Marangoni Flow in Freely Suspended Liquid Films.

We demonstrate controlled material transport driven by temperature differences in thin freely suspended smectic films. Films with submicrometer thicknesses and lateral extensions of several millimeters were studied in microgravity during suborbital rocket flights. In-plane temperature differences cause two specific Marangoni effects, directed flow and convection patterns. At low gradients, practically thresholdless, flow transports material with a normal (negative) temperature coefficient of the surface tension dσ/dT<0 from the hot to the cold film edge, it accumulates at the cold film edge. In materials with dσ/dT>0, the reverse transport from the cold to the hot edge is observed. We present a model that describes the effect quantitatively. It predicts that not the temperature gradient in the film plane but the temperature difference between the thermopads is relevant for the effect.

Outflow and clogging of shape-anisotropic grains in hoppers with small apertures.

Outflow of granular material through a small orifice is a fundamental process in many industrial fields, for example in silo discharge, and in everyday's life. Most experimental studies of the dynamics have been performed so far with monodisperse disks in two-dimensional (2D) hoppers or spherical grains in 3D. We investigate this process for shape-anisotropic grains in 3D hoppers and discuss the role of size and shape parameters on avalanche statistics, clogging states, and mean flow velocities. It is shown that an increasing aspect ratio of the grains leads to lower flow rates and higher clogging probabilities compared to spherical grains. On the other hand, the number of grains forming the clog is larger for elongated grains of comparable volumes, and the long axis of these blocking grains is preferentially aligned towards the center of the orifice. We find a qualitative transition in the hopper discharge behavior for aspect ratios larger than ≈6. At still higher aspect ratios >8-12, the outflowing material leaves long vertical holes in the hopper that penetrate the complete granular bed. This changes the discharge characteristics qualitatively.

Defect Interactions in Anisotropic Two-Dimensional Fluids.

Disclinations in liquid crystals bear striking analogies to defect structures in a wide variety of physical systems, and their straightforward optical observability makes them excellent models to study fundamental properties of defect interactions. We employ freely suspended smectic-C films, which behave as quasi-two-dimensional polar nematics. A procedure to capture high-strength disclinations in localized spots is introduced. These disclinations are released in a controlled way, and the motion of the mutually repelling topological charges with strength +1 is studied quantitatively. We demonstrate that the classical models, which employ elastic one-constant approximation, fail to describe their dynamics correctly. In realistic liquid crystals, even small differences between splay and bend constants lead to the selection of pure splay or pure bend +1 defects. For those, the models work only in very special configurations. In general, additional director walls are involved which reinforce the repulsive interactions substantially.

Rupture and recoil of bent-core liquid crystal filaments.

The recoil process of free-standing liquid crystal filaments is investigated experimentally and theoretically. We focus on two aspects, the contraction speed of the filament and a spontaneously formed undulation instability. At the moment of rupture, the filaments buckle similarly to the classical Euler buckling of elastic rods. The tip velocity decays with decreasing filament length. The wavelength of buckling affinely decreases with the retracting filament tip. The energy gain related to the decrease of the total length and surface area of the filaments is mainly dissipated by layer rearrangements during thickening of the fibre. A flow back into the meniscus is relevant only in the final stage of the recoil process. We introduce a model for the quantitative description of the filament retraction speed. The dynamics of this recoil behaviour may find relevance as a model for biology-related filaments.

Light-induced Soret effect and adsorption of nanocrystals in organic solvents.

A light-induced Soret effect accompanied by photoinduced adsorption of pigment nanoparticles is described in organic solvents. We report an unexpected inversion of the nanoparticle flux which is directed along the temperarture gradient at short exposures to the light and switches against the gradient at longer exposures. This change of flux direction is due to light-induced adsorption of the nanocrystals onto the substrates of the cell.

Mesophase structure and behaviour in bulk and restricted geometry of a dimeric compound exhibiting a nematic-nematic transition.

