Experimental characterization of a novel soft polymer heat exchanger for wastewater heat recovery.

Wastewater released from showers, sinks, and washers contains a considerable amount of waste heat that can be recovered by using a heat exchanger. Conventional metal heat exchangers for wastewater heat recovery have common problems of corrosion, fouling and clogging, which makes it necessary to develop a new type of heat exchanger for such low-grade thermal energy recovery applications. This study deals with a novel patented polymer heat exchanger (WO2020049233A1) made of soft polyurethane tubes that are capable of oscillation once subjected to external forces. Laboratory tests coupled with theoretical analyses show a stable global heat transfer coefficient of 100-110 W/m2·K, achieving 67-92% of the performance of titanium-, aluminum-, and copper-made heat exchangers with the same configuration. It further reveals that the performance of the soft heat exchanger can be enhanced by 30% when it is under oscillation. In addition, the external convective thermal resistance appears to be the dominant one instead of heat conduction through the wall material. The special operating condition of heat recovery from a sewer pipeline makes the polymer heat exchanger particularly adapted with its equivalent thermal performance but advantages of high flexibility, modularity, and low cost.

Grooves Accelerate Dew Shedding.

Gravity-driven drainage of small volumes of condensates, such as natural dew, is a challenge because small drops usually remain pinned to inclined surfaces. We report that submillimetric grooves substantially reduce dew retention by modifying the repartition of liquid: Because of a long-range coalescence mechanism mediated by grooves imbibition, the growth and shedding of large drops are accelerated. Such findings can be applied to increase the passive harvesting of dew as well as to accelerate the drainage of other condensates.

Roughness-enhanced collection of condensed droplets.

Gravity shedding of droplets is limited by droplet pinning, a major limitation for low condensation processes and in particular passive dew harvesting in its use as an alternative source of water. We present experiments showing that, paradoxically, a simple surface treatment increasing roughness (sand-blasting) favors droplet shedding compared to the original substrate, provided that sand-blasting does not increase too much the surface roughness. Sand-blasting ensures the high density of nucleation sites and enhances drops coalescence and growth at a sub-micron scale, thus lowering the lag-time to obtain drop sliding during condensation. Early nucleation indeed overcompensates the delay increase due to roughness. Edges of the substrate, where drops grow faster, also improve water collection, thanks to the early sliding of edge drops that behave as natural wipers. Combining the effects of sand-blasting and edges increases significantly the rate of collection of dew condensation on a substrate at a given time, gains of about 30% can be commonly obtained.

A liquid contact line receding on a soft gel surface: dip-coating geometry investigation.

We studied the dynamics of a liquid contact line receding on a hydrophobic soft gel (SBS-paraffin). In order to realize a well-defined geometry with an accurate control of velocity, a dip-coating setup was implemented. Provided that the elastic modulus is small enough, a significant deformation takes place near the contact line, which in turn drastically influences the wetting behaviour. Depending on the translation velocity of the substrate, the contact line exhibits different regimes of motions. Continuous motions are observed at high and low velocities, meanwhile two types of stick-slip motion - periodic and erratic - appear at intermediate velocities. We suggest that the observed transitions could be explained in terms of the competition between different frequencies, i.e., the frequency of the strain field variation induced by the contact line motion and the crossover frequency of the gel related to the material relaxation. Our results provide systematic views on how the wetting of liquid is modified by the rheological properties of a complex soft substrate.

Vibration-induced streaming flow near a sharp edge: Flow structure and instabilities in a large span of forcing amplitude.

The steady streaming generated near solid walls by the periodic forcing of a viscous fluid is known to be strongly enhanced near sharp structures, owing to centrifugal effects that lead to the generation of an intense jet from the sharp tip. This flow has been shown to provide efficient active mixing in microchannels, due to strong transverse velocity. The forcing is often prescribed by acoustic transducers, but it can also be generated from low-frequency time-periodic flow ensured by mechanical vibrations. In this paper, we study the flow structure generated by low-frequency forcing (typically 10 Hz) around a sharp tip. Using direct numerical simulations, we extract both the time-periodic and steady responses within a large span of amplitude of vibrations. When the amplitude is smaller than the tip radius of curvature, we recover the flow structure observed at higher frequencies (>1 kHz) in previous studies, namely, an intense symmetric central jet and a quadratic dependence for the characteristic streaming velocity with the oscillating velocity v_{s}∼v_{a}^{2}. At higher amplitudes, such a scaling no longer holds and the streaming flow pattern loses its left-right symmetry. We then analyze the mechanisms of the instability from the careful examination of the instationary flow fields, and we propose possible mechanisms for such a flow transition involving the coupling between the streaming jet and instationary vorticity.

Tailoring silicon for dew water harvesting panels.

