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MXene has attracted considerable attention for supercapacitor applications in the past decade owing to its exceptional electrochemical properties. Although major research interests are focused on composite-based MXene, doping engineering of MXene has recently emerged as a promising alternative. This work unveils the potential of doped MXene for supercapacitor applications with a critical perspective. Various doping engineering strategies and synthesis methods adopted are explicitly delineated. Detailed discussions on the optimization of lattice, functionalization, substitution, and interface modification are provided. Further, it sheds light on recent developments with the asssociated mechanism of doped MXene supercapacitors, followed by the associated challenges. Finally, a roadmap for further progress of doped MXene for the realization of advanced and high-performing energy storage systems has been described. We envision that this Perspective will open up new avenues for the further exploration of this domain.
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Prompt recombination of photoproduced charges in bulk and surface of a photocatalyst significantly impedes catalytic efficiency. To address these challenges, FeOOH nanorods (NRs) anchored NaNbO3 (NNO) piezoelectric microcubes (MCs) have been fabricated for ciprofloxacin (CIP) degradation and oxygen evolution through water splitting by coupling macroscopic spontaneous piezoelectric polarization and a built-in electric field. The local electric field induced by surface oxygen vacancies (Ovs) and orientation of FeOOH NRs over NNO MCs afford the polarization electric field a significant boost, driving the quick separation/migration of charge carriers from bulk to the surface. The polarized NNO/FeOOH composite with ample Ovs demonstrates an outstanding piezophotocatalytic CIP degradation of 93% in 1 h, higher than pristine materials (NNO and FeOOH), and a high O2 evolution rate of 1155 µmol h-1. The effect of piezoelectric polarization on the catalytic activity is supplemented by theoretical simulations. This work offers an avenue for selective pollutant remediation and water splitting through the rational design of piezoelectric polarization-mediated heterostructure systems with surface Ovs.
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Ciprofloxacina , Oxigênio , Catálise , Água , Modelos Teóricos , Preparações FarmacêuticasRESUMO
Bone exhibits piezoelectric properties. Thus, electrical stimulations such as pulsed electromagnetic fields (PEMFs) and stimuli-responsive piezoelectric properties of scaffolds have been investigated separately to evaluate their efficacy in supporting osteogenesis. However, current understanding of cells responding under the combined influence of PEMF and piezoelectric properties in scaffolds is still lacking. Therefore, in this study, we fabricated piezoelectric scaffolds by functionalization of polycaprolactone-tricalcium phosphate (PCL-TCP) films with a polyvinylidene fluoride (PVDF) coating that is self-polarized by a modified breath-figure technique. The osteoinductive properties of these PVDF-coated PCL-TCP films on MC3T3-E1 cells were studied under the stimulation of PEMF. Piezoelectric and ferroelectric characterization demonstrated that scaffolds with piezoelectric coefficient d33 = -1.2 pC/N were obtained at a powder dissolution temperature of 100 °C and coating relative humidity (RH) of 56%. DNA quantification showed that cell proliferation was significantly enhanced by PEMF as low as 0.6 mT and 50 Hz. Hydroxyapatite staining showed that cell mineralization was significantly enhanced by incorporation of PVDF coating. Gene expression study showed that the combination of PEMF and PVDF coating promoted late osteogenic gene expression marker most significantly. Collectively, our results suggest that the synergistic effects of PEMF and piezoelectric scaffolds on osteogenesis provide a promising alternative strategy for electrically augmented osteoinduction. The piezoelectric response of PVDF by PEMF, which could provide mechanical strain, is particularly interesting as it could deliver local mechanical stimulation to osteogenic cells using PEMF.
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Fosfatos de Cálcio , Materiais Revestidos Biocompatíveis , Campos Eletromagnéticos , Osteogênese , Poliésteres , Polivinil , Alicerces Teciduais , Regeneração Óssea , Diferenciação Celular , Proliferação de Células , Células Cultivadas , Materiais Revestidos Biocompatíveis/química , Expressão Gênica , Osteogênese/efeitos dos fármacos , Osteogênese/genética , Osteogênese/efeitos da radiação , Poliésteres/química , Poliésteres/farmacologia , Polivinil/química , Solventes , Engenharia Tecidual , Difração de Raios XRESUMO
With the rapid development of wearable electronic systems, the need for stretchable nanogenerators becomes increasingly important for autonomous applications such as the Internet-of-Things. Piezoelectric nanogenerators are of interest for their ability to harvest mechanical energy from the environment with its inherent polarization arising from crystal structures or molecular arrangements of the piezoelectric materials. In this work, 3D printing is used to fabricate a stretchable piezoelectric nanogenerator which can serve as a self-powered sensor based on synthesized oxide-polymer composites.
