Anomalous Temperature Effect in Weakly Coupled Superlattices: Carrier Transport in a THz Quantum Cascade Laser.

We present an investigation into the vertical transport through 13 different superlattice structures, where the well and barrier widths, doping concentration, dopant position, and contact layers were varied. Although superlattices have been extensively studied since 1970, there is a lack of publications on transport through superlattices similarly low doped as THz quantum cascade lasers (QCLs), for which the doping is in the 3-5×10^{10} cm^{-2} range. The superlattices presented are doped in the same range as THz QCLs, with contact layers and fabrication comparable to high-temperature THz QCLs. The temperature-dependent current-voltage characteristics were measured starting from 5 K and an anomalous temperature effect was observed at the first plateau. The measured current through the superlattice first decreases before increasing again with increasing temperature, resulting in the lowest current occurring at 75-110 K. This behavior is also observed in some THz QCLs. The effect disappears for thinner barriers, higher quantum well doping, or modified contact layers, indicating a strong dependency on band bending, due to the large difference in the doping of the contact layers and the superlattice, which is confirmed with multiscattering Büttiker simulations.

Deep learning control of THz QCLs.

Artificial neural networks are capable of fitting highly non-linear and complex systems. Such complicated systems can be found everywhere in nature, including the non-linear interaction between optical modes in laser resonators. In this work, we demonstrate artificial neural networks trained to model these complex interactions in the cavity of a Quantum Cascade Random Laser. The neural networks are able to predict modulation schemes for desired laser spectra in real-time. This radically novel approach makes it possible to adapt spectra to individual requirements without the need for lengthy and costly simulation and fabrication iterations.

High-speed quantum cascade detector characterized with a mid-infrared femtosecond oscillator.

Quantum cascade detectors (QCD) are photovoltaic mid-infrared detectors based on intersubband transitions. Owing to the sub-picosecond carrier transport between subbands and the absence of a bias voltage, QCDs are ideally suited for high-speed and room temperature operation. Here, we demonstrate the design, fabrication, and characterization of 4.3 µm wavelength QCDs optimized for large electrical bandwidth. The detector signal is extracted via a tapered coplanar waveguide (CPW), which was impedance-matched to 50 Ω. Using femtosecond pulses generated by a mid-infrared optical parametric oscillator (OPO), we show that the impulse response of the fully packaged QCDs has a full-width at half-maximum of only 13.4 ps corresponding to a 3-dB bandwidth of more than 20 GHz. Considerable detection capability beyond the 3-dB bandwidth is reported up to at least 50 GHz, which allows us to measure more than 600 harmonics of the OPO repetition frequency reaching 38 dB signal-to-noise ratio without the need of electronic amplification.

Engineering the spectral bandwidth of quantum cascade laser frequency combs.

Quantum cascade lasers (QCLs) facilitate compact optical frequency comb sources that operate in the mid-infrared and terahertz spectral regions, where many molecules have their fundamental absorption lines. Enhancing the optical bandwidth of these chip-sized lasers is of paramount importance to address their application in broadband high-precision spectroscopy. In this work, we provide a numerical and experimental investigation of the comb spectral width and show how it can be optimized to obtain its maximum value defined by the laser gain bandwidth. The interplay of nonoptimal values of the resonant Kerr nonlinearity and cavity dispersion can lead to significant narrowing of the comb spectrum and reveals the best approach for dispersion compensation. The implementation of high mirror losses is shown to be favorable and results in proliferation of the comb sidemodes. Ultimately, injection locking of QCLs by modulating the laser bias around the round trip frequency provides a stable external knob to control the frequency-modulated comb state and recover the maximum spectral width of the unlocked laser state.

In-Phase and Anti-Phase Synchronization in a Laser Frequency Comb.

Coupled clocks are a classic example of a synchronization system leading to periodic collective oscillations. Already in 1665, Christiaan Huygens described this phenomenon as a kind of "sympathy" among oscillators. In this work, we describe the formation of two types of laser frequency combs as a system of oscillators coupled through the beating of the lasing modes. We experimentally show two completely different types of synchronization in a quantum dot laser-in-phase and splay-phase states. Both states can be generated in the same device, just by varying the damping losses of the system. This modifies the coupling among the oscillators. The temporal laser output is characterized using both linear and quadratic autocorrelation techniques. Our results show that both pulses and frequency-modulated states can be generated on demand within the same device. These findings allow us to connect laser frequency combs produced by amplitude-modulated and frequency-modulated lasers and link these to pattern formation in coupled systems such as Josephson-junction arrays.

