Silicon Nanoantenna Mix Arrays for a Trifecta of Quantum Emitter Enhancements.

Dielectric nanostructures have demonstrated optical antenna effects due to Mie resonances. Previous work has exhibited enhancements in absorption, emission rates and directionality with practical limitations. In this paper, we present a Si mix antenna array to achieve a trifecta enhancement of ∼1200-fold with a Purcell factor of ∼47. The antenna design incorporates ∼10 nm gaps, within which fluorescent molecules strongly absorb the pump laser energy through a resonant mode. In the emission process, the antenna array increases the radiative decay rates of the fluorescence molecules via a Purcell effect and provides directional emission through a separate mode. This work could lead to novel CMOS-compatible platforms to enhance fluorescence for biological and chemical applications.

Full Color and Grayscale Painting with 3D Printed Low-Index Nanopillars.

Sculpting nanostructures into different geometries in either one or two dimensions produces a wide range of colorful elements in microscopic prints. However, achieving different shades of gray and control of color saturation remain challenging. Here, we report a complete approach to color and grayscale generation based on the tuning of a single nanostructure geometry. Through two-photon polymerization lithography, we systematically investigated color generation from the basic single nanopillar geometry in low-refractive-index (n < 1.6) material. Grayscale and full color palettes were achieved that allow decomposition onto hue, saturation, and brightness values. This approach enabled the "painting" of arbitrary colorful and grayscale images by mapping desired prints to precisely controllable parameters during 3D printing. We further extend our understanding of the scattering properties of the low-refractive-index nanopillar to demonstrate grayscale inversion and color desaturation and steganography at the level of single nanopillars.

Noninterleaved Metasurface for (26-1) Spin- and Wavelength-Encoded Holograms.

Nanostructured metasurfaces demonstrate extraordinary capabilities to control light at the subwavelength scale, emerging as key optical components to physical realization of multitasked devices. Progress in multitasked metasurfaces has been witnessed in making a single metasurface multitasked by mainly resorting to extra spatial freedom, for example, interleaved subarrays, different angles. However, it imposes a challenge of suppressing the cross-talk among multiwavelength without the help of extra spatial freedom. Here, we introduce an entirely novel strategy of multitasked metasurfaces with noninterleaved single-size Si nanobrick arrays and minimalist spatial freedom demonstrating massive information on 6-bit encoded color holograms. The interference between electric dipole and magnetic dipole in individual Si nanobricks with in-plane orientation enables manipulating six bases of incident photons simultaneously to reconstructed 6-bit wavelength- and spin-dependent multicolor images. Those massively reconstructed images can be distinguished by pattern recognition. It opens an alternative route for integrated optics, data encoding, security encryption, and information engineering.

On the correlation of absorption cross-section with plasmonic color generation.

Through numerical simulations, we investigate the correlation between the absorption cross-section and the color saturation of plasmonic nanostructures of varying density. Understanding this correlation, enables the prediction of an optimal nanostructure separation, or combinations of different nanostructure sizes for plasmonic color printing applications. Here, we use metal-insulator-metal (MIM) aluminum nanostructures that support gap-plasmons. Large absorption cross-sections were observed that exceed twelve times the physical cross-section of the nanostructure disks. We derive a set of equations to determine the optimal separation for a periodic array using the absorption cross-section of an individual structure to realize saturated colors. Using the optimum pitch and enabled by the large absorption cross-sections of our structures, we employ color mixing strategies to realize a wider color gamut. The simulated color gamut exceeds the sRGB gamut for some colors, and includes dark tones. Color mixing using structures with large absorption cross-sections is a practical approach to generate a broad range of colors, in comparison to fabricating structures with continuously varying sizes.

A universal metasurface transfer technique for heterogeneous integration.

Metasurfaces offer a versatile platform for engineering the wavefront of light using nanostructures with subwavelength dimensions and hold great promise for dramatically miniaturizing conventional optical elements due to their small footprint and broad functionality. However, metasurfaces so far have been mainly demonstrated on bulky and planar substrates that are often orders of magnitude thicker than the metasurface itself. Conventional substrates not only nullify the reduced footprint advantage of metasurfaces, but also limit their application scenarios. The bulk substrate also determines the metasurface dielectric environment, with potentially undesired optical effects that undermine the optical performance. Here we develop a universal polymer-assisted transfer technique to tackle this challenge by decoupling the substrate employed on the fabrication of metasurfaces from that used for the target application. As an example, Huygens' metasurfaces with 120 nm thickness in the visible range (532 nm) are demonstrated to be transferred onto a 100 nm thick freestanding SiNx membrane while maintaining excellent structural integrity and optical performance of diffraction-limited focusing. This transfer method not only enables the thinnest dielectric metalens to the best of our knowledge, but also opens up new opportunities in integrating cascaded and multilayer metasurfaces, as well as the heterogeneous integration with nonconventional substrates and various electronic/photonic devices.

Coloured vortex beams with incoherent white light illumination.

