1.
J Org Chem
; 84(21): 13935-13947, 2019 11 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-31533423
RESUMO
The redox-neutral cascade dearomatization of indoles with o-aminobenzaldehydes has been realized via the hydride transfer strategy, achieving the condition- and substrate-controlled divergent synthesis of tetrahydroquinoline-fused spiroindolenines. The integration of hydride transfer-involved C(sp3)-H functionalization with dearomatization provides a promising platform for the construction of structurally diverse molecules.