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Rheumatoid arthritis (RA) is a systemic immune disorder marked by synovitis, bone damage, and cartilage erosion, leading to increased socio-economic burdens and reduced quality of life. Despite its unknown cause, advancements in understanding its pathophysiology have facilitated novel therapeutic approaches. Current treatments, including disease-modifying anti-rheumatic drugs (DMARDs) and biologics, often result in low efficacy and unnecessary side effects. To address the limitations of these drugs, carrier-based drug delivery systems, such as nanomicelles, have emerged as a promising solution. In this study, nanomicelles were synthesised utilizing PLGA (poly(lactic-co-glycolic acid)) as a backbone; this backbone is conjugated with chlorogenic acid (CGA), which is known for suppressing inflammation, and incorporates methotrexate (MTX), a model drug that is established for RA treatment. The nanomicelles were extensively characterized in terms of size, charge, drug loading, and drug-release behaviour. The in vivo assessment of MTX-PLGA-b-CGA nanomicelles in a collagen-induced arthritis model demonstrated a remarkable reduction in joint swelling, cartilage erosion, and disease severity. Furthermore, histological findings confirmed cartilage integrity and reduced expression of key pro-inflammatory markers, including receptor activator of nuclear factor kappa beta ligand (RANKL) and tumor necrosis factor (TNF-α). The approach based on the MTX-PLGA-b-CGA nanomicelles presents a biocompatible and potentially effective therapeutic strategy for management of the severity and progression of RA, providing a hopeful alternative for RA treatment.
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Artrite Experimental , Ácido Clorogênico , Metotrexato , Micelas , Copolímero de Ácido Poliláctico e Ácido Poliglicólico , Animais , Ácido Clorogênico/química , Ácido Clorogênico/farmacologia , Ácido Clorogênico/administração & dosagem , Metotrexato/química , Metotrexato/farmacologia , Metotrexato/administração & dosagem , Artrite Experimental/tratamento farmacológico , Artrite Experimental/patologia , Copolímero de Ácido Poliláctico e Ácido Poliglicólico/química , Camundongos , Portadores de Fármacos/química , Masculino , Liberação Controlada de Fármacos , Nanopartículas/química , Artrite Reumatoide/tratamento farmacológicoRESUMO
Although extensive research has been performed on metal oxide-based supercapacitors during recent years, they remain lacking in their intrinsic conductivity and stability. To resolve this, 1D/2D heterostructure materials are being utilized, which significantly improves the performance and stability of both materials while employing their synergistic advantage consisting of morphologically tuned surfaces and superior electroactive sites. However, the performance remains unsatisfactory due to the sluggish faradaic reaction at the electrode/electrolyte interface. To address this challenge, we combined the synergistic advantage of morphological nanoengineering and the fast reaction kinetics of redox mediators, thus anticipating superior energy storage performance. A novel 1D/2D heterostructure of ZnCo2O4 (ZCO) and GaN was designed and implemented for the first time, and it demonstrated an excellent specific capacitance of 1693 F g-1 in the mixed electrolyte of KOH and K4[Fe(CN)6]. The all-solid-state flexible hybrid supercapacitor delivered an energy density of 92.63 W h kg-1 at a power density of 1287.52 W kg-1, with superb stability and mechanical endurance that outperformed previously reported ZCO-based materials. Additionally, we delineated the underlying mechanism governing the utilization of redox mediators along with morphological nanoengineering, which will facilitate the current development of state-of-the-art energy storage systems.
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Foreshadowing future needs has catapulted the progress of skin-like electronic devices for human-machine interactions. These devices possess human skin-like properties such as stretchability, self-healability, transparency, biocompatibility, and wearability. This review highlights the recent progress in a promising material, MXenes, to realize soft, deformable, skin-like electrodes. Various structural designs, fabrication strategies, and rational guidelines adopted to realize MXene-based skin-like electrodes are outlined. We explicitly discussed machine learning-based material informatics to understand and predict the properties of MXenes. Finally, an outlook on the existing challenges and the future roadmap to realize soft skin-like MXene electrodes to facilitate technological advances in the next-generation human-machine interactions has been described.
