide glass with ultra-low content of the impurities. The experimental results demonstrated that the Se-H can be completely eliminated in the arsenic selenide glass host and fiber without the introduction of any chloride. We further explored the applications of such low loss and Se-H-free chalcogenide glass fiber in the mid-infrared. It was found that, using such a Se-H free fiber, a flattened supercontinuum spectrum above the -30 dB level from 1.2 to 13 µm was generated from the Se-H free fiber with a 5.5 µm laser pumping. The sensitivity was found to be improved 5.1 times for CO2 gas in the 3 to 6 µm wavelength range.

High-sensitivity micro-strain sensing using a broadband wavelength-tunable thulium-doped all-fiber structured mode-locked laser.

We demonstrate a thulium-doped mode-locked fiber laser with ultra-broadband wavelength tunability for micro-strain sensing based on the multimode interference (MMI) effect in single-mode-multimode-single-mode (SMS) fiber configuration. The homemade SMS device with high performance is fusion spliced in the laser cavity, and the developed dispersion precisely managed the all-fiber structured mode-locked picosecond laser with a record-breaking wavelength tuning range from 1976 to 1916 nm while exerting axial strain on this SMS device. We experimentally explored the regularity between the strain and the central-wavelength shift of the mode-locked pulse, and for the first time to the best of the authors' knowledge, achieved the precise in-line axial strain measurement from 0 to 5385 µÉ› by using the tunable ultrafast-laser-based sensor, and sensitivity is up to -11.5 pm/µÉ›. With high compactness and durability, this sensor has advantages in real-time dynamic measurement over other passive devices, thus will undoubtedly find various application scenarios.

Generation of watt-level supercontinuum covering 2-6.5 µm in an all-fiber structured infrared nonlinear transmission system.

We demonstrate a watt-level mid-infrared supercontinuum source, with the spectrum covering the infrared region from 2 to 6.5 µm, in an all-fiber structured laser transmission system. To further improve the SC spectral bandwidth, power and system compactness in the follow-up As2S3 fiber, we theoretically and experimentally explored some knotty problems that would potentially result in the As2S3 fiber end-facet failure and low SC output power during the high-power butt-coupling process and proposed an optimal coupling distance on the premise of the safety of As2S3 fiber end face. In addition, we also built a multi-pulse pumping model for the first time to more precisely estimate the SC spectral evolution in As2S3 fiber. This work will give an important reference to someone who is working on the all-fiber structured, high-power mid- and far-infrared supercontinuum source.

Metallic 2H-Tantalum Selenide Nanomaterials as Saturable Absorber for Dual-Wavelength Q-Switched Fiber Laser.

A novel 2H-phase transition metal dichalcogenide (TMD)-tantalum selenide (TaSe2) with metallic bandgap structure is a potential photoelectric material. A band structure simulation of TaSe2 via ab initio method indicated its metallic property. An effective multilayered TaSe2 saturable absorber (SA) was fabricated using liquid-phase exfoliation and optically driven deposition. The prepared 2H-TaSe2 SA was successfully used for a dual-wavelength Q-switched fiber laser with the minimum pulse width of 2.95 µs and the maximum peak power of 64 W. The repetition rate of the maximum pulse energy of 89.9 kHz was at the level of 188.9 nJ. The metallic 2H-TaSe2 with satisfactory saturable absorbing capability is a promising candidate for pulsed laser applications.

Mid-infrared flattened supercontinuum generation in all-normal dispersion tellurium chalcogenide fiber.

We have prepared a well-structured tellurium chalcogenide (ChG) fiber with a specialized double cladding structure by an improved extrusion method, and experimentally demonstrated an ultra-flat mid-infrared (MIR) supercontinuum (SC) generation in such a fiber. The step-index fiber had an optical loss of <1 dB/m in a range from 7.4 to 9.7 µm with a minimum loss of 0.69 dB/m at 7.87 µm. Simulation showed that an all-normal dispersion profile can be realized in this double cladding tellurium fiber. An ultra-flat MIR SC spectrum (~3.2-12.1µm at -10 dB, ~2-14 µm at -30 dB) was generated from a 22-cm long fiber pumped with a femtosecond laser at 5 µm (~150 fs, 1 kHz). Then the degree of coherence was calculated out based on a simulation, showing that a high coherent MIR SC (from 2.9 to 13.1 µm) can be generated in this double-cladding tellurium fiber.

1.2-15.2 µm supercontinuum generation in a low-loss chalcohalide fiber pumped at a deep anomalous-dispersion region.