The orbital angular momentum is a fundamental degree of freedom of light wavefronts, currently exploited in applications where information capacity is a key requirement, such as optical communication, super-resolution imaging and high-dimensional quantum computing. However, generating orbital angular momentum beams requires spatio-temporally coherent light sources (lasers or supercontinuum sources), because incoherent light would smear out the doughnut features of orbital angular momentum beams, forming polychromatic or obscured orbital angular momentum beams instead. Here we show generation of coloured orbital angular momentum beams using incoherent white light. Spatio-temporal coherence is achieved by miniaturizing spiral phase plates and integrating them with structural colour filters, three-dimensionally printed at the nanoscale. Our scheme can in principle generate multiple helical eigenstates and combine colour information into orbital angular momentum beams independently. These three-dimensional optical elements encoded with colour and orbital angular momentum information substantially increase the number of combinations for optical anti-counterfeiting and photonic lock-key devices in a pairwise fashion.

Schrödinger's red pixel by quasi-bound-states-in-the-continuum.

While structural colors are ubiquitous in nature, saturated reds are mysteriously absent. This long-standing problem of achieving Schrödinger's red demands sharp transitions from "stopband" to a high-reflectance "passband" with total suppression of higher-order resonances at blue/green wavelengths. Current approaches based on nanoantennas are insufficient to satisfy all conditions simultaneously. Here, we designed Si nanoantennas to support two partially overlapping quasi-bound-states-in-the-continuum modes with a gradient descent algorithm to achieve sharp spectral edges at red wavelengths. Meanwhile, high-order modes at blue/green wavelengths are suppressed via engineering the substrate-induced diffraction channels and the absorption of amorphous Si. This design produces possibly the most saturated and brightest reds with ~80% reflectance, exceeding the red vertex in sRGB and even the cadmium red pigment. Its nature of being sensitive to polarization and illumination angle could be potentially used for information encryption, and this proposed paradigm could be generalized to other Schrödinger's color pixels.

Nanocavity-induced trion emission from atomically thin WSe2.

Exciton is a bosonic quasiparticle consisting of a pair of electron and hole, with promising potentials for optoelectronic device applications, such as exciton transistors, photodetectors and light emitting devices. However, the charge-neutral nature of excitons renders them challenging to manipulate using electronics. Here we present the generation of trions, a form of charged excitons, together with enhanced exciton resonance in monolayer WSe2. The excitation of the trion quasiparticles is achieved by the hot carrier transport from the integrated gold plasmonic nanocavity, formed by embedding monolayer WSe2 between gold nanoparticles and a gold film. The nanocavity-induced negatively charged trions provide a promising route for the manipulation of excitons, essential for the construction of all-exciton information processing circuits.

Reversible Tuning of Mie Resonances in the Visible Spectrum.

Dielectric optical nanoantennas are promising as fundamental building blocks in next generation color displays, metasurface holograms, and wavefront shaping optical devices. Due to the high refractive index of the nanoantenna material, they support geometry-dependent Mie resonances in the visible spectrum. Although phase change materials, such as the germanium-antimony-tellurium alloys, and post-transition metal oxides, such as ITO, have been used to tune antennas in the near-infrared spectrum, reversibly tuning the response of dielectric antennas in the visible spectrum remains challenging. In this paper, we designed and experimentally demonstrated dielectric nanodisc arrays exhibiting reversible tunability of Mie resonances in the visible spectrum. We achieved tunability by exploiting phase transitions in Sb2S3 nanodiscs. Mie resonances within the nanodisc give rise to structural colors in the reflection mode. Crystallization and laser-induced amorphization of these Sb2S3 resonators allow the colors to be switched back and forth. These tunable Sb2S3 nanoantenna arrays could enable the next generation of high-resolution color displays, holographic displays, and miniature LiDAR systems.

Wide-Gamut Plasmonic Color Palettes with Constant Subwavelength Resolution.

Unlike dye-based colorants, for which dilution results in a decrease in color saturation, a reduction of nanostructure density in plasmonic prints could increase color saturation instead. This interesting observation can be explained by the absorption cross-section of the nanostructure being larger than its physical cross-section. In this paper, we demonstrate the correlation between absorption cross-section and nanostructure density and use it to realize saturated colors by fabricating metal-insulator-metal aluminum nanostructures that support gap-surface plasmons (GSPs). We obtained structures with absorption cross-sections that exceed 10 times their physical cross-sections. The large absorption cross-sections of the GSP structures herald a color-mixing scheme where nanostructures of different hues are combined within subpixels at a constant pitch. The pitch is chosen such that the total absorption cross-section of individual constituents of the cell occupies the unit size area. Using a constant pitch of 320 nm, hence preserving the print resolution, our structures exhibit 45% coverage of the sRGB color space. By employing absorption cross-sections of the nanostructures, we produced black and saturated green pixels, which have been challenging to achieve in plasmonic color printing. The effects of square and hexagonal arrangements on color saturation are investigated, and point mixing effects are observed between individual nanostructures.