High frequency modulation and (quasi) single-sideband emission of mid-infrared ring and ridge quantum cascade lasers.

We investigate the high frequency modulation characteristics of mid-infrared surface-emitting ring and edge-emitting ridge quantum cascade lasers (QCLs). In particular, a detailed comparison between circular ring devices and ridge-QCLs from the same laser material, which have a linear waveguide in a "Fabry-Pérot (FP) type" cavity, reveals distinct similarities and differences. Both device types are single-mode emitting, based on either 2 nd- (ring-QCL) or 1 st-order (ridge-QCL) distributed feedback (DFB) gratings with an emission wavelength around 7.56 µm. Their modulation characteristics are investigated in the frequency-domain using an optical frequency-to-amplitude conversion technique based on the ro-vibrational absorptions of CH 4. We observe that the amplitude of frequency tuning Δf over intensity modulation index m as function of the modulation frequency behaves similarly for both types of devices, while the ring-QCLs typically show higher values. The frequency-to-intensity modulation (FM-IM) phase shift shows a decrease starting from ∼72 ∘ at a modulation frequency of 800 kHz to about 0 ∘ at 160 MHz. In addition, we also observe a quasi single-sideband (qSSB) regime for modulation frequencies above 100 MHz, which is identified by a vanishing -1 st-order sideband for both devices. This special FM-state can be observed in DFB QCLs and is in strong contrast to the behavior of regular DFB diode lasers, which do not achieve any significant sideband suppression. By analyzing these important high frequency characteristics of ring-QCLs and comparing them to ridge DFB-QCLs, it shows the potential of intersubband devices for applications in e.g. novel spectroscopic techniques and highly-integrated and high-bitrate free-space data communication. In addition, the obtained results close an existing gap in literature for high frequency modulation characteristics of QCLs.

Thermoelectric-cooled terahertz quantum cascade lasers.

We demonstrate the first lasing emission of a thermo-electrically cooled terahertz quantum cascade laser (THz QCL). A high temperature three-well THz QCL emitting at 3.8 THz is mounted to a novel five-stage thermoelectric cooler reaching a temperature difference of ΔT = 124 K. The temperature and time-dependent laser performance is investigated and shows a peak pulse power of 4.4 mW and a peak average output power of 100 µW for steady-state operation.

Suppression of axial growth by boron incorporation in GaAs nanowires grown by self-catalyzed molecular beam epitaxy.

The addition of boron to GaAs nanowires grown by self-catalyzed molecular beam epitaxy was found to have a strong effect on the nanowire morphology, with axial growth greatly reduced as the nominal boron concentration was increased. Transmission electron microscopy measurements show that the Ga catalyst droplet was unintentionally consumed during growth. Concurrent radial growth, a rough surface morphology and tapering of nanowires grown under boron flux suggest that this droplet consumption is due to reduced Ga adatom diffusion on the nanowire sidewalls in the presence of boron. Modelling of the nanowire growth puts the diffusion length of Ga adatoms under boron flux at around 700-1000 nm. Analyses of the nanowire surfaces show regions of high boron concentration, indicating the surfactant nature of boron in GaAs.

Application of a ring cavity surface emitting quantum cascade laser (RCSE-QCL) on the measurement of H2S in a CH4 matrix for process analytics.

The present work reports on the first application of a ring-cavity-surface-emitting quantum-cascade laser (RCSE-QCL) for sensitive gas measurements. RCSE-QCLs are promising candidates for optical gas-sensing due to their single-mode, mode-hop-free and narrow-band emission characteristics along with their broad spectral coverage. The time resolved down-chirp of the RCSE-QCL in the 1227-1236 cm-1 (8.15-8.09 µm) spectral range was investigated using a step-scan FT-IR spectrometer (Bruker Vertex 80v) with 2 ns time and 0.1 cm-1 spectral resolution. The pulse repetition rate was set between 20 and 200 kHz and the laser device was cooled to 15-17°C. Employing 300 ns pulses a spectrum of ~1.5 cm-1 could be recorded. Under these laser operation conditions and a gas pressure of 1000 mbar a limit of detection (3σ) of 1.5 ppmv for hydrogen sulfide (H2S) in nitrogen was achieved using a 100 m Herriott cell and a thermoelectric cooled MCT detector for absorption measurements. Using 3 µs long pulses enabled to further extend the spectral bandwidth to 8.5 cm-1. Based on this increased spectral coverage and employing reduced pressure conditions (50 mbar) multiple peaks of the target analyte H2S as well as methane (CH4) could be examined within one single pulse.

