Prevalence and Source Tracing of PFAS in Shallow Groundwater Used for Drinking Water in Wisconsin, USA.

Samples from 450 homes with shallow private wells throughout the state of Wisconsin (USA) were collected and analyzed for 44 individual per- and polyfluoroalkyl substances (PFAS), general water quality parameters, and indicators of human waste as well as agricultural influence. At least one PFAS was detected in 71% of the study samples, and 22 of the 44 PFAS analytes were detected in one or more samples. Levels of PFOA and/or PFOS exceeded the proposed Maximum Contaminant Levels of 4 ng/L, put forward by the U.S. Environmental Protection Agency (EPA) in March 2023, in 17 of the 450 samples, with two additional samples containing PFHxS ≳ 9 ng/L (the EPA-proposed hazard index reference value). Those samples above the referenced PFAS levels tend to be associated with developed land and human waste indicators (artificial sweeteners and pharmaceuticals), which can be released to groundwater via septic systems. For a few samples with levels of PFOA, PFOS, and/or PFHxS > 40 ng/L, application of wastes to agricultural land is a possible source. Overall, the study suggests that human waste sources, septic systems in particular, are important sources of perfluoroalkyl acids, especially ones with ≤8 perfluorinated carbons, in shallow groundwater.

Attenuation of Pb and Sb in shooting range soils by Fe amendments.

Lead (Pb) and antimony (Sb) contamination pose a major environmental risk at firing ranges and threaten land sustainability. Methods for the stabilization of metal (loid) contaminants are necessary to prevent off-site migration of metals in surface and ground water or from soil erosion. In the present study, two remediation treatments (ferric chloride/calcium carbonate and nanoscale zero-valent iron (nZVI)) were applied to flow-through soil columns containing four types of soils (sand, sandy loam, loamy sand, and silty loam) to study Pb and Sb behavior. Water runoff was continuously monitored for three months prior to amendment addition and for the following ten months. Soils were characterized before and after reaction. We found Sb was more mobile than Pb in all soil systems and was primarily present in the dissolved fraction whereas Pb was associated with both soil organic matter (SOM) and Fe colloids. Dominant Pb solid phase species were comprised of Pb0, PbO, PbCO3, and Pb sorbed to Fe(III) oxides while Sb was present as fully oxidized Sb(V) in soil and soil solution. The nZVI addition had minimal impact on Pb and Sb immobilization compared to control soil. The FeCl2 and CaCO3 amendment decreased pore water Sb concentrations by >80% for all soil types and >96% reduction in the fine- and coarse-grained soil types (silt loam and sand). Lead was initially mobilized coinciding with a decrease in pH from the hydrolysis of Fe(II) in solution. Additional soil treatments have the potential to be effective for system-wide immobilization with adequate additions of CaCO3 buffer. Though this study focused on bullet fragment weathering as a source of Pb and Sb the results have application to environmental monitoring and remediation efforts at mining or industrial runoff sites.