Dew water, mostly ignored until now, can provide clean freshwater resources, just by extracting the atmospheric vapor available in surrounding air. Inspired by silicon-based solar panels, the vapor can be harvested by a concept of water condensing panels. Efficient water harvesting requires not only a considerable yield but also a timely water removal from the surface since the very beginning of condensation to avoid the huge evaporation losses. This translates into strict surface properties, which are difficult to simultaneously realize. Herein, we study various functionalized silicon surfaces, including the so-called Black Silicon, which supports two droplet motion modes-out-of-plane jumping and in-plane sweeping, due to its unique surface morphology, synergistically leading to a pioneering combination of above two required characteristics. According to silicon material's scalability, the proposed silicon-based water panels would benefit from existing infrastructures toward dual functions of energy harvesting in daytime and water harvesting in nighttime.

Structure and thermorheology of concentrated pluronic copolymer micelles in the presence of laponite particles.

Small-angle neutron scattering and thermorheology techniques are used to investigate in detail the effect of laponite particles in aqueous solutions of poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide), PEO-PPO-PEO, block copolymers in the concentrated regime. At high polymer concentration or temperature, the micellar solutions exhibit a phase transition from fluid to crystal due to crowding of the micelles. The addition of laponite is found to disturb this phase transition. The adsorption of the copolymer unimers onto laponite in large amounts describes these findings. It is shown that the preferred adsorption of the copolymer chains results in a sufficient increase in free volume for the remaining micelles to yield the observed enhancement of the structural disorder.

Unveiling of the mechanisms of acoustic streaming induced by sharp edges.

Acoustic waves can generate steady streaming within a fluid owing to the generation of viscous boundary layers near walls of typical thickness δ. In microchannels, the acoustic wavelength λ is adjusted to twice the channel width w to ensure a resonance condition, which implies the use of MHz transducers. Recently, though, intense acoustic streaming was generated by acoustic waves of a few kHz (hence with λ≫w), owing to the presence of sharp-tipped structures of curvature radius at the tip r_{c} smaller than δ. The present study quantitatively investigates this sharp-edge acoustic streaming via the direct resolution of the full Navier-Stokes equation using the finite element method. The influence of δ,r_{c}, and viscosity ν on the acoustic streaming performance is quantified. Our results suggest choices of operating conditions and geometrical parameters, in particular the dimensionless tip radius of curvature r_{c}/δ and the liquid viscosity.

Acoustic Streaming Generated by Sharp Edges: The Coupled Influences of Liquid Viscosity and Acoustic Frequency.

Acoustic streaming can be generated around sharp structures, even when the acoustic wavelength is much larger than the vessel size. This sharp-edge streaming can be relatively intense, owing to the strongly focused inertial effect experienced by the acoustic flow near the tip. We conducted experiments with particle image velocimetry to quantify this streaming flow through the influence of liquid viscosity ν , from 1 mm 2 /s to 30 mm 2 /s, and acoustic frequency f from 500 Hz to 3500 Hz. Both quantities supposedly influence the thickness of the viscous boundary layer δ = ν π f 1 / 2 . For all situations, the streaming flow appears as a main central jet from the tip, generating two lateral vortices beside the tip and outside the boundary layer. As a characteristic streaming velocity, the maximal velocity is located at a distance of δ from the tip, and it increases as the square of the acoustic velocity. We then provide empirical scaling laws to quantify the influence of ν and f on the streaming velocity. Globally, the streaming velocity is dramatically weakened by a higher viscosity, whereas the flow pattern and the disturbance distance remain similar regardless of viscosity. Besides viscosity, the frequency also strongly influences the maximal streaming velocity.

Experimental study of the POP technique: focus on the physical basis of the process.

INTRODUCTION: Central or peripheral vascular access devices have been in use for many decades. However, despite adequate care and maintenance, complete occlusion may occur, and its impact cannot be overlooked. A new procedure using a percussion technique has been published and referred as 'the POP technique'. METHODS: A hydrodynamic bench was used permitting both the recording of the movement of the piston with a fast camera and the pressure variations in the polyurethane and silicone catheters while connected to 2- and 3-piece syringes. RESULTS: The results are twofold. First the upward movement of the piston leads to the installation of a saturation vapour pressure in the body of the syringe. During this sequence, the clot is submitted to a force of aspiration. Then the release of the plunger leads to a pulse pressure whose dynamics and intensity are dependent of the types of syringes and catheters. CONCLUSIONS: The experiments bring to light the importance of practical features such as the orientation of the syringe and the nature of the polyurethane or silicone catheters. Then the analysis enables the definition of practical rules for safe practice of the POP technique. This study will impact clinicians as many may be tempted to use the technique in hope to resolve the occlusion safely, in a timely manner.

Diazonium salt chemistry for the design of nano-textured anti-icing surfaces.