Spectrally resolved far-fields of terahertz quantum cascade lasers.

We demonstrate a convenient and fast method to measure the spectrally resolved far-fields of multimode terahertz quantum cascade lasers by combining a microbolometer focal plane array with an FTIR spectrometer. Far-fields of fundamental TM0 and higher lateral order TM1 modes of multimode Fabry-Pérot type lasers have been distinguished, which very well fit to the results obtained by a 3D finite-element simulation. Furthermore, multimode random laser cavities have been investigated, analyzing the contribution of each single laser mode to the total far-field. The presented method is thus an important tool to gain in-depth knowledge of the emission properties of multimode laser cavities at terahertz frequencies, which become increasingly important for future sensing applications.

Advanced gas sensors based on substrate-integrated hollow waveguides and dual-color ring quantum cascade lasers.

This study shows the first combination of a ring-shaped vertically emitting quantum cascade laser (riQCL) providing two distinct emission wavelengths combined with a substrate-integrated hollow waveguide (iHWG). This ultra-compact riQCL-iHWG gas sensing device enables the simultaneous detection of two vapor phase species - here, furan and 2-methoxyethanol - providing distinctive absorption features at the emission wavelengths of the riQCL (i.e., 1144 and 1170 cm-1). Hence, multianalyte gas sensing via a unique mid-infrared (MIR) sensor concept is demonstrated.

Coupled cavity terahertz quantum cascade lasers with integrated emission monitoring.

We demonstrate the on-chip generation and detection of terahertz radiation in coupled cavity systems using a single semiconductor heterostructure. Multiple sections of a terahertz quantum cascade laser structure in a double-metal waveguide are optically coupled and operate either as a laser or an integrated emission monitor. A detailed analysis of the photon-assisted carrier transport in the active region below threshold reveals the detection mechanism for photons emitted by the very same structure above threshold. Configurations with a single laser cavity and two coupled laser cavities are studied. It is shown that the integrated detector can be used for spatial sensing of the light intensity within a coupled cavity.

Time-resolved spectral characterization of ring cavity surface emitting and ridge-type distributed feedback quantum cascade lasers by step-scan FT-IR spectroscopy.

We present the time-resolved comparison of pulsed 2nd order ring cavity surface emitting (RCSE) quantum cascade lasers (QCLs) and pulsed 1st order ridge-type distributed feedback (DFB) QCLs using a step-scan Fourier transform infrared (FT-IR) spectrometer. Laser devices were part of QCL arrays and fabricated from the same laser material. Required grating periods were adjusted to account for the grating order. The step-scan technique provided a spectral resolution of 0.1 cm(-1) and a time resolution of 2 ns. As a result, it was possible to gain information about the tuning behavior and potential mode-hops of the investigated lasers. Different cavity-lengths were compared, including 0.9 mm and 3.2 mm long ridge-type and 0.97 mm (circumference) ring-type cavities. RCSE QCLs were found to have improved emission properties in terms of line-stability, tuning rate and maximum emission time compared to ridge-type lasers.

Subwavelength micropillar array terahertz lasers.

We report on micropillar-based terahertz lasers with active pillars that are much smaller than the emission wavelength. These micropillar array lasers correspond to scaled-down band-edge photonic crystal lasers forming an active photonic metamaterial. In contrast to photonic crystal lasers which use significantly larger pillar structures, lasing emission is not observed close to high-symmetry points in the photonic band diagram, but in the effective medium regime. We measure stimulated emission at 4 THz for micropillar array lasers with pillar diameters of 5 µm. Our results not only demonstrate the integration of active subwavelength optics in a terahertz laser, but are also an important step towards the realization of nanowire-based terahertz lasers.

Grating-based far field modifications of ring quantum cascade lasers.

We present methods for beam modifications of ring quantum cascade lasers emitting around λ = 9µm, which are based on novel distributed feedback grating designs. This includes the creation of a rotationally symmetric far field with a central intensity maximum using an off-center grating as well as the generation of partial radially polarized emission beams induced by a rotation of the grating slits.

Quantum cascade lasers with a tilted facet utilizing the inherent polarization purity.