A novel low-loss selenium-based chalcohalide fiber, with a low zero-dispersion wavelength, was prepared by an innovative preparation process. The composition optimized fiber has a wide transmission range of up to 11.5 µm, a lowest fundamental mode zero-dispersion wavelength of 4.03 µm, and a minimum optical loss of 1.12 dB/m at 6.4 µm, which provides a possibility to replace As2S3 and As2Se3 in a cascade of ZrF4-BaF2-LaF3-AlF3-NaF(ZBLAN)-As2S3-As2Se3 fiber in the practical all-fiberized supercontinuum (SC) source. Meanwhile, the broadest SC spectrum, ∼1.2 to 15.2 µm, was achieved by pumping a 12-cm-long fiber with a femtosecond laser at a deep anomalous-dispersion region. Furthermore, simulations are adopted to interpret the results as well as to demonstrate spectral evolution along the fiber. To the best of our knowledge, this is the broadest SC spectrum reported in any selenium-based chalcogenide fiber.

Shortening Nucleation Time to Enable Ultrafast Phase Transition in Zn1Sb7Te12 Pseudo-Binary Alloy.

Zn1Sb7Te12 thin films have been deposited by magnetron co-sputtering of ZnTe and Sb2Te3 targets. The microstructure, phase-change speed, optical cycling stability, and crystallization kinetics have been investigated during thermal annealing and laser irradiation. The thermal-annealed and laser-irradiated films give a clear evidence of the coexistence of trigonal Sb2Te3 and cubic ZnTe phases, which are homogeneously distributed in a single alloy as confirmed by advanced scanning transmission electron microscopy. The formation of both phases increases the initial nucleation sites, leading to the rapid phase-change speed in the Zn1Sb7Te12 film. The film has a minimum crystallization time of ∼3 ns at 70 mW with almost no incubation period for the formation of critical nuclei compared to Ge2Sb2Te5 and other Zn-based films. Moreover, the complete crystallization of Zn1Sb7Te12 thin films is achieved within 10 ns. The ultrafast two-dimensional nucleation and crystal growth speed in Zn1Sb7Te12 obtained from the laser-irradiated system is almost 7 times faster compared to that in Ge2Sb2Te5 film. Controlling the crystallization process through doping ZnTe into Sb2Te3 is thus promising for the development of high-speed optical switching technology.

Extension of the Swanepoel method for obtaining the refractive index of chalcogenide thin films accurately at an arbitrary wavenumber.

The well-known Swanepoel method was often used to obtain the refractive index (RI) of thin films at the wavenumber values corresponding to the extremes of the transmission interference fringes. But it is difficult to accurately obtain the RI of chalcogenide thin films, especially at an arbitrary wavenumber. So a regional approach method (RAM) was presented here to extend the Swanepoel method to an arbitrary wavenumber. In the RAM the RI at the arbitrary wavenumber was determined through dynamic matching. The calculated values were used to match the experimental transmittance. The accuracy of the RI is better than 0.5%. The RI of a well-known film was obtained by the RAM. And the results are in great agreement with the true values of the RI of the film which indicates the correctness and effectiveness of the RAM. Moreover, the transmission spectrum of Ge-Sb-Se film was measured in the ultra-broadband range of 2000-18000 cm-1 (555-5000 nm), and finally the RI of the film was obtained at the 22 wavenumbers of the spacer 600 cm-1 by the RAM.

Broadband mid-infrared supercontinuum generation in 1-meter-long As2S3-based fiber with ultra-large core diameter.

In this study, the supercontinuum (SC) generation in a 1-m-long As2S3 fiber with a 200 µm core diameter was demonstrated experimentally. The high-purity As2S3 fiber we used exhibited very low optical loss with a background loss of approximately 0.1 dB/m at a wavelength of 2-5 µm. SC generation was studied by pumping the fiber at different wavelengths and different peak powers. A strong spectral broadening with a 30 dB spectral flatness spanning from 1.4 to 7.0 µm was obtained when the fiber was pumped with 150 fs short pulses at 5.0 µm. The SC generation in bent fiber was also studied. The result showed that the bending radius of the fiber will significantly affect the SC spectra bandwidth and the output power. The SC spectra in the used fiber could still be maintained when it was bent to a radius of 5 cm.

1.5-14 µm midinfrared supercontinuum generation in a low-loss Te-based chalcogenide step-index fiber.

We have experimentally demonstrated midinfrared (MIR) supercontinuum (SC) generation in a low-loss Te-based chalcogenide (ChG) step-index fiber. The fiber, fabricated by an isolated extrusion method, has an optical loss of 2-3 dB/m at 6.2-10.3 µm and 3.2 dB/m at 10.6 µm, the lowest value reported for any Te-based ChG step-index fiber. A MIR SC spectrum (∼1.5 to 14 µm) is generated from the 23-cm fiber pumped by a 4.5 µm laser (∼150 fs, 1 kHz). To the best of our knowledge, this is the first SC experimental demonstration in Te-based ChG fiber and the broadest MIR SC generation pumped in the normal dispersion regime in the optical fibers.