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To address the growing energy demand, remarkable progress has been made in transferring the fossil fuel-based economy to hydrogen-based environmentally friendly photocatalytic technology. However, the sluggish production rate due to the quick charge recombination and slow diffusion process needs careful engineering to achieve the benchmark photocatalytic efficiency. Piezoelectric photocatalysis has emerged as a promising field in recent years due to its improved catalytic performance facilitated by a built-in electric field that promotes the effective separation of excitons when subjected to mechanical stimuli. This review discusses the recent progress in piezo-photocatalytic hydrogen evolution while elaborating on the mechanistic pathway, effect of piezo-polarization and various strategies adopted to improve piezo-photocatalytic activity. Moreover, our review systematically emphasizes the fundamentals of piezoelectricity and piezo-phototronics along with the operational mechanism for designing efficient piezoelectric photocatalysts. Finally, the summary and outlooks provide insight into the existing challenges and outline the future prospects and roadmap for the development of next-generation piezo-photocatalysts towards hydrogen evolution.
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Hidrogênio , CatáliseRESUMO
Piezoelectric materials convert mechanical stress to electrical energy and thus are widely used in energy harvesting and wearable devices. However, in the piezoelectric family, there are two pairs of properties that improving one of them will generally compromises the other, which limits their applications. The first pair is piezoelectric strain and voltage constant, and the second is piezoelectric performance and mechanical softness. Here, we report a molecular bond weakening strategy to mitigate these issues in organic-inorganic hybrid piezoelectrics. By introduction of large-size halide elements, the metal-halide bonds can be effectively weakened, leading to a softening effect on bond strength and reduction in polarization switching barrier. The obtained solid solution C6H5N(CH3)3CdBr2Cl0.75I0.25 exhibits excellent piezoelectric constants (d33 = 367 pm/V, g33 = 3595 × 10-3 Vm/N), energy harvesting property (power density is 11 W/m2), and superior mechanical softness (0.8 GPa), promising this hybrid as high-performance soft piezoelectrics.
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For emerging biocompatible, wearable, and stretchable epidermal electronic devices, it is essential to realize novel stretchable conductors with the attributes of transparency, low-cost and nontoxic components, green-solvent processbility, self-healing, and thermal stabililty. Although conducting materials-rubber composites, ionic hydrogels, organogels have been developed, no stretchable material system that meets all the outlined requirements has been reported. Here, a series of P(SPMA-r-MMA) polymers with different ratios of ionic side chains is designed and synthesized, and it is demonstrated that the resulting stretchable ionic conductors with glycerol are transparent, water processable, self-healable, and thermally stable due to the chemically linked ionic side chain, satisfying all of the aforementioned requirements. Among the series of polymer gels, the P(SPMA0.75 -r-MMA0.25 ) gel shows optimum conductivity (6.7 × 10-4 S cm-1 ), stretchability (2636% of break at elongation), and self-healing (98.3% in 3 h) properties. Accordingly, the transparent and self-healable P(SPMA0.75 -r-MMA0.25 ) gels are used to realize thermally robust actuators up to 100 °C and deformable and self-healable thermal sensors.
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Stretchable and self-healing (SH) energy storage devices are indispensable elements in energy-autonomous electronic skin. However, the current collectors are not self-healable nor intrinsically stretchable, they mostly rely on strain-accommodating structures that require complex processing, are often limited in stretchability, and suffer from low device packing density and fragility. Here, an SH conductor comprising nickel flakes, eutectic gallium indium particles (EGaInPs), and carboxylated polyurethane (CPU) is presented. An energy storage device is constructed by the two SH electrodes assembled with graphene nanoplatelets sandwiching an ionic-liquid electrolyte. An excellent electrochemical healability (94% capacity retention upon restretching at 100% after healing from bifurcation) is unveiled, stemming from the complexation modulated redox behavior of EGaIn in the presence of the ligand bis(trifluoromethanesulfonyl)imide, which enhances the reversible Faradaic reaction of Ga. Self-healing can be achieved where the damaged regions are electrically restored by the flow of liquid metal and mechanically healing activated by the interfacial hydrogen bonding of CPU with an efficiency of 97.5% can be achieved. The SH conductor has an initial conductivity of 2479 S cm-1 that attains a high stretchability with 700% strain, it restores 100% stretchability even after breaking/healing with the electrical healing efficiency of 75%.
