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1.
Int J Mol Sci ; 18(7)2017 Jul 17.
Artigo em Inglês | MEDLINE | ID: mdl-28714928

RESUMO

The aim of this study consisted of manufacturing renewable binderless fiberboards from coriander straw and a deoiled coriander press cake, thus at the same time ensuring the valorization of crop residues and process by-products. The press cake acted as a natural binder inside the boards owing to the thermoplastic behavior of its protein fraction during thermopressing. The influence of different fiber-refining methods was evaluated and it was shown that a twin-screw extrusion treatment effectively improved fiber morphology and resulted in fiberboards with enhanced performance as compared to a conventional grinding process. The best fiberboard was produced with extrusion-refined straw using a 0.4 liquid/solid (L/S) ratio and with 40% press cake addition. The water sensitivity of the boards was effectively reduced by 63% through the addition of an extrusion raw material premixing operation and thermal treatment of the panels at 200 °C, resulting in materials with good performance showing a flexural strength of 29 MPa and a thickness swelling of 24%. Produced without the use of any chemical adhesives, these fiberboards could thus present viable, sustainable alternatives for current commercial wood-based materials such as oriented strand board, particleboard and medium-density fiberboard, with high cost-effectiveness.


Assuntos
Materiais de Construção/análise , Teste de Materiais/métodos , Força Compressiva , Conservação dos Recursos Naturais/métodos , Coriandrum , Resistência à Tração , Madeira
2.
Environ Sci Pollut Res Int ; 27(14): 16121-16133, 2020 May.
Artigo em Inglês | MEDLINE | ID: mdl-32100217

RESUMO

Indoor air quality is a major public health issue. It is related to the choice of construction materials and associated with VOC emissions. Two wood-based commercial panels were tested: a medium-density fiberboard (MDF) and a chipboard (CH), and they were compared to a material produced from a coriander biorefinery (COR). Indicators chosen to compare the materials were physical properties (density, bending properties, surface hardness, thickness swelling, and water absorption) and VOC emissions. Emissions were evaluated in an environmental chamber at 23 °C, 31 °C, and 36 °C, and during 28 days. Carbonyl emissions on day 1 at 23 °C were 74, 146, and 35 µg m-2 h-1, respectively, for MDF, CH, and COR. Terpenic emissions were 12, 185, and 37 µg m-2 h-1, respectively. Higher temperature resulted in higher emissions which decreased over time, except for formaldehyde. VOC emissions depended largely on material and temperature. Formaldehyde emission was 300 to 600 times lower for coriander boards (< 0.2 µg m-2 h-1), making them significantly more environmentally friendly materials in comparison with MDF and chipboard. These results highlight the interest of coriander by-products as raw materials for producing fiberboards with low impact on indoor air quality.


Assuntos
Poluição do Ar em Ambientes Fechados/análise , Coriandrum , Compostos Orgânicos Voláteis/análise , Materiais de Construção , Formaldeído/análise , Madeira/química
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