RESUMO
In the title compound, C18H14N2O, the dihedral angle between the methyl-phenyl ring and the phthalazone ring system (r.m.s. deviation = 0.034 Å) is 53.93â (9)°. In the crystal, mol-ecules are connected by C-Hâ¯O hydrogen bonds, forming chains along [101]. The chains are linked by π-π inter-actions [centroid-centroid distance 3.6990â (12)â Å], forming layers parallel to (10-1).
RESUMO
In the title compound, C18H21N3O2, the dihedral angle between the benzene rings is 68.85â (11)°. In the crystal, the mol-ecules are linked by C-Hâ¯O and N-Hâ¯O hydrogen bonds, as well as weak C-Hâ¯π contacts, forming a three-dimensional supra-molecular architecture.
RESUMO
In the title compound, C30H40FNO3, the dihedral angle between the benzene rings is 57.76â (7)°. The alkyl chain adopts an all-trans conformation. In the crystal, mol-ecules are linked by pairs of C-Hâ¯O hydrogen bonds, forming inversion dimers.
RESUMO
In the title compound, C17H13ClN2O2, the phenyl and chloro-benzene rings are inclined to the central pyrazole ring at 40.84â (9) and 65.30â (9)°, respectively. In the crystal, pairs of C-Hâ¯π inter-actions link the mol-ecules into inversion dimers and C-Hâ¯O hydrogen bonds link these dimers into columns extended in [010]. The crystal packing exhibits short inter-molecular Oâ¯Cl contacts of 3.0913â (16)â Å.
RESUMO
In the title compound, C12H11Cl3N2O4, the dihedral angle between the aromatic ring and the hydrazine (NH-N=C) grouping is 52.2â (3)°. The butanedioate groups exhibit planar conformations. An intra-molecular N-Hâ¯O hydrogen bond links the N-H group of the hydrazine to one of the meth-oxy groups of the butane-dioate moiety. In the crystal, mol-ecules are linked by C-Hâ¯O hydrogen bonds and π-π inter-actions are also observed [centroid-centroid separation = 3.535â (1)â Å].
RESUMO
In the title compound, C15H12Cl2N2O, the atoms not making up the chloro-benzene ring are approximately coplanar (r.m.s. deviation = 0.073â Å). The dihedral angle between these 13 atoms and the chloro-benzene ring is 67.37â (10)°. The C=O and Csp (2)-Cl groups are almost eclipsed [Cl-C-C=O = -6.5â (3)°]. In the crystal, C(6) chains linked by C-Hâ¯O hydrogen bonds result in [100] chains.
RESUMO
The asymmetric unit of the title compound, C11H10N4O3, contains two independent mol-ecules in which the benzene rings make dihedral angles of 38.3â (2) and 87.1â (2)° with respect to the triazole rings. In the crystal, the mol-ecules are linked by C-Hâ¯O hydrogen bonds, forming chains along [021]. Further, weak C-Oâ¯π [3.865â (5)â Å, 83.8â (3)°] and N-Oâ¯π [3.275â (5) and 3.240â (6)â Å, 141.8â (4) and 102.8â (3)°] inter-actions are observed.
RESUMO
In the title compound, C15H12FN3O2, the dihedral angles between the central benzene ring and the pendant benzene and oxa-diazole rings are 45.05â (13) and 15.60â (14)°, respectively. The C atom of the meth-oxy group is roughly coplanar with its attached ring [displacement = 0.178â (4)â Å]. In the crystal, N-Hâ¯N hydrogen bonds link the mol-ecules into [010] chains. Weak C-Hâ¯π inter-actions are also observed.
RESUMO
In the title compound, C22H19N3O4, the dihedral angle between the furan and pyrazole rings is 82.73â (19)° while the dihedral angles between the furan and pyrazole rings and their attached benzene rings are 31.93â (18) and 1.88â (18)°, respectively. In the crystal, inversion dimers linked by pairs of C-Hâ¯O hydrogen bonds generate R 2 (2)(16) loops. In addition, weak C-Hâ¯π and aromatic π-π stacking [minimum centroid-centroid distance = 3.5374â (17)â Å] inter-actions are observed.
RESUMO
In the title compound, C7H8N6O2S, the dihedral angle between the imidazole and thia-diazole rings is 70.86â (15)°. In the crystal, mol-ecules are linked into [10-1] chains by N-Hâ¯N hydrogen bonds, which incorporate centrosymmetric R 2 (2)(8) and R 2 (2)(18) loops. The chains are linked by C-Hâ¯O and C-Hâ¯N inter-actions, generating a three-dimensional network. Very weak π-π stacking [centroid-centroid distance = 3.901â (17)â Å] is also observed.
RESUMO
The asymmetric unit of the title compound, C(19)H(19)ClO(4), contains two independent mol-ecules. The dihedral angles between the benzene rings are 63.41â (8) and 61.41â (9)°. Adjacent mol-ecules of different types are inter-connected in pairs through π-π inter-actions between their central benzene rings [centroid-centroid separation = 3.801â (2)â Å, inter-planar spacing = 3.605â (2)â Å, centroid shift = 1.204â (2)â Å]. Finally, C-Hâ¯O hydrogen bonds link these dimers into bilayers parallel to (100).
RESUMO
In the title compound, C(14)H(10)O(2), the tricycle is not planar, being bent with a dihedral angle of 4.7â (1)° between the two benzene rings. In the crystal, π-π inter-actions between the six-membered rings of neighbouring mol-ecules [centroid-centroid distances = 3.580â (3) and 3.605â (3)â Å] form stacks propagating along [101].