Aryl diazonium salts have emerged as a new generation of robust surface modifiers for a wide range of applications. However, their use for creating anti-icing surfaces has never been investigated so far. We fill this gap by modifying nano-textured copper surfaces with aryl diazonium salts, bearing low surface energy end groups, leading to efficient anti-icing properties.

Mechanical characteristics of plastic base Ports and impact on flushing efficacy.

BACKGROUND: Three types of totally implantable venous access devices, Ports, are currently in use: titanium, plastic (polyoxymethylene, POM), and mixed (titanium base with a POM shell). Physics theory suggests that the interaction between a non-coring needle (NCN, made of stainless steel) and a plastic base would lead to the stronger material (steel) altering the more malleable material (plastic). OBJECTIVES: To investigate whether needle impacts can alter a plastic base's surface, thus potentially reducing flushing efficacy. STUDY DESIGN AND METHODS: A Port made of POM was punctured 200 times with a 19-gauge NCN. Following the existing guidelines, the needle tip pricked the base with each puncture. The Port's base was then examined using a two-dimensional optical instrument, and a bi-dimensional numerical simulation using COMSOL® was performed to investigate potential surface irregularities and their impact on fluid flow. RESULTS: Each needle impact created a hole (mean depth, 0.12 mm) with a small bump beside it (mean height, 0.02 mm) the Reynolds number Rek≈10. A numerical simulation of the one hole/bump set showed that the flushing efficacy was 60% that of flushing along a flat surface. DISCUSSION: In clinical practice, the number of times a Port is punctured depends on patient and treatment characteristics, but each needle impact on the plastic base may increase the risk of decreased flushing effectiveness. Therefore, the more a plastic Port is accessed, the greater the risk of microorganisms, blood products, and medication accumulation. CONCLUSIONS: Multiple needle impacts created an irregular surface on the Port's base, which decreased flushing efficacy. Clinical investigation is needed to determine whether plastic base Ports are associated with an increased risk of Port infection and occlusion compared to titanium base Ports.

Edge effects on water droplet condensation.

In this study we investigate the effect of geometrical or thermal discontinuities on the growth of water droplets condensing on a cooled substrate. Edges, corners, and cooled and noncooled boundaries can have a strong effect on the vapor concentration profile and mass diffusion around the drops. In comparison to growth in a pattern where droplets have to compete to catch vapor, which results in a linear water concentration profile directed perpendicularly to the substrate, droplets near discontinuities can get more vapor (outer edges, corners), resulting in faster growth or less vapor (inner edges), giving lower growth. When the cooling heat flux limits growth instead of mass diffusion (substrate with low thermal conductivity, strong heat exchange with air), edge effects can be canceled. In certain cases, growth enhancement can reach nearly 500% on edges or corners.

Power port contrast medium flushing and trapping: impact of temperature, an in vitro experimental study.

PURPOSE: The use of totally implantable venous access devices (TIVADs) certified as "high pressure resistant" or "power port" has begun to spread worldwide as a safe procedure for power contrast injection. Owing to the thermo-rheological properties of the contrast media, the primary aim of this work is to present an in vitro experimental impact study concerning the impact of the temperature level on flushing efficiency after contrast medium injection. Moreover, we report experimental data that confirms the role of needle bevel orientation. The secondary aim is to answer the following questions: Is there significant device contrast medium trapping after contrast medium injection? Is saline flushing efficient? And, finally, is it safe to inject contrast medium through an indwelled port catheter? RESULTS: The experimental results show that in addition to hydrodynamics, temperature is a key parameter for the efficiency of device flushing after contrast medium injection. It appears that this is the case when the cavity is incompletely rinsed after three calibrated flushing volumes of 10 mL saline solution, even by using the Huber needle bevel opposite to the port exit. This leads to a potentially important trapped volume of contrast medium in the port, and consequently to the possibility of subsequent salt precipitates and long term trisubstituted benzene nuclei delivery that might impair the solute properties, which may be further injected via the power port later on. CONCLUSION: We thus suggest, in TIVADS patients, the use of a temporary supplementary intravenous line rather than the port to perform contrast medium injections in daily radiology routine practice.

Thermal and hydrodynamic modelling of active catheters for interventional radiology.

Interventional radiologists desire to improve their operating tools such as catheters. Active catheters in which the tip is moved using shape memory alloy actuators activated using the Joule effect present a promising approach for easier navigation in the small vessels. However, the increase in temperature caused by this Joule effect must be controlled in order to prevent damage to blood cells and tissues. This paper is devoted to the simulation and experimental validation of a fluid-thermal model of an active catheter prototype. Comparisons between computer-predicted and experimentally measured temperatures are presented for both experiments in air and water at 37°C. Good agreement between the computational and experimental results is found, demonstrating the validity of the developed computer model. These comparisons enable us to highlight some important issues in the modelling process and to determine the optimal current for the activation of the catheter.