We present structural studies of a dimeric compound composed of a central heptyl spacer linking two mesogens consisting of terphenyl units at which two adjacent fluoro groups are attached to each central ring. The terminal rings are linked to pentyl chains as terminal groups. The material exhibits a nematic-nematic transition and a low temperature modulated phase. The higher temperature nematic phase was found to exhibit an anomaly of the bend elastic constant similar to that of the dimers with N-Ntb phase sequence, and the physical properties of the low-temperature nematic phase are similar to those of the known Ntb materials. The structure of the low-temperature modulated smectic/columnar phase is described together with its ability to form freely suspended films and fibres. The relation of the modulated structure to the fibre formation and to the appearance of the labyrinthine instability in freely-suspended films is discussed.

Granular gases of rod-shaped grains in microgravity.

Granular gases are convenient model systems to investigate the statistical physics of nonequilibrium systems. In the literature, one finds numerous theoretical predictions, but only few experiments. We study a weakly excited dilute gas of rods, confined in a cuboid container in microgravity during a suborbital rocket flight. With respect to a gas of spherical grains at comparable filling fraction, the mean free path is considerably reduced. This guarantees a dominance of grain-grain collisions over grain-wall collisions. No clustering was observed, unlike in similar experiments with spherical grains. Rod positions and orientations were determined and tracked. Translational and rotational velocity distributions are non-Gaussian. Equipartition of kinetic energy between translations and rotations is violated.

Two-dimensional microrheology of freely suspended liquid crystal films.

Smectic liquid crystals form freely-suspended, fluid films of highly uniform structure and thickness, making them ideal systems for studies of hydrodynamics in two dimensions. We have measured particle mobility and shear viscosity by direct observation of the gravitational drift of silica spheres and smectic islands included in these fluid membranes. In thick films, we observe a hydrodynamic regime dominated by lateral confinement effects, with the mobility of the inclusion determined predominantly by coupling of the fluid flow to the fixed boundaries of the film. In thin films, the mobility of inclusions is governed primarily by coupling of the fluid to the surrounding air, as predicted by Saffman-Delbrück theory.

Transient hexagonal structures in sheared emulsions of isotropic inclusions on smectic bubbles in microgravity conditions.

We describe the collective behavior of isotropic droplets dispersed over a spherical smectic bubble, observed under microgravity conditions on the International Space Station (ISS). We find that droplets can form two-dimensional hexagonal structures changing with time. Our analysis indicates the possibility of spatial and temporal periodicity of such structures of droplets. Quantitative analysis of the hexagonal structure including the first three coordination circles was performed. A peculiar periodic-in-time ordering of the droplets, related to one-dimensional motion of droplets with non-uniform velocity, was found.

Corona patterns around inclusions in freely suspended smectic films.

We discuss the structure and physical origin of corona patterns observed around solid or liquid spherical inclusions in freely suspended smectic films. Such patterns are observed when droplets or solid beads of micrometer size are sprayed onto the films. They are found in the smectic C phase and in the smectic A phase above such a smectic C phase, but disappear, for example, at the transition into a lower-temperature smectic B phase. We show that these structures are equivalent to splay domains found in the meniscus of freely suspended films, originating from surface-induced spontaneous splay.

An instrument for studying granular media in low-gravity environment.

A new experimental facility has been designed and constructed to study driven granular media in a low-gravity environment. This versatile instrument, fully automatized, with a modular design based on several interchangeable experimental cells, allows us to investigate research topics ranging from dilute to dense regimes of granular media such as granular gas, segregation, convection, sound propagation, jamming, and rheology-all without the disturbance by gravitational stresses active on Earth. Here, we present the main parameters, protocols, and performance characteristics of the instrument. The current scientific objectives are then briefly described and, as a proof of concept, some first selected results obtained in low gravity during parabolic flight campaigns are presented.

Field-induced texture transitions in a bent-core nematic liquid crystal.

It is demonstrated in electro-optic experiments that an external electric field of the order of 10;{5} V/m induces persisting texture transitions in a nematic phase formed by bent-core mesogens. The field-induced metastable state is identified by its optical and electric properties. After the field is switched off, the original and induced states can coexist in domains for about one hour in planar sandwich cells. During this time, the induced domains gradually shrink but they can be stabilized in moderate electric fields. The occurrence of similar domains in homeotropic cells suggests that the transition into a metastable biaxial state is observed. In the field-free planar ground state, the formation of inversion walls is observed inside the metastable domains.