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Advances in next-generation soft electronic devices rely on the development of highly deformable, healable, and printable energy generators to power these electronics. Development of deformable or wearable energy generators that can simultaneously attain extreme stretchability with superior healability remains a daunting challenge. We address this issue by developing a highly conductive, extremely stretchable, and healable composite based on thermoplastic elastomer with liquid metal and silver flakes as the stretchable conductor for triboelectric nanogenerators. The elastomer is used both as the matrix for the conductor and as the triboelectric layer. The nanogenerator showed a stretchability of 2500% and it recovered its energy-harvesting performance after extreme mechanical damage, due to the supramolecular hydrogen bonding of the thermoplastic elastomer. The composite of the thermoplastic elastomer, liquid metal particles, and silver flakes exhibited an initial conductivity of 6250 S cm-1 and recovered 96.0% of its conductivity after healing.
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Ruddlesden-Popper (RP) halide perovskites are the new kids on the block for high-performance perovskite photovoltaics with excellent ambient stability. The layered nature of these perovskites offers an exciting possibility of harnessing their ferroelectric property for photovoltaics. Adjacent polar domains in a ferroelectric material allow the spatial separation of electrons and holes. Presently, the structure-function properties governing the ferroelectric behavior of RP perovskites are an open question. Herein, we realize tunable ferroelectricity in 2-phenylethylammonium (PEA) and methylammonium (MA) RP perovskite (PEA)2(MA) nÌ -1Pb nÌ I3 nÌ +1. Second harmonic generation (SHG) confirms the noncentrosymmetric nature of these polycrystalline thin films, whereas piezoresponse force microscopy and polarization-electric field measurements validate the microscopic and macroscopic ferroelectric properties. Temperature-dependent SHG and dielectric constant measurements uncover a phase transition temperature at around 170 °C in these films. Extensive molecular dynamics simulations support the experimental results and identified the correlated reorientation of MA molecules and ion translations as the source of ferroelectricity. Current-voltage characteristics in the dark reveal the persistence of hysteresis in these devices, which has profound implications for light-harvesting and light-emitting applications. Importantly, our findings disclose a viable approach for engineering the ferroelectric properties of RP perovskites that may unlock new functionalities for perovskite optoelectronics.
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Textiles that are capable of harvesting biomechanical energy via triboelectric effects are of interest for self-powered wearable electronics. Fabrication of conformable and durable textiles with high triboelectric outputs remains challenging. Here we propose a washable skin-touch-actuated textile-based triboelectric nanogenerator for harvesting mechanical energy from both voluntary and involuntary body motions. Black phosphorus encapsulated with hydrophobic cellulose oleoyl ester nanoparticles serves as a synergetic electron-trapping coating, rendering a textile nanogenerator with long-term reliability and high triboelectricity regardless of various extreme deformations, severe washing, and extended environmental exposure. Considerably high output (~250-880 V, ~0.48-1.1 µA cm-2) can be attained upon touching by hand with a small force (~5 N) and low frequency (~4 Hz), which can power light-emitting diodes and a digital watch. This conformable all-textile-nanogenerator is incorporable onto cloths/skin to capture the low output of 60 V from subtle involuntary friction with skin, well suited for users' motion or daily operations.
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Fontes de Energia Elétrica , Eletricidade , Nanopartículas/química , Fósforo/química , Pele/anatomia & histologia , Têxteis , Tato/fisiologia , Fenômenos Biomecânicos , Fricção , Humanos , Movimento (Física)RESUMO
Recently developed triboelectric nanogenerators (TENGs) act as a promising power source for self-powered electronic devices. However, the majority of TENGs are fabricated using metallic electrodes and cannot achieve high stretchability and transparency, simultaneously. Here, slime-based ionic conductors are used as transparent current-collecting layers of TENG, thus significantly enhancing their energy generation, stretchability, transparency, and instilling self-healing characteristics. This is the first demonstration of using an ionic conductor as the current collector in a mechanical energy harvester. The resulting ionic-skin TENG (IS-TENG) has a transparency of 92% transmittance, and its energy-harvesting performance is 12 times higher than that of the silver-based electronic current collectors. In addition, they are capable of enduring a uniaxial strain up to 700%, giving the highest performance compared to all other transparent and stretchable mechanical-energy harvesters. Additionally, this is the first demonstration of an autonomously self-healing TENG that can recover its performance even after 300 times of complete bifurcation. The IS-TENG represents the first prototype of a highly deformable and transparent power source that is able to autonomously self-heal quickly and repeatedly at room temperature, and thus can be used as a power supply for digital watches, touch sensors, artificial intelligence, and biointegrated electronics.