Reverse pillar chalcogenide glass waveguides with ultraflat and low dispersion profile over an ultrawide bandwidth.

Two types of reverse pillar integrated chalcogenide glass (As2S3) waveguides are proposed in this study. These geometries exhibit an ultraflat and low dispersion profile with four zero dispersion wavelengths. Its low dispersion is approximately ±10 ps/nm/km over a 2240 nm bandwidth (for L waveguide) and ±13 ps/nm/km over a 2030 nm bandwidth (for F waveguide). Waveguide dispersion engineering is achieved by tuning the structural parameters of the waveguide, which has less sensitivity to the variations of structural parameters compared with silicon pillar waveguides. Moreover, the nonlinear coefficient and phase-matching condition in four-wave mixing (FWM) showed a great potential for broadband FWM processes in the near- and middle-infrared regions.

Investigation on Spectral Characteristic and Threshold Behavior of Network Structure of Ge-Sb-S Chalcogenide Glasses.

Two series of chalcogenide glasses in Ge-Sb-S ternary system were synthesized with melt-quenching method. The phycochemical properties and spectral characteristic of glasses with different content of Ge and Sb were obtained with a series of measurements, and the systematic analysis on the change of optical properties was conducted in terms of microstructure of glasses combined with the Raman spectra. With constraint theory based on mean coordination number (Z), we described the variation trend of network structure directly. It was found that as long as the value of Z reaches 2.6, new vibration peaks would be formed in the Raman spectra indicating the presence of threshold behavior as well as the change of the network structure of the Ge-Sb-S glasses which could be expressed in a specific varition in the number of metal bonds and the nonmetal bonds. The appearance of new functional groups in the network have changed the total bond energy of glasses, and then affected the energy band structure of glasses representing the corresponding threshold behavior of the value of optical band gap (Eopg).

Quantum cutting in Pr3+-Yb3+ codoped chalcohalide glasses for high-efficiency c-Si solar cells.

Downconversion materials, which can convert one high-energy photon to two low-energy photons, have provided a promising avenue for the enhancement of solar cell efficiency. In this work, the Pr3+-Yb3+ codoped 25GeS2-35Ga2S3-40CsCl chalcohalide glasses were synthesized in a vacuumed silica ampoule by the melting-quenching technique. Under 474 nm excitation, the visible and near-IR emission spectra reveal the energy transfer from Pr3+ to Yb3+ ions, resulting in the intense 1008 nm near-IR emission for the c-Si solar cells. By tuning the excitation laser power, it is determined that one visible photon has been cut into two near-IR photons during the energy transfer process. With the help of an integrated sphere, the real quantum yields of near-IR emissions were calculated. For the 0.2Pr2S3-0.2Yb2S3 (in mol.%) codoped chalcohalide glass, the quantum yield equals 10.8%. Although this efficiency is still low, this result will open a new route to realize the efficient spectral modification of the solar spectrum.

Clinical Effect of Acupuncture Combined with Traditional Chinese Medicine Application on the Treatment of Functional Dyspepsia in Children and the Influence on Serum 5-HT and NO Levels.

Objective: To explore the clinical effect of acupuncture combined with traditional Chinese medicine (TCM) application on the treatment of functional dyspepsia (FD) in children and the influence on serum 5-HT and NO levels. Methods: 94 FD children admitted to the pediatric department of our hospital from March 2019 to March 2020 were selected as the research object and divided into the study group (n = 45) and reference group (n = 49) by the number table method. The routine Western medicine therapy was given to the reference group and the combination therapy of acupuncture and TCM application was given to the study group to analyze the effect of different therapies on FD children by detecting their serum 5-hydroxytryptamine (5-HT) and nitric oxide (NO) levels and electrogastrogram (EGG) before and after treatment. Results: The sex ratio, mean age, mean duration of disease, mean weight, mean BMI value, and residence of children in the two groups were not significantly different (P > 0.05); after treatment, the study group obtained significantly lower symptom scores and shorter disappearance time of clinical symptoms when comparing with the reference group (P < 0.001); the total clinical effective rate of the study group was significantly higher than that of the reference group (P < 0.05); the treated serum 5-HT and NO levels of children in both groups were significantly lower than those before treatment (P < 0.05), and in the between-group comparison, those of the study group were significantly lower (P < 0.05); and the treated AP, FP, and normal slow wave ratio of gastric antrum and body were significantly higher in the study group than in the reference group (P < 0.05). Conclusion: The combination therapy of acupuncture and TCM application is a reliable method for improving the clinical symptoms in FD children. This strategy greatly reduces the levels of serum factors in child patients and shortens the corresponding treatment time. Further research will be conducive to establishing a better solution for such patients.