Acid-based lignocellulosic biomass biorefinery for bioenergy production: Advantages, application constraints, and perspectives.

The production of chemicals and fuels from renewable biomass with the primary aim of reducing carbon footprints has recently become one of the central points of interest. The use of lignocellulosic biomass for energy production is believed to meet the main criteria of maximizing the available global energy source and minimizing pollutant emissions. However, before usage in bioenergy production, lignocellulosic biomass needs to undergo several processes, among which biomass pretreatment plays an important role in the yield, productivity, and quality of the products. Acid-based pretreatment, one of the existing methods applied for lignocellulosic biomass pretreatment, has several advantages, such as short operating time and high efficiency. A thorough analysis of the characteristics of acid-based biomass pretreatment is presented in this review. The environmental concerns and future challenges involved in using acid pretreatment methods are discussed in detail to achieve clean and sustainable bioenergy production. The application of acid to biomass pretreatment is considered an effective process for biorefineries that aim to optimize the production of desired products while minimizing the by-products.

Microbial fuel cells for bioelectricity production from waste as sustainable prospect of future energy sector.

Microbial fuel cell (MFC) is lauded for its potentials to solve both energy crisis and environmental pollution. Technologically, it offers the capability to harness electricity from the chemical energy stored in the organic substrate with no intermediate steps, thereby minimizes the entropic loss due to the inter-conversion of energy. The sciences underneath such MFCs include the electron and proton generation from the metabolic decomposition of the substrate by microbes at the anode, followed by the shuttling of these charges to cathode for electricity generation. While its promising prospects were mutually evinced in the past investigations, the upscaling of MFC in sustaining global energy demands and waste treatments is yet to be put into practice. In this context, the current review summarizes the important knowledge and applications of MFCs, concurrently identifies the technological bottlenecks that restricted its vast implementation. In addition, economic analysis was also performed to provide multiangle perspectives to readers. Succinctly, MFCs are mainly hindered by the slow metabolic kinetics, sluggish transfer of charged particles, and low economic competitiveness when compared to conventional technologies. From these hindering factors, insightful strategies for improved practicality of MFCs were formulated, with potential future research direction being identified too. With proper planning, we are delighted to see the industrialization of MFCs in the near future, which would benefit the entire human race with cleaner energy and the environment.

Heavy metal removal by biomass-derived carbon nanotubes as a greener environmental remediation: A comprehensive review.

The concentrations of heavy metal ions found in waterways near industrial zones are often exceed the prescribed limits, posing a continued danger to the environment and public health. Therefore, greater attention has been devoted into finding the efficient solutions for adsorbing heavy metal ions. This review paper focuses on the synthesis of carbon nanotubes (CNTs) from biomass and their application in the removal of heavy metals from aqueous solutions. Techniques to produce CNTs, benefits of modification with various functional groups to enhance sorption uptake, effects of operating parameters, and adsorption mechanisms are reviewed. Adsorption occurs via physical adsorption, electrostatic interaction, surface complexation, and interaction between functional groups and heavy metal ions. Moreover, factors such as pH level, CNTs dosage, duration, temperature, ionic strength, and surface property of adsorbents have been identified as the common factors influencing the adsorption of heavy metals. The oxygenated functional groups initially present on the surface of the modified CNTs are responsible towards the adsorption enhancement of commonly-encountered heavy metals such as Pb2+, Cu2+, Cd2+, Co2+, Zn2+, Ni2+, Hg2+, and Cr6+. Despite the recent advances in the application of CNTs in environmental clean-up and pollution treatment have been demonstrated, major obstacles of CNTs such as high synthesis cost, the agglomeration in the post-treated solutions and the secondary pollution from chemicals in the surface modification, should be critically addressed in the future studies for successful large-scale applications of CNTs.

A state-of-the-art review on emission characteristics of SI and CI engines fueled with 2,5-dimethylfuran biofuel.