Buckling instability of droplet chains in freely suspended smectic films.

A buckling instability of chains of isotropic droplets in smectic films is investigated. The c -director field in a free-standing film is prepared as a target pattern with a continuous radial deformation. In such a pattern, isotropic liquid droplets are induced by light irradiation of the photochromic mesogenic material. The droplets align tangentially in regular chains in the regular structure of the c -director field. Incorporation of additional droplets lengthens the chains at a given ring diameter until they form complete rings. Further chain growth introduces a reversible buckling with a characteristic wave length. The phenomenon is similar in many respects to growth processes in biosystems or Euler buckling in polymer foils. A simple model of the wavelength selection mechanism is introduced.

Frustrated packing of spheres in a flat container under symmetry-breaking bias.

We study statistical properties of packings of monodisperse spheres in a flat box. After "gravitational" filling and appropriate agitation, a nearly regular (in plane) but frustrated (normal to the plane) triangular lattice forms, where beads at individual sites touch either the front or back wall. It has striking analogies to order in antiferromagnetic Ising spin models. When tilting the container, Earth's gravitational field mimics external forces similar to magnetic fields in the spin systems. While packings in vertical containers adopt a frustrated state with statistical correlations between neighboring sites, the configurations continuously approach the predictions of a random Ising model when the cell tilt is increased. Our experiments offer insights into both the influence of geometrical constraints on random granular packing and a descriptive example of frustrated ordering.

Self-organization of isotropic droplets in smectic- C free-standing films.

Free standing smectic films have been investigated at the transition from the smectic- C phase to the isotropic phase. In the vicinity of the bulk transition temperatures, isotropic droplets of micrometer size appear in the film. Such systems represent convenient models for anisotropic, two-dimensional emulsions. A characteristic feature of the droplets is their mutual interaction by elastic distortions of the local orientation of the film, the c director, which are related to the anchoring conditions of the c director at the droplet border. We describe in detail the director deformations created by isotropic droplets of different sizes, and their role in the spontaneous organization of regular droplet patterns. Depending upon droplet size and anchoring strength, topological defects can be induced in the c -director field. Qualitative differences to literature data on cholesteric droplets in smectic- C* films are discussed.

Structure and elastic properties of smectic liquid crystalline elastomer films.

Mechanical measurements, x-ray investigations, and optical microscopy are employed to characterize the interplay of chemical composition, network topology, and elastic response of smectic liquid crystalline elastomers (LCEs) in various mesophases. Macroscopically ordered elastomer films of submicrometer thicknesses were prepared by cross linking freely suspended smectic polymer films. The cross-linked material preserves the mesomorphism and phase transitions of the precursor polymer. The elastic response of the smectic LCE is entropic, and the corresponding elastic moduli are of the order of MPa. In the tilted ferroelectric smectic-C* phase, the network structure plays an important role. Due to the coupling of elastic network deformations to the orientation of the mesogenic groups in interlayer cross-linked materials (mesogenic cross-linker units), the stress-strain characteristics is found to differ qualitatively from that in the other phases.

Tension of freely suspended fluid filaments.

Stable fluid filaments with diameters of several micrometers and slenderness ratios well above 1000 are unique objects formed by some liquid crystalline phases of bent-core mesogens. We present a technique to determine filament tensions from their deflection under defined loads. A strong temperature dependence is observed, with a minimum near the clearing temperature. Both the nonlinear relation between filament tension and diameter and the substantial increase of the tension with lower temperatures indicate contributions of volume terms, in addition to surface capillary forces. We discuss a model that relates these bulk terms to elastic forces, originating from the undulated smectic layer structure. This model can explain the origin of the filament stability.

Multistage polar switching in bent-core mesogens.

We report a novel type of electro-optical switching in a tilted smectic phase of bent-shaped mesogens. The switching consists of a continuous stage and two bistable transitions. Detailed optical and electro-optical measurements using high-speed imaging are given and possible interpretations of the experimental results are discussed.