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Molybdenum trioxide is an interesting inorganic system in which the empty 4d states have potential to hold extra electrons and therefore can change states from insulating opaque (MoO3) to colored semimetallic (HxMoO3). Here, we characterize the local electrogeneration and charge transfer of the synthetic layered two-dimensional 2D MoO3-II (a polymorph of MoO3 and analogous to α-MoO3) in response to two different redox couples, i.e., [Ru(NH3)6]3+ and [Fe(CN)6]3- by scanning electrochemical microscopy (SECM). We identify the reduction of [Ru(NH3)6]3+ to [Ru(NH3)6]2+ at the microelectrode that leads to the reduction of MoO3-II to conducting blue-colored molybdenum bronze HxMoO3. It is recognized that the dominant conduction of the charges occurred preferentially at the edges active sites of the sheets, as edges of the sheets are found to be more conducting. This yields positive feedback current when approaching the microelectrode toward 2D MoO3-II-coated electrode. In contrast, the [Fe(CN)6]4-, which is reduced from [Fe(CN)6]3-, is found unfavorable to reduce MoO3-II due to its higher redox potential, thus showing a negative feedback current. The charge transfer on MoO3-II is further studied as a function of applied potential. The results shed light on the charge transfer behavior on the surface of MoO3-II coatings and opens the possibility of locally tuning of their oxidation states.
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Smart sensing electronic devices with good transparency, high stretchability, and self-powered sensing characteristics are essential in wearable health monitoring systems. This paper innovatively proposes a stretchable nanocomposite nanogenerator with good transparency that can be conformally attached to the human body to harvest biomechanical energy and monitor physiological signals. The work reports an innovative device that uses sprayed silver nanowires as transparent electrodes and sandwiches a nanocomposite of piezoelectric BaTiO3 and polydimethylsiloxane as the sensing layer, which exhibits good transparency and mechanical transformability with stretchable, foldable, and twistable properties. The highly flexible nanogenerator affords a good input-output linearity under the vertical force and the sensing ability to detect lateral stretching deformation up to 60% strain under piezoelectric mechanisms. Furthermore, the proposed device can effectively harvest touch energies from the human body as a single-electrode triboelectric nanogenerator. Under periodic contact and separation, a maximum output voltage of 105 V, a current density of 6.5 µA/cm2, and a power density of 102 µW/cm2 can be achieved, exhibiting a good power generation performance. Owing to the high conformability and excellent sensitivity of the nanogenerator, it can also act as a self-powered wearable sensor attached to different parts of the human body for real-time monitoring of the human physiological signals such as eye blinking, pronunciation, arm movement, and radial artery pulse. The designed nanocomposite nanogenerator shows great potential for use in self-powered e-skins and healthcare monitoring systems.
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Nanocompostos , Fontes de Energia Elétrica , Monitorização Fisiológica , Nanotecnologia , NanofiosRESUMO
Ferroelectric materials have attracted interest in recent years due to their application in energy harvesting owing to its piezoelectric nature. Ferroelectric polymers are flexible and can sustain larger strains compared to inorganic counterparts, making them attractive for harvesting energy from mechanical vibrations. Herein, we report, for the first time, the enhanced piezoelectric energy harvesting performance of the bilayer films of poled poly(vinylidene fluoride-trifluoroethylene) [PVDF-TrFE] and graphene oxide (GO). The bilayer film exhibits superior energy harvesting performance with a voltage output of 4 V and power output of 4.41 µWcm(-2) compared to poled PVDF-TrFE films alone (voltage output of 1.9 V and power output of 1.77 µWcm(-2)). The enhanced voltage and power output in the presence of GO film is due to the combined effect of electrostatic contribution from graphene oxide, residual tensile stress, enhanced Young's modulus of the bilayer films, and the presence of space charge at the interface of the PVDF-TrFE and GO films, arising from the uncompensated polarization of PVDF-TrFE. Higher Young's modulus and dielectric constant of GO led to the efficient transfer of mechanical and electrical energy.
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Mixed-metal molybdates are interesting host materials for ion-insertion electrodes due to their versatile crystal chemistry, which confers a highway for the conduction of electrons as well as ions. Silver decamolybdate in triclinic crystal structure (T-Ag6 Mo10 O33 ) consists of layers of MoO6 octahedra separated by arrays of silver ions that are able to store a high amount of charges.