1.
RSC Adv
; 12(14): 8588-8591, 2022 Mar 15.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35424822
RESUMO
Planar chiral [2.2]paracyclophanes are resolved through the direct C-H arylation of enantiopure oxazolines, providing a convenient route to ligands and chiral materials. Preliminary results show that hydrolysis followed by decarboxylative phosphorylation leads to enantiopure [2.2]paracyclophane derivatives that are otherwise challenging to prepare.