We report on quantum cascade lasers (QCLs) with a tilted facet utilizing their polarization property. Contrary to diode lasers, QCLs generate purely TM polarized light due to the intersubband selection rules. This property enables the utilization of reflectivity in terms of only TM polarized light (TM reflectivity). The TM reflectivity is reduced by tilting the front facet, resulting in enhanced light output power from the tilted facet. The peak output power of a QCL with a facet angle of 12° are increased by 31 %. The slope efficiency of a QCL with a facet angle of 17° are increased by 43 %. Additionally, a peculiar property of TM reflectivity, the Brewster angle, is investigated by using COMSOL simulations to find its availability in QCLs.

Design and performance of GaSb-based quantum cascade detectors.

InAs/AlSb quantum cascade detectors (QCDs) grown strain-balanced on GaSb substrates are presented. This material system offers intrinsic performance-improving properties, like a low effective electron mass of the well material of 0.026 m 0, enhancing the optical transition strength, and a high conduction band offset of 2.28 eV, reducing the noise and allowing for high optical transition energies. InAs and AlSb strain balance each other on GaSb with an InAs:AlSb ratio of 0.96:1. To regain the freedom of a lattice-matched material system regarding the optimization of a QCD design, submonolayer InSb layers are introduced. With strain engineering, four different active regions between 3.65 and 5.5 µm were designed with InAs:AlSb thickness ratios of up to 2.8:1, and subsequently grown and characterized. This includes an optimized QCD design at 4.3 µm, with a room-temperature peak responsivity of 26.12 mA/W and a detectivity of 1.41 × 108 Jones. Additionally, all QCD designs exhibit higher-energy interband signals in the mid- to near-infrared, stemming from the InAs/AlSb type-II alignment and the narrow InAs band gap.

Mid-infrared Ring Interband Cascade Laser: Operation at the Standard Quantum Limit.

Many precision applications in the mid-infrared spectral range have strong constraints based on quantum effects that are expressed in particular noise characteristics. They limit, e.g., sensitivity and resolution of mid-infrared imaging and spectroscopic systems as well as the bit-error rate in optical free-space communication. Interband cascade lasers (ICLs) are a class of mid-infrared lasers exploiting interband transitions in type-II band alignment geometry. They are currently gaining significant importance for mid-infrared applications from < 3 to > 6 µm wavelength, enabled by novel types of high-performance ICLs such as ring-cavity devices. Their noise behavior is an important feature that still needs to be thoroughly analyzed, including its potential reduction with respect to the shot-noise limit. In this work, we provide a comprehensive characterization of λ = 3.8 µm-emitting, continuous-wave ring ICLs operating at room temperature. It is based on an in-depth study of their main physical intensity noise features such as their bias-dependent intensity noise power spectral density and relative intensity noise. We obtained shot-noise-limited statistics for Fourier frequencies above 100 kHz. This is an important result for precision applications, e.g., interferometry or advanced spectroscopy, which benefit from exploiting the advantage of using such a shot-noise-limited source, enhancing the setup sensitivity. Moreover, it is an important feature for novel quantum optics schemes, including testing specific light states below the shot-noise level, such as squeezed states.

An interband cascade laser based heterodyne detector with integrated optical amplifier and local oscillator.

Heterodyne detection based on interband cascade lasers (ICL) has been demonstrated in a wide range of different applications. However, it is still often limited to bulky tabletop systems using individual components such as dual laser setups, beam shaping elements, and discrete detectors. In this work, a versatile integrated ICL platform is investigated for tackling this issue. A RF-optimized, two-section ICL approach is employed, consisting of a short section typically used for efficient modulation of the cavity field and a long gain section. Such a laser is operated in reversed mode, with the entire Fabry-Pérot waveguide utilized as a semiconductor optical amplifier (SOA) and the electrically separated short section as detector. Furthermore, a racetrack cavity is introduced as on-chip single-mode reference generator. The field of the racetrack cavity is coupled into the SOA waveguide via an 800 nm gap. By external injection of a single mode ICL operating at the appropriate wavelength, a heterodyne beating between the on-chip reference and the injected signal can be observed on the integrated detector section of the SOA-detector.

Enhanced light output power of quantum cascade lasers from a tilted front facet.

We present a technique for enhancing the light output power of quantum cascade lasers (QCLs) by tilting of the front facet, which leads to a change of the modal reflectivity, resulting in an asymmetric light intensity distribution along the laser cavity. This asymmetry provides most of the light being emitted through one facet of the laser. An experimental study of threshold current, slope efficiency and light output power as a function of the front facet angles were performed and compared to conventional QCLs. The lasers with a front facet angle of 8° shows a 20% improved power output from the front facet.