1.
J Am Chem Soc
; 137(10): 3450-3, 2015 Mar 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25715659
RESUMO
We present the synthesis of a two-dimensional polymer at the air/water interface and its nm-resolution imaging. Trigonal star, amphiphilic monomers bearing three anthraceno groups on a central triptycene core are confined at the air/water interface. Compression followed by photopolymerization on the interface provides the two-dimensional polymer. Analysis by scanning tunneling microscopy suggests that the polymer is periodic with ultrahigh pore density.