Fresnel Diffraction Strategy Enables the Fabrication of Flexible Superomniphobic Surfaces.

Doubly re-entrant surfaces inspired by springtails exhibit excellent repellency to low-surface-tension liquid. However, the flexible doubly re-entrant surfaces are difficult to fabricate, especially for the overhang of the structure. Herein, we demonstrate a simple Fresnel aperture diffraction modulation strategy in microscale lithography coupled with a molding process to obtain the flexible doubly re-entrant superomniphobic surfaces with nanoscale overhangs. The negative nanoscale overhang features were formed in a single-layer photoresist due to the fine-modulation of the optical intensity fluctuation of the Fresnel aperture diffraction. The as-prepared flexible non-fluorinated polydimethylsiloxane (PDMS) doubly re-entrant microstructure based on the Fresnel aperture diffraction (D-BF) surface (without any additional treatments) could repel ethanol droplets (21.8 mN m-1) in the Cassie-Baxter state. The robust nanoscale overhangs obtained by the molding process enable the maximum breakthrough pressure for the low-surface-tension ethanol droplets on the D-BF surfaces up to about 230 Pa, allowing ethanol liquids with Weber numbers up to 8.7 to fully bounce off. The fabricated non-fluorinated D-BF superomniphobic surface maintains outstanding liquid repellency after the surface wettability modification and deformation test.

One-Step Fabrication of Flexible Bioinspired Superomniphobic Surfaces.

Flexible superomniphobic doubly re-entrant (Dual-T) microstructures inspired by springtails have attracted growing attention due to their excellent liquid-repellent properties. However, the simple and practical manufacturing processes of the flexible Dual-T microstructures are urgently needed. Here, we proposed a one-step molding process coupled with the lithography technique to fabricate the elastomeric polydimethylsiloxane (PDMS) Dual-T microstructure surfaces with high uniformity. The angle between the downward overhang and the horizontal direction could reach 90° (vertical overhang). The flexible superomniphobic Dual-T microstructure surfaces, without fluorination treatment and physical treatments, could repel liquids with a surface tension lower than 20 mN m-1 in the Cassie-Baxter state. Owing to the excellent robustness of the one-step molding downward overhanging, the max breakthrough pressure of this surface could reach up to 164.3 Pa for ethanol droplets. Furthermore, the flexible superomniphobic Dual-T surface allowed impinging ethanol droplets to completely rebound at the Weber number up to 7.1 with an impact velocity of ∼0.32 m s-1. The Dual-T microstructure surface maintained excellent superomniphobicity even after surface oxygen plasma treatment and exhibited excellent structural robustness and recoverability to various large mechanical deformations.