Currently, the considerable decline in fossil fuel resources and the high rise in vehicle emissions have prompted researchers and governments to formulate strategies for sustainable energy development. In addition to imposing strict laws, promoting sustainable energy sources such as the development of new types of non-fossil fuels has been considered a suitable direction for the roadmap to healing the Earth's environment. Biomass sources have affirmed huge potentials in the production of biofuels. In the pathway of searching renewable biofuels, it is found that that 2,5-dimethylfuran (DMF) can become a promising fuel because it is synthesized from lignocellulose biomass, which is an available feedstock for the production of prospective fuels. Indeed, recent review studies have focused in great detail on engine performance evaluation using DMF but seemed to have gaps in emission characteristics. In this work, the controversial issues of emissions from spark and compression ignition engines during the DMF combustion were completely assessed. Indeed, the mechanism of formation and oxidation of DMF compounds during combustion was clearly described to serve as the basis for analyzing and comparing the pollution emission behavior of different fuels. More importantly, gaseous emissions, PM characteristics, and soot tendency from spark and compression ignition engines were thoroughly evaluated on the basis of the experimental and numerical data. In general, DMF has shown outstanding advantages upon emissions compared to fossil fuels; however, the impacts of DMF on the engine durability and fuel system should be further investigated to have a comprehensive analysis of this biofuel class.

Efficient nickel or copper oxides decorated graphene-polyaniline interface for application in selective methanol sensing.

Graphene sheets decorated with nickel or copper oxides that were anchored on polyaniline (denoted as PANI-graphene/NiO and PANI-graphene/CuO) were prepared by a simple, easy to-control electrochemical method and applied as novel materials for sensitive and selective methanol sensing. The fabricated sensors exhibited good electrocatalytic activity, appropriate dynamic linear range (20-1300 mM), sensitivity (0.2-1.5 µA mM-1 cm-2) and excellent selectivity towards methanol. It should be highlighted from the selectivity tests that no significant interference was observed from ethanol and other alcohols. To our best knowledge, using inexpensive but efficient transition metals like Ni, Cu instead of Pt, Pd and their composites with PANI, graphene would be scientifically novel and practically feasible approach for sensor fabrication that could be potentially used to identify methanol adulteration in counterfeit alcoholic beverages.

SnO2/TiO2 nanotube heterojunction: The first investigation of NO degradation by visible light-driven photocatalysis.

Titania (TiO2) as a commercial photocatalyst has been continually struggling due to the limitation of ultraviolet light response and the high recombination rate of photoinduced carriers. The development of heterojunction nanostructures provides great promise to achieve the activation by visible light and suppress the photoinduced electron-hole pairs recombination. Herein, we synthesized a SnO2 and TiO2 nanotube heterojunction (SnO2/TNT) via a one-step hydrothermal strategy and systematically investigated NO photocatalytic degradation over the SnO2/TNTs heterojunction under visible light at the parts per billion level. Various physicochemical characterization techniques were conducted to verify the physical and chemical properties of the materials. For example, the morphology and lattice spacings of the materials were examined by high-resolution TEM (HR-TEM) images and selected area electron diffraction (SAED) pattern, X-ray photoelectron spectroscopy (XPS) was employed to study the oxidation states and propose the band alignment diagram of the SnO2/TNTs heterojunction, and photoluminescence spectroscopy was employed for understanding of carrier's trapping, migration and transfer. The photocatalytic results show that the SnO2/TNTs heterojunction exhibits the superior photocatalytic performance, and the photocatalytic degradation efficiency of NO can reach 60% under visible light with effective inhibition of NO2 production. The excellent photocatalytic ability is due to the low recombination rate of the photoinduced electron-hole pairs. Furthermore, a trapping experiment was combined with electron spin resonance (ESR) and utilized to identify the involvement of reactive radicals in the photocatalysis process suggesting that and OH mediated pathways play a predominant role in NO removal.

Photoreduction route for Cu2O/TiO2 nanotubes junction for enhanced photocatalytic activity.

Here, we synthesized copper(i) oxide and titanium dioxide nanotubes (TNTs) heterojunctions (HJs) by a photoreduction method using a low-power UV lamp without involving any additional steps, such as chemical reduction, surfactant, or protection agents. Transmission electron microscopy, X-ray diffraction, Raman scattering, X-ray photoelectron spectroscopy, diffuse reflectance spectra, and photoluminescence spectroscopy were carried out to verify the formation of a HJ between the Cu2O nanoparticles (Cu2O NPs) and TNTs. The efficiency and the rate of methylene blue photo-degradation over the Cu2O/TNTs HJ were found to be nearly double and triple compared to the isolated TNTs. The enhanced efficiency is attributed to the narrow band gap and defect states caused by the oxygen vacancies in the vicinity of HJs. Moreover, the type II band alignment of Cu2O NPs and TNTs naturally separates the photo-generated carriers and constrains the recombination process owing to the internal electric field across the Cu2O